Hydrogen solid storage: First-principles study of ZrNiH3

The ZrNiH₃ compound is a good candidate for hydrogen storage. In this work we used the first-principles calculation to study this compound. The crystal structures, the electronic properties and the optimization of the internal parameters are treated by the FP-LAPW method implanted in the WIEN2K code. The enthalpies of the dehydrogenation of the ZrNiH₃ compound are calculated. We found that the enthalpy is about −42.89 kJ/mol H, greater but similar to the experimental value of −34.3 kJ/mol H. Potential reasons for this discrepancy are discussed.     

Simulation and Experimental Studies of Illumination Effects on the Current Transport of Nitridated GaAs Schottky Diode

Semiconductors - In this paper, we studied the electrical characteristic of Schottky diodes based on gold contact on nitridated GaAs substrates. The used (100) GaAs substrate is n-type with...     

Decomposing global solar radiation into its diffuse and direct normal radiation

ABSTRACT

This work presents a model based on Radial Basis Function (RBF) to estimate the diffused solar radiation (DSR) and direct normal radiation (DNR) fractions of solar radiation from global solar radiation in a semiarid area in Algeria based on a database measured between 2013 and 2015. The data has been collected at Applied Research Unit for Renewable Energies, (URAER) at Ghardaia city situated in the south of Algeria. The experimental results show that RBF model estimates DNR and DSR with high performance. The difference between the measured and the predicted values show a normalised Root Mean Square Error (nRMSE) of 0.033 and 0.065 for DNR and DSR, respectively. The obtained values of Determination Coefficient (R²) and Correlation Coefficient (R) are: 97.3%, 98.60%, respectively for DNR and 88.89%, 91.12% For DSR.

However, the obtained results are very plausible and showed that RBF model estimates the DSR and DNR with good accuracy.     

On an independent and identically distributed mixture bilinear time‐series model

A class of nonlinear time‐series models in which the underlying process follows a finite mixture of bilinear representations is proposed. The mixture feature appears in the conditional distribution of the process which is given as a finite mixture of distributions evaluated at the normed innovations of diagonal bilinear specifications. This class is aimed at capturing special characteristics exhibited by many observed time series such as tail heaviness, multimodality, asymmetry and change in regime. Some probabilistic properties of the proposed model, namely strict and second‐order stationarity, geometric ergodicity, covariance structure, existence of higher order moments, tail behaviour and invertibility, are first studied. Parameter estimation is then performed through the EM algorithm, performance of which is shown via simulation experiments. Applications to some real‐time‐series data are proposed and through which it is shown how neglecting the mixture framework in a bilinear representation results in a loss in adequacy.     

Comparative behavior under compression of concrete columns repaired by fiber reinforced polymer (FRP) jacketing and ultra high-performance fiber reinforced concrete (UHPFRC)

This paper summarizes the experimental results from a comprehensive research program to study the fundamental stress–strain behavior of damaged concrete repaired by two techniques: increased concrete section and bonding fiber reinforced polymer (FRP). In this work, two types of FRP composite jackets were used, carbon fiber reinforced polymer (CFRP) and glass fiber reinforced polymer, and two types of concretes were used to repair the damaged concrete by increased concrete section: ordinary concrete and ultra high-performance fiber reinforced concrete (UHPFRC). Fifteen circular columns of concrete (110 × 220) cm³ were initially pre-damaged up to intense cracking, repaired by increased concrete section and by bonding FRP, and tested under uni-axial compression by loading up the damage. The impact of different design parameters, including plain concrete strength, types of composites, and type of concrete used for increasing section, was considered in this study. The strength enhancement and ductility improvement of specimens are discussed. A simple model is presented to predict the compressive strength of repaired damaged concrete columns. A significant strength and an increase in ductility were achieved, particularly when the columns were repaired by increasing section with UHPFRC and by bonding CFRP. These preliminary tests indicate that the use of UHPFRC is an effective technique for rehabilitating damaged concrete columns, highly competitive with the repaired concrete by wrapping specimens with FRP composite jackets.     

