Effect of the geometry and pattern of the flow channel on the performance of polymer electrolyte membrane fuel cell

This research focuses on the effect of the geometry and patterns of the gas flow channel on the PEM fuel cell performance. Simulation was conducted and the results were verified by experiments. Three-dimensional, single phase, compressible and isothermal models of 5 cm² electrodes, anode and cathode, were developed and studied by utilizing a commercial Computational Fluid Dynamics (CFD) software, FLUENT 4.5. Two types of gas flow channel were investigated: conventional and interdigitated. The results showed that the flow channel pattern does not have a significant effect on the anode cell performance, whereas it has a strong effect/influence on the cathode cell performance. The interdigitated design provides a higher limiting current density and cell performance than the conventional design on the cathode side. Moreover, the cell performance does not depend on the inlet and outlet channel widths. On the contrary, for the interdigitated design, it was influenced by the shoulder width. Finally, experiments were conducted to validate the simulation results.     

TIVA and SEI developments for enhanced front and backside interconnection failure analysis

Thermally-Induced Voltage Alteration (TIVA) and Seebeck Effect Imaging (SEI) are newly developed techniques for localizing shorted and open conductors from the front and backside of an IC. Recent improvements have greatly increased the sensitivity of the TIVA/SEI system, reduced the acquisition times by more than 20X, and localized previously unobserved defects. The system improvements, non-linear response of IC defects to heating, modeling of laser heating and examples using the improved system are presented.     

Electronic structures of interfacial states formed at polymeric semiconductor heterojunctions

Heterojunctions between organic semiconductors are central to the operation of light-emitting and photovoltaic diodes, providing respectively for electron-hole capture and separation. However, relatively little is known about the character of electronic excitations stable at the heterojunction. We have developed molecular models to study such interfacial excited electronic excitations that form at the heterojunction between model polymer donor and polymer acceptor systems: poly(9,9-dioctylfluorene-co-bis-N,N-(4-butylphenyl)-bis-N,N-phenyl-1,4-phenylenediamine) (PFB) with poly(9,9-dioctylfluorene-co-benzothiadiazole) (F8BT), and poly(9,9-dioctylfluorene-co-N-(4-butylphenyl)diphenylamine) (TFB) with F8BT. We find that for stable ground-state geometries the excited state has a strong charge-transfer character. Furthermore, when partly covalent, modelled radiative lifetimes (approximately 10(-7) s) and off-chain axis polarization (30 degrees) match observed 'exciplex' emission. Additionally for the PFB:F8BT blend, geometries with fully ionic character are also found, thus accounting for the low electroluminescence efficiency of this system.     

Photocatalytic degradation of benzene,toluene, ethylbenzene,and xylene (BTEX) using transition metal-doped titanium dioxide immobilized on fiberglass cloth

Transition metal (Fe, V and W)-doped TiO₂ was synthesized via the solvothermal technique and immobilized onto fiberglass cloth (FGC) for uses in photocatalytic decomposition of gaseous volatile organic compounds—benzene, toluene, ethylbenzene and xylene (BTEX)—under visible light. Results were compared to that of the standard commercial pure TiO₂ (P25) coated FGC. All doped samples exhibit higher visible light catalytic activity than the pure TiO₂. The V-doped sample shows the highest photocatalytic activity followed by the W- and Fe-doped samples. The UV-Vis diffuse reflectance spectra reveal that the V-doped sample has the highest visible light absorption followed by the W- and Fe-doped samples. The X-ray diffraction (XRD) patterns indicate that all doped samples contain both anatase and rutile phases with the majority (>80%) being anatase. No new peaks associated with dopant oxides can be observed, suggesting that the transition metal (TM) dopants are well mixed into the TiO₂ lattice, or are below the detection limit of the XRD. The X-ray absorption near-edge structure spectra of the Ti K-edge transition indicate that most Ti ions are in a tetravalent state with octahedral coordination, but with increased lattice distortion from Fe- to V- and W-doped samples. Our results show that the TM-doped TiO₂ were successfully synthesized and immobilized onto flexible fiberglass cloth suitable for treatment of gaseous organic pollutants under visible light.     

Local thermal probing to detect open and shorted IC interconnections

A new failure analysis technique has been developed for backside and frontside localization of open and shorted interconnections on ICs. This scanning optical microscopy technique takes advantage of the interactions between IC defects and localized heating using a focused infrared laser (λ=1340 nm). Images are produced by monitoring the voltage changes across a constant current supply used to power the IC as the laser beam is scanned across the sample. The method utilizes the Seebeck Effect to localize open interconnections and Thermally-Induced Voltage Alteration to detect shorts. The interaction physics describing the signal generation process and several examples demonstrating the localization of opens and shorts are described. Operational guidelines and limitations are also discussed.     

