A review of the photovoltaic industry and its development in Africa

This article presents an overview of the commercialisation experiences of photovoltaics and draws some conclusion from the past and applies them to the future. In particular, the development for this industry in Africa is examined to identify the areas of strength and potential as well as the necessary infrastructure—for production, distribution and installation in order to support its growth. The question of capital requirement versus the efficiency of photovoltaics is highlighted and the reliabilty factor is analysed. As a result of examining the past, three issues seem crucial for the future development of photovoltaics, especially in Africa: (1) technology development; (2) education; (3) finance. These issues are addressed and their interdependence and impact on the use of photovoltaics are explored. The success stories of several photovoltaic companies in Africa, in spite of their problems, can be a source of optimism for the future contribution of this industry to the improved quality of life and economic growth as well as the employment opportunities on this continent. Finally, a method of co-operation between research in photovoltaics at the universities and local industry is proposed as part of the Research and Development (R&D) infrastructure necessary for the technical support of this field.     

Influence of long- term aging and superimposed creep

In an effort to understand the effects of long-term aging at high temperatures and those of the superimposed creep stresses on the microstructural variations in a 0.50Cr-0.50Mo-0.25V steel, the shoulder and gage portions of the specimens subjected to stress rupture tests at 500 °C and 540 °C have been studied by transmission electron microscopy. The optical microstructure, in the normalized and tempered condition, consists of about 95 pct ferrite with the remainder bainite. The ferrite has an extremely fine precipitation of vanadium carbide (VC) as interphase precipitate as well as in random distribution. In the bainitic area, M₃C is present in the globular as well as plate-like morphology. Specimens ruptured at 500 °C and 540 °C were selected for transmission electron microscopic study. Both the interphase precipitates and randomly distrib- uted precipitates of VC coarsen considerably due to prolonged exposure at elevated tempera- tures, and ultimately fine M₂C platelets nucleate and grow on either side of these precipitates, resulting in the formation of the so-called H-carbides. The superimposed creep stress has a marginal effect on the coarsening kinetics of VC but has enhanced its precipitation along dis- locations and has promoted the formation of H-carbides.     

Al-4.5Cu-2Mg合金应力-应变定位及分布的有限元分析（英文）

通过有限元方法分析不同加工路线和条件对Al-4.5Cu-2Mg合金微观形变行为的影响。合金采用4种不同的加工技术和条件制备,分别为有或无细化剂的常规重力铸造、流变铸造和SIMA工艺。以合金的光学显微结构作为代表性体积元(RVEs),采用两种不同的边界条件模拟合金在单轴载荷作用下的变形行为,最后将模拟的应力-应变行为与实验结果进行比较。结果表明,微观结构形态对应力和应变分布及承载能力具有显著影响,共晶相比α(Al)相能承受更高的载荷,具有较薄且均匀分布的共晶网络结构的球状α(Al)相能提供更好的应力和应变分布。因此,SIMA加工合金比其他技术加工合金拥有更好的应力和应变分布。最后,将该合金的模拟屈服强度与实验进行验证,结果具有较好的一致性。     

Experimental and theoretical study on amino acid derivatives as eco-friendly corrosion inhibitor on mild steel in hydrochloric acid solution

Amino acid derivatives, namely, 2-(2-oxo-2-phenothiazin-10-yl)ethylamino)-3-mercaptopropanoic acid (OPEM) and 2-(2-oxo-2-phenothiazin-10-yl)ethylamino)acetic acid (OPEA) were synthesized and investigated as inhibitors for mild steel corrosion in 15% HCl solution using the weight loss, polarization, and electrochemical impedance spectroscopy (EIS) techniques. The inhibition efficiency of both the inhibitors increased with increasing the temperature and concentration of inhibitor. The inhibitors OPEM and OPEA show corrosion inhibition efficiency of 97.5 and 95.8%, respectively, in 200?ppm concentration, at 333?K. Polarization studies showed that both studied inhibitors were of mixed type in nature. The adsorption of inhibitors on the mild steel surface obeys Langmuir adsorption isotherm and the surface of inhibited and uninhibited specimens were analyzed by scanning electron microscopy (SEM). The semiempirical AM1 method was employed for theoretical calculations and the obtained results were found to be consistent with the experimental findings.     

