Synthesis and properties of peroxy derivatives of epoxy resins based on Bisphenol A: Effects of the presence of boron trifluoride ethereate

Oligomers containing peroxy groups have been synthesized on the basis of epoxides reacting with tert–butylhydroperoxide in the presence of boron trifluoride etherate. Dependence of reaction rates upon the quantity of catalyst, temperature and also nature of hydroperoxide has been investigated: A kinetic equation for the process has been formulated and also a kinetic scheme for the reaction taking into account the presence of boron trifluoride etherate is proposed. Structures of the synthesized peroxy oligomers have been confirmed by IR- and NMR-spectroscopy. The reaction initiating properties of the oligomers so synthesized were studied using as the example the styrene polymerization reaction. Electronic Publication     

Penetration of a thick plate by a slightly deformable long rod

A numerical simulation has been performed for the high-velocity deep penetration of a slightly deformable long rod into a thick plate. The main features are examined for the multistage rod retardation, and a study is made on how the impact velocity affects the characteristic parameters. An analytical model is formulated for the interaction, which is convenient for engineering use. The calculation agrees well with available experiments.Translated from Problemy Prochnosti, No. 10, pp. 63—70, October, 1993.We are indebted to Professor Sh. U. Galiev for participating in the formulation and for fruitful discussions.     

Allelic polymorphism of the DNA-loci met and D7S23, linked to the mucoviscidosis gene in human populations of the Volga-Ural region

Data on allelic polymorphism of MET and D7S23 DNA loci linked to the human cystic fibrosis gene studied in three Bashkir ethnic groups and some Volga-Ural populations (Tartars, Maris, Mordovians, Udmurts, Chuvashs, and Komis) are presented. Udmurts were found to be substantially different from Bashkirs, Tartars, Mordovians, and Chuvashs by the allele frequency distribution observed for MET, while Komis and Bashkirs differed by this parameter from Mordovians and Maris. Comparative analysis of restriction fragment length polymorphism (RFLP) at the D7S23 locus revealed statistically significant differences in genotype frequencies between Bashkirs of the Arkhangel' skii region and populations of Mordva and Udmurtia. In this respect, the Mordovian population appeared to be notably different from the populations of Bashkortostan, Tatarstan, Marii-El, Udmurtiya, Chuvashiya, and Komis. Genetic distances were calculated and corresponding dendrograms were constructed on the basis of data on Met-H, CS.7, and the ApoB locus hypervariable region allelic frequencies. Three ethnogeographic Bashkir groups belonging to one tree branch were found to be closely related to the populations of Tartars, Maris, Udmurts, and Chuvashs and substantially different from Komis and Mordovians. Thus, the position of Volga-Ural populations on the dendrogram corresponds to the degree of relationship between the Finno-Ugric and Turkic populations, confirming the usefulness of DNA polymorphism analysis for the study of the genetic structure of populations.     

Physicomechanical properties and failure of detonation coatings

Conclusions The effect of the complex of external factors such as plastic deformation, temperature, chemical interaction causes structural and phase changes of powder materials in detonation coatings leading to relatively low ductility of the coating. The bend strength of the coatings up to 0.25 mm thick is similar to that of the dense materials. To produce high-quality detonation coatings, it is necessary to avoid hard temperature and kinetic parameters of the spraying process, and the extent of deformation of the particles should be limited to minimize formation, in the coatings, of internal stresses and a defective structure. Coatings made of alloyed steels with a large amount of the hardening phase are especially sensitive to defects.The physicochetnical and mechanical properties of the coatings on the substrates showed the strong mutual effect in the process of formation of the coatings and combined deformation under loading. This fact must be taken into account in selecting coating-substrate pairs for service in the conditions specified in advance.The mechanism of failure of detonation of coatings up to 0.25 mm thick produced by optimum technology in three-point bend loading does not differ from the mechanism of failure of the dense materials. With increasing thickness of the coatings their strength and ductility properties rapidly decrease and the failure mechanism also changes.Translated from Poroshkovaya Metallurgiya, No. 11(299), pp. 88–94, November, 1987.     

DSGE Model Estimation on the Basis of Second-Order Approximation

This article compares the properties of different non-linear Kalman filters: the well-known Unscented Kalman filter (UKF), the central difference Kalman filter (CDKF) and the new Quadratic Kalman filter (QKF). A small financial DSGE model is repeatedly estimated by several quasi-likelihood methods with different filters for data generated by the model. Errors in parameters estimation are a measure of the filters’ quality. The result shows that the QKF has a reasonable advantage in terms of quality over the CDKF and the UKF, albeit with some loss in speed.     

Fracture of solids by radiation pulses as a method of ensuring safety in space

To determine the optimum conditions of fracturing or altering the trajectory of dangerous space objects (large iron or rock space bodies, threatening to collide with the Earth), and also destroy space debris in the space around the Earth, the author presents a mathematical formulation of the problem of calculating the dynamic strength of solids under the effect of high-energy loading pulses. The results of numerical modeling are compared with the experimental data for the formulation of cupola-shaped swollen areas on the rear surface of a metallic plate subjected to laser radiation. The change in the fracture mechanisms (front and rear spallation) with increasing energy of the effect has been detected. Recommendations are given for optimizing the pulsed laser effect on dangerous space objects to ensure the fragmentation or change their orbit.Expanded form of the document presented at the International Conference Space Protection of the Earth≓ (SPE'94, Snezhinsk, Russian, September 26–30, 1994).Translated from Problemy Prochnosti, No. 3, pp. 31–51, March, 1996.     

Effect of current pulse frequency on the structure and properties of electric-spark alloyed coatings of the Ti - Al - N system

The mass transfer kinetics, composition, structure, and properties of coatings, formed by high-frequency electric-spark alloying of 45 and 40X steels with the Ti - Al (3:1, 1:1, 1:3) intermetallics and TiN - AIN (1:1) nitride were studied as a function of the current pulse frequency(ν = 1200 and 1600 Hz). A decrease in ν was found to lead to a higher mass transfer coefficient and higher microhardness and Young’s modulus of the coating as well. This is due to the decrease in the Ti/Al ratio on the surface. The phase composition of intermetallic and nitride coatings differed only insignificantly and did not depend on the value of ν. The main phases of the coatings were Fe - Ti - O and Al - Ti - O solid solutions. The nitride and intermetallic coatings had similar friction coefficients f and wear rates I (f = 0.26 and 0.28, I = 5.4 and 5.9 µm/km), despite the difference in their structure. We can assume that the coating phase composition which defines the composition of the secondary structure under dry friction, is the main factor controlling tribological behavior.