The Metalloporphyrin Antioxidant, MnTE-2-PyP, Inhibits Th2 Cell Immune Responses in an Asthma Model

MnTE-2-PyP, a superoxide dismutase mimetic, inhibited OVA-induced airway inflammation in mice suggesting an effect on Th2 responsiveness. Thus, we hypothesized that MnTE-2-PyP may alter dendritic cell-Th2 interactions. Bone marrow derived dendritic cells (DC) and OVA(323-339)-specific Th2 cells were cultured separately in the presence or absence of MnTE-2-PyP for 3 days prior to the co-culturing of the two cell types in the presence of an OVA(323-339) peptide and in some cases stimulated with CD3/CD28. MnTE-2-PyP-pretreated DC inhibited IL-4, IL-5 and IFNγ production and inhibited Th2 cell proliferation in the DC-Th2 co-culturing system in the presence of the OVA(323-339) peptide. Similar results were obtained using the CD3/CD28 cell-activation system; the addition of MnTE-2-PyP inhibited Th2 cell proliferation. MnTE-2-PyP suppressed CD25 expression on OVA-specific Th2 cells, which implied that MnTE-2-PyP can inhibit the activation of Th2 cells. MnTE-2-PyP also down-regulated co-stimulatory molecules: CD40, CD80 and CD86 on immature DC. Our studies suggest that the major mechanism by which MnTE-2-PyP inhibits airway inflammation is by acting on the DC and suppressing Th2 cell proliferation and activation.     

Frequency dependence of the lifetime of a surface micromachined microengine driving a load

Experiments have been performed on surface micromachined microengines driving load gears to determine the rotational frequency dependence on median cycles to failure. A sample of 272 microengines, each driving a load, was stressed at eight different frequencies. Frequency dependence was observed and a model was developed based on fundamental wear mechanisms and forces exhibited in resonant mechanical systems. Stressing loaded microengines caused observable wear in the rotating joints and in a few instances led to fracture of the pin joint in the drive gear.     

On investigation of vibro-acoustics of FDB spindle motors for hard disk drives

The present work investigates vibro-acoustic behaviors of the fluid dynamic bearing (FDB) spindle motors for hard disk drives (HDD) through the sound spectra and the frequency response functions (FRF) of the motor structure. The quantitative evidence on the significance of the acoustic noise originated from the electromagnetic source is deduced from the sound spectra that were measured in two distinct cases of the spinning motor: in the normal operation and at the moment immediately after the power supply was disconnected. It is found that the effect of electromagnetic noise source is more dominant than the combined effect of the mechanical and aerodynamic sources. In addition, it is identified that, within the audible range of frequency, the frequency range of 13.4–20 kHz deems important to the noise problem as it is the main contributor to the acoustic noise for the FDB spindle motors. Moreover, the structural resonances that can be identified via the FRF are found to play an important role in the noise emitted by the motors. The concurrence of resonance and excitation frequencies clearly intensifies the sound spectrum, resulting in high discrete peaks, hence higher decibel level.     

Electrospinning of poly(l‐lactide‐co‐dl‐lactide) copolymers: Effect of chemical structures and spinning conditions

Nanofibers of poly(L ‐lactide‐co‐DL ‐Lactide) (PDLLA_x) copolymers with DL‐lactate (DLLA) contents of 0, 2.5, 7.5, and 50%, which exhibit strong structure/properties correlation, were fabricated by electrospinning. Effect of the copolymer structure and electrospinning conditions on morphology and properties of the fibers were examined by SEM, DSC, XRD, and tensile measurements. Bead‐free fibers of PDLLA_x prepared from a DMF/CHCl₃ mixed solvent are roughly 10‐times smaller in size (600–800 nm), with lower degree of surface porosity, compared to those of CHCl₃. When CHCl₃ is employed, an increase in size (2.4–5.5 μm) and surface porosity (0–45%) with relative humidity value is observed in crystallizable copolymers, whereas an amorphous copolymer shows a reverse trend. Thermal properties and chain arrangements of the electrospun fibers are critically affected by DLLA content of the copolymers and electrospinning conditions, as a result from interplay between intermolecular and intramolecular hydrogen bonding. Contents of crystalline domains and “physical crosslinks” generated from DL lactate segments are proposed as the origin of this phenomenon. Fiber mats of PDLLA with 50% DLLA content show a large improvement in all aspects of mechanical properties, which are suitable for various biomedical applications. POLYM. ENG. SCI., 54:472–480, 2014. © 2013 Society of Plastics Engineers     

Thermal modeling of localized laser heating in multi-level interconnects

Thermal modeling was used to simulate thermal profiles from localized laser heating on two multi-level interconnect structures with metallization complexity comparable to those used in advanced interconnect systems. The modeling focused on addressing issues with regard to the effectiveness of laser-based techniques in defect localization in state-of-the-art metallization schemes. Modeling results indicate that indirect heating from the laser does not propagate effectively through adjacent metal layers from both the front side and the back side. Poor heat conduction and its associated thermal spreading during laser heating make defect detection difficult beyond three levels of metal. Thermal distribution and spreading were found to be more affected by interconnect geometries than by variations in laser spot size. Smaller temperature rises during laser heating were observed in the newer interconnect structures consisting of copper and low-k dielectric materials than in those with conventional aluminum, tungsten, and silicon dioxide. The smaller temperature rise leads to weaker signal strength at the defect sites and makes it more difficult to detect defects in the newer-material structures. Metallization density also affects heat conduction in advanced interconnect systems but the temperature rise during laser heating varies slowly as a function of metallization density.