Multi-party semi-quantum key distribution-convertible multi-party semi-quantum secret sharing

This paper proposes a multi-party semi-quantum secret sharing (MSQSS) protocol which allows a quantum party (manager) to share a secret among several classical parties (agents) based on GHZ-like states. By utilizing the special properties of GHZ-like states, the proposed scheme can easily detect outside eavesdropping attacks and has the highest qubit efficiency among the existing MSQSS protocols. Then, we illustrate an efficient way to convert the proposed MSQSS protocol into a multi-party semi-quantum key distribution (MSQKD) protocol. The proposed approach is even useful to convert all the existing measure–resend type of semi-quantum secret sharing protocols into semi-quantum key distribution protocols.     

Influence of long-term aging at 520 °C and 560 °C and the superimposed creep stress on the microstructure of 1.25Cr-0.5Mo steel

In order to understand the influence of high-temperature aging effects and those of the superimposed creep stress on the microstructural variations in a 1.25Cr-0.5Mo steel, the shoulder as well as gage portions of specimens subjected to stress-rupture tests at 520 °C and 560 °C have been studied by transmission electron microscopy. In the normalized and tempered condition, the microstructure of the steel consists of 90 pct ferrite and 10 pct bainite, and M₃C is the only carbide present in bainite and at a few ferrite grain boundaries. On aging at 520 °C for 5442 hours, Cr₂N precipitates in a fibrous form at ferrite-bainite interfaces, and the creep stress has enhanced this mode of precipitation. On holding for 13,928 hours at 520 °C, fibrous carbide is still present but its composition has changed to Mo₂C, while the superimposed creep stress has promoted the precipitation of Mo₂C needles with fine globular precipitates of M₂₃C₆. Aging at 560 °C for 1854 or 10,338 hours has resulted in the precipitation of longer Mo₂C needles and ellipsoidal M₂₃C₆ carbide precipitation; the superimposed creep stress has resulted in a more dense precipitation of shorter needles in both cases. There is some recovery of bainitic ferrite at 560 °C, though the cementite coarsening is negligible.     

PFC-CTR,PFC-OCB: Efficient stream cipher modes of authencryption

Authencryption is a cryptographic process of providing confidentiality and integrity protection of messages in a single pass, simultaneously, without any support of conventional checksum, MAC, or hash function. This article encompasses the process to construct the stream cipher-based authencryption environment, where the keystream is generated from any secure block algorithm like AES. Accordingly, in order to demonstrate the working principle of authencryption in the stream cipher environment, the authors introduce two stream cipher modes of authencryption, namely, PFC-CTR and PFC-OCB. PFC-CTR denotes the counter-based authencryption environment, and PFC-OCB specifies the authencryption environment built upon the underlying foundation of OCB. They argue that both of the proposed stream cipher modes of authencryption are quite robust against several active attacks (e.g., message stream modification attacks, known-plain-text attacks, and chosen-plain-text attacks). At the same time, they can efficiently deal with other issues like “limited error propagation,” and so on, existing in several conventional stream cipher modes of operation like CFB, OFB, and CTR.     

Affine invariant comparison of point-sets using convex hulls and hausdorff distances

Many object recognition or identification applications involve comparing features associated with point-sets. This paper presents an affine invariant point-set matching technique which measures the similarity between two point-sets by embedding them into an affine invariant feature space. The developed technique assumes no a priori knowledge of reference points, as is the case in many identification problems. Reference points of a point-set are obtained based on its convex hull. An enhanced version of the Modified Hausdorff Distance is also introduced and used in the feature space for comparing two point-sets. It should be noted that the technique does not attempt to obtain correspondences between the point-sets. The introduced technique is applied to two real databases and its performance is found favorable as compared to three other affine invariant matching techniques.     

Finite element analysis of stress–strain localization and distribution in Al-4.5Cu-2Mg alloy

Finite element analysis has been carried out to understand the effect of various processing routes and condition on the microscale deformation behavior of Al-4.5Cu-2Mg alloy. The alloy has been developed through four different routes and condition, i.e. conventional gravity casting with and without refiner, rheocasting and SIMA process. The optical microstructures of the alloy have been used to develop representative volume elements (RVEs). Two different boundary conditions have been employed to simulate the deformation behavior of the alloy under uniaxial loading. Finally, the simulated stress–strain behavior of the alloy is compared with the experimental result. It is found that the microstructural morphology has a significant impact on stress and strain distribution and load carrying capacity. The eutectic phase always carries a higher load than the α(Al) phase. The globular α(Al) grains with thinner and uniformly distributed eutectic network provide a better stress and strain distribution. Owing to this, SIMA processed alloy has better stress and strain distribution than other processes. Finally, the simulated yield strength of the alloy is verified by experiment and they have great agreement.