Metal Oxide Nanowire and Thin-Film-Based Gas Sensors for Chemical Warfare Simulants Detection

This work concerns with metal oxide (MOX) gas sensors based on nanowires and thin films. We focus on chemical warfare agents (CWAs) detection to compare these materials from the functional point-of-view. We work with different chemicals including simulants for Sarin nerve agents, vescicant gases, cyanide agents, and analytes such as ethanol, acetone, ammonia, and carbon monoxide that can be produced by everyday activities causing false alarms. Explorative data analysis has been used to demonstrate the different sensing performances of nanowires and thin films. Within the chosen application, our analysis reveal that the introduction of nanowires inside the array composed by thin films can improve its sensing capability. Cyanide simulants have been detected at concentrations close to 1 ppm, lower than the Immediately Dangerous for Life and Health (IDLH) value of the respective warfare agent. Higher sensitivity has been obtained to simulants for Sarin and vescicant gases, which have been detected at concentrations close or even lower than 100 ppb. Results demonstrate the suitability of the proposed array to selectively detect CWA simulants with respect to some compounds produced by everyday activities.     

Low sensitivity of computed tomography in the staging of gastric lymphomas of mucosa-associated lymphoid tissue: impact on prospective trials and ordinary clinical practice

The natural history and management of gastric lymphomas of mucosa-associated lymphoid tissue (MALTomas) are not completely understood. Most stage I cases are now entered into prospective trials to confirm the excellent results obtained with conservative treatment, whereas current therapeutic policies are based on accumulated experience. The limits of staging work-ups may have a significant impact on prospective trials and ordinary clinical practice. The authors explore the sensitivity of computed tomography scanning in detecting perigastric adenopathy in 20 patients with gastric MALToma treated by gastrectomy. Clinical staging identified 17 patients as having stage I MALTomas and three patients as having stage II1 MALTomas. Histopathologic staging showed that 8 of 17 patients formerly diagnosed with stage I MALToma had perigastric nodal involvement, whereas the three patients with clinical stage II1 were confirmed as such. Computed tomography scanning has low sensitivity in detecting perigastric lymphadenopathy in gastric MALTomas. This leads to understaging, with a significant impact on therapeutic decision, and distorts newly acquired knowledge about the disease's natural history and management, introducing a bias in prospective clinical trials. Endoscopic ultrasonography should be tested as a staging procedure both in prospective trials and in ordinary clinical practice.     

The photoinduced charge transfer mechanism in aligned and unaligned carbon nanotubes

Using time-resolved reflectivity measurements on unaligned and aligned bundled single-wall carbon nanotubes with a pump energy of 1.55 eV, quasi-resonant with the second Van Hove singularity of semiconducting tubes, a positive sign of the transient reflectivity is detected in unaligned nanotubes. In contrast a negative sign is detected in aligned nanotubes. This discovery addresses a long-standing question showing that in unaligned nanotubes the stronger intertube interactions favor the formation of short-lived free charge carriers in semiconducting tubes. A detailed analysis of the transient reflectivity spectral response shows that the free carriers in the photo-excited state of semiconducting tubes move towards metallic tubes in about 400 fs.     

Gas Sensing Behavior of Mesoporous SiOC Glasses

In this study, for the first time, we report the gas sensing behavior of aerogel‐derived silicon oxycarbide (SiOC) glasses. The SiOC glass pyrolyzed at 1400°C has specific surface area of 150 m²/g with pore size in the 2–20 nm range. SiOC sensor shows good response to 5 ppm NO₂ at 300°C. NO₂ response completely disappears at 400°C, and from this temperature SiOC sensor starts respond to H₂. The optimum sensitivity for H₂ is obtained at 500°C. SiOC sensor is very selective; it is not sensitive to other gases such as acetone vapor or CO, even at high concentrations.     