Frequency Dependent Capacitance and Conductance–Voltage Characteristics of Nitride GaAs Schottky Diode

Semiconductors - A nitride GaAs Schottky diode have been fabricated by nitridation of GaAs substrates with thickness 0.7 nm of GaN layer. The capacitance–voltage C(V) and...     

Interaction of human immunodeficiency virus type 1 envelope glycoprotein V3 loop with CCR5 and CD4 at the membrane of human primary macrophages

We show that infection of primary monocyte-derived macrophages (MDMs) and blood lymphocytes (PBLs) by human immunodeficiency virus type 1 (HIV-1) R5 strains, but not that of PBLs by X4 strain HIV-1LAI, is inhibited by beta-chemokines RANTES and MIP-1alpha. A biotinylated disulfide-bridged peptide mimicking the complete loop of clade B consensus V3 domain of gp120 (V3Cs), but not a biotinylated V3LAI peptide or a control beta-endorphin peptide of approximately the same molecular weight (MW), was found to bind specifically to MDM membrane proteins, in particular two proteins of 42 and 62 kDa migrating as sharp bands after electroblotting onto Immobilon, and this was specifically inhibited by anti-V3 antibodies. When biotinylated V3Cs was incubated with intact MDMs, which were then washed and lysed, and the resulting material was incubated with streptavidin-agarose beads and electroblotted onto Immobilon, fresh V3Cs also bound to proteins of the same molecular weight recovered in the V3Cs-interacting material. This binding was inhibited by anti-V3 antibodies, and no binding occurred with the control peptides. V3Cs also bound to soluble recombinant CD4, and CD4 monoclonal antibody Q4120 specifically recognized the V3Cs-interacting 62-kDa protein, which should thus correspond to CD4. Recombinant radiolabeled RANTES, MIP-1alpha, and MIP-1beta, but not IL-8, also bound to a 42-kDa protein on the membrane of MDMs as well as to the V3Cs-interacting 42-kDa protein, and excess unlabeled V3Cs inhibited such binding. This protein was also recognized by antibodies to CCR5, the RANTES/MIP-1alpha/MIP-1beta receptor. These data show that V3Cs binds to MDM membrane proteins that comprise CD4 and CCR5, and that multimolecular complexes involving at least gp120 V3, CD4, and CCR5 are formed on the surface of MDMs as part of V3-mediated postbinding events occurring during HIV-1 infection.     

Effect of mannosylated derivatives on HIV-1 infection of macrophages and lymphocytes

We previously demonstrated that gp120/160 (Env) of HIV-1 interact in a carbohydrate-specific manner with mannosyl/N-acetylglucosaminyl derivatives and that HIV-1LAI infection of monocytic U937 and lymphoid CEM cells was inhibited by CD4-free Concanavalin A-reactive glycopeptides from U937 cells. We report here that the natural glycoproteins bovine fetuin and asialofetuin, human orosomucoid and alpha-fetoprotein, and mannan, which all specifically interact with Env, inhibited infection of primary macrophages by macrophage-tropic HIV-1 strains, whereas dextran had no such effect. This activity was conserved if fetuin, asialofetuin, or orosomucoid were heat-treated, which rules out the role of their three-dimensional structure. Orosomucoid and mannan partially inhibited Env binding to macrophages but not to U937 or CEM cells. This indicates that Env does not bind in the same manner to primary macrophages and to immortalized CD4+ cells, and that orosomucoid and mannan act at CD4-independent stages of virus binding to macrophages. Mannan also inhibited Env binding to surface glycopeptides obtained after trypsin treatment of macrophages. Furthermore, orosomucoid and fetuin interacted with, and they inhibited the binding of a V3 loop B clade consensus peptide to several macrophage membrane proteins, including two 36 and 42 kDa proteins. These data indicate that these glycoproteins interfere with post-binding events during HIV-1 infection of primary macrophages. In contrast, the compounds did not affect infection of U937 or CEM cells by T-cell tropic HIV-1LAI nor infection of peripheral blood lymphocytes by HIV-1LAI or HIV-1(Ba-L). Thus, carbohydrate-specific inhibition of HIV infection depends on the cell type more than on the viral strain, and differences in the glycan structure of cell-type-specific cofactors may be important for HIV entry into cells.