Leaf area index estimation with MODIS reflectance time series and model inversion during full rotations of Eucalyptus plantations

The leaf area index (LAI) of fast-growing Eucalyptus plantations is highly dynamic both seasonally and inter-annually, and is spatially variable depending on pedo-climatic conditions. LAI is very important in determining the carbon and water balance of a stand, but is difficult to measure during a complete stand rotation and at large scales. Remote-sensing methods allowing the retrieval of LAI time series with accuracy and precision are therefore necessary. Here, we tested two methods for LAI estimation from MODIS 250m resolution red and near-infrared (NIR) reflectance time series. The first method involved the inversion of a coupled model of leaf reflectance and transmittance (PROSPECT4), soil reflectance (SOILSPECT) and canopy radiative transfer (4SAIL2). Model parameters other than the LAI were either fixed to measured constant values, or allowed to vary seasonally and/or with stand age according to trends observed in field measurements. The LAI was assumed to vary throughout the rotation following a series of alternately increasing and decreasing sigmoid curves. The parameters of each sigmoid curve that allowed the best fit of simulated canopy reflectance to MODIS red and NIR reflectance data were obtained by minimization techniques. The second method was based on a linear relationship between the LAI and values of the GEneralized Soil Adjusted Vegetation Index (GESAVI), which was calibrated using destructive LAI measurements made at two seasons, on Eucalyptus stands of different ages and productivity levels. The ability of each approach to reproduce field-measured LAI values was assessed, and uncertainty on results and parameter sensitivities were examined. Both methods offered a good fit between measured and estimated LAI (R² = 0.80 and R² = 0.62 for model inversion and GESAVI-based methods, respectively), but the GESAVI-based method overestimated the LAI at young ages.     

Semiconducting tin oxide nanowires and thin films for Chemical Warfare Agents detection

In this work we report the preparation and structural characterization of tin oxide nanowires as functional materials for the development of chemical sensors. Aspects of material preparation relevant for gas sensing applications, such as the control of the wire diameter, are emphasized. The functional characterization is focused on the detection of Chemical Warfare Agents (CWAs) simulants, with particular regard to poisoning effects induced by dimethyl methyl phosphonate (DMMP), a simulant for Sarin nerve agent. Tin oxide thin films, prepared by means of rheotaxial growth and thermal oxidation (RGTO) technique, are used as reference to better compare the performance of nanowires with thin films traditionally used in gas sensing field.     

Spectral features associated with nitrogen,phosphorus, and potassium deficiencies in Eucalyptus saligna seedling leaves

Nitrogen (N), phosphorous (P) and potassium (K) deficiency symptoms were induced in Eucalyptus saligna seedlings. Leaves of these seedlings were measured radiometricaly in order to characterize spectrally the symptoms. It was used the SPECTRON SE-590, linked to a LICOR integrating sphere, running at 0.4 to 0.09 mu m spectral range. The results indicated that only the symptoms related with K deficiency could be spectrally detected in the visible region. The time lag from the beginning of the experiment was fundamental to characterize the symptoms, due to the synergism of the symptoms related with mineral deficiencies. The SPECTRON SE-590 fine spectral resolution proved unnecessary to spectrally characterize the symptoms.     

Spectral reflectance characterization of shallow lakes from the Brazilian Pantanal wetlands with field and airborne hyperspectral data

The relationships between field water reflectance spectra and physico-chemical data of seven freshwater and five saltwater lakes from the Brazilian Pantanal wetlands were characterized. Selection of the lakes was based on previous inspection of the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) images. Principal component analysis (PCA) was used to identify homogeneous groups of lakes, in which the regression relationships were evaluated. The continuum removal method was applied to characterize minor spectral variations in the depth of the absorption bands present in field and image spectra. The results showed lakes with very distinct spectral characteristics. The transition from the freshwater to the saltwater lakes was characterized by lower values of depth and Secchi depth, larger concentrations of dissolved organic carbon (DOC), total suspended sediments (TSS), calcium (Ca), magnesium (Mg), sodium (Na) and potassium (K), and higher values of pH and electrical conductivity. The saline lakes presented a higher overall reflectance in the 400–900?nm range than the freshwater lakes, as indicated by the first principal component. From the optically active constituents analysed, DOC better explained variations in water reflectance. The discrimination of the saltwater lakes along the second principal component was due to the decrease in the chlorophyll (Chl) and to the increase in the DOC concentrations from the greenish to the bluish saline lakes. The AVIRIS instrument was able to detect the narrow 630?nm absorption band present in field water reflectance spectra.