The Einstein relation in nanostructured materials: simplified theory and suggestion for experimental determination

An attempt is made to study the Einstein relation for the diffusivity–mobility ratio (DMR) in quantum wells (QWs) and quantum well wires (QWWs) of tetragonal compounds on the basis of a newly formulated electron energy spectrum taking into account the combined influences of the anisotropies in effective electron mass, the spin–orbit splitting, and the presence of crystal field splitting, respectively. The results for quantum-confined III–V compounds form a special case of our generalized analysis. The DMR has also been studied for QWs and QWWs of II–VI and IV–VI materials. Taking QWs and QWWs of CdGeAs₂, InAs, CdS and PbSe as examples, it was found that the DMR increases with increasing carrier statistics and decreasing film thickness respectively in various oscillatory manners emphasizing the influence of dimensional quantizations and the energy band constants in different cases. An experimental method of determining the DMR in nanostructures with arbitrary dispersion laws has also been suggested and the present simplified analysis is in agreement with the suggested relationship. The well-known results for nanostructures with parabolic energy bands have also been obtained as special cases from this generalized analysis under certain limiting conditions.     

Reputation based probabilistic resource allocation for avoiding free riding and formation of common interest groups in unstructured P2P networks

Free riding is a major problem in peer-to-peer networks. Reputation management systems are generally employed to overcome this problem. In this paper, a new reputation based scheme called probabilistic resource allocation is proposed. This strategy probabilistically decide whether to provide the resource to requesting peer or not. Aforesaid method gives selection preference to higher reputation peers and at the same time provides some finite probability of interaction between those peers who don’t have good reputation about each other. This avoids disconnection between the aforesaid peers. The proposed scheme also introduces a new mechanism for resource distribution which not only allocates resources based on peers’ reputation but simultaneously maximizes network utility also. Algorithm for formation of interest groups based upon both similarity of interests and reputation between peers is also presented.     

Toepler's spark law in a GIS with compressed SF/sub 6/-N/sub 2/ mixture

This paper deals with the experimental measurements and analysis of the formative time lags to breakdown and an estimation of the Toepler's constant for gas gaps, under the application of 50 Hz AC voltage. The experiments were carried out in a 145 kV gas insulated system (GIS) bus duct with pure N/sub 2/, pure SF/sub 6/ and SF/sub 6/-N/sub 2/ mixture as insulating media. The formative time lags to breakdown in the gas gaps were measured using a fast response capacitive sensor. Toepler's spark law has been used to explain the breakdown phenomenon in the GIS and the values of Toepler's constant (k/sub t/), which gives an estimation of the formative time lags, were determined. Results show that the formative time lags vary inversely with gas pressure and the gas mixture concentrations for two gaps studied (0.46 mm and 0.61 mm). In the case of another gap (0.20 mm), the variation in the formative time lags with pressure as well as SE, concentration in the mixture has been found to be negligibly small between gas mixtures, although significant variation can be seen between pure SF/sub 6/ and pure N/sub 2/. Toepler's constant, k/sub t/, increases with gas pressure as well as SF/sub 6/ concentration in the mixture for the gaps studied. Hence, k/sub t/ is a function of the gas pressure and the concentrations of SF/sub 6/ in the gas mixture for the above-mentioned gaps.     

Separation of acid–water mixtures by pervaporation using nanoparticle filled mixed matrix copolymer membranes

BACKGROUND: Low energy and less expensive membrane based separation of acetic acid‐water mixtures would be a better alternative to conventional separation processes. However, suitable acid resistant membranes are still lacking. Thus, the objective of the present study was to develop mixed matrix membrane (MMM) which would allow high flux and water selectivity over a wide range of feed concentrations of acid in water. RESULTS: Three MMMs, namely PANBA0.5, PANBA1.5 and PANBA3 were made by emulsion copolymerization of acrylonitrile (AN) and butyl acrylate (BA) with 5.5:1 comonomer ratio and in situ incorporation of 0.5, 1.5 and 3 wt%, sodium montmorilonite (Na‐MMT) nanofillers, respectively. For a feed concentration of 99.5 wt% of acid in water the membranes show good permeation flux (2.61, 3.19, 3.97 kg m^?2 h^?1 µm^?1, for PANBA0.5, PANBA1.5 and PANBA3 membrane, respectively) and very high separation factors for water (1473, 1370, 1292 for PANBA0.5, PANBA1.5 and PANBA3 membrane, respectively) at 30 °C. Similarly for a dilute acid–water solution, i.e. for 71.6 wt% acid the membrane showed a very high thickness normalize flux (8.67, 9.44, 11.56 kg m^?2 h^?1 µm^?1, for PANBA0.5, PANBA1.5 and PANBA3 membrane, respectively) and good water selectivity (101.7, 95.3, 79 for PANBA0.5, PANBA1.5 and PANBA3 membrane, respectively) at the same feed temperature. The permeation ratio, permeability, diffusion coefficient and activation energy for permeation of the membranes were also estimated. CONCLUSION: Unlike most of the reported membranes, the present MMMs allowed high flux and selectivity over a wide range of feed concentrations. These membranes may also be effective for separating other similar organic‐water mixtures. Copyright © 2012 Society of Chemical Industry     

Synthesis and properties of click coupled graphene oxide sheets with three‐dimensional macromolecules

A facile click chemistry approach to the functionalization of three‐dimensional hyperbranched polyurethane (HPU) to graphene oxide (GO) nanosheets is presented. HPU‐functionalized GO samples of various compositions were synthesized by reacting alkyne‐functionalized HPU with azide‐functionalized GO sheets. The morphological characterization of the HPU‐functionalized GO was performed using transmission electron microscopy and its chemical characterization was carried out using Fourier transform‐infrared spectroscopy, nuclear magnetic resonance spectroscopy, and X‐ray photoelectron spectroscopy. The graphene sheet surfaces were highly functionalized, leading to improved solubility in organic solvents, and consequently, enhanced mechanical, thermal, and thermoresponsive and photothermal shape memory properties. The strategy reported herein provides a very efficient method for regulating composite properties and producing high performance materials. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43358.     

Tailored dielectric and mechanical properties of noncovalently functionalized carbon nanotube/poly(styrene‐b‐(ethylene‐co‐butylene)‐b‐styrene) nanocomposites

The preparation of high‐dielectric poly(styrene‐b‐(ethylene‐co‐butylene)‐b‐styrene) (SEBS) composites containing functionalized single‐walled carbon nanotubes (f‐SWCNTs) noncovalently appended with dibutyltindilaurate are reported herein. Transmission electron microscopy and X‐ray photoelectron and Raman spectroscopy confirmed the noncovalent functionalization of the SWCNTs. The SEBS‐f‐SWCNT composites exhibited enhanced mechanical properties as well as a stable and high dielectric constant of approximately 1000 at 1 Hz with rather low dielectric loss at 2 wt% filler content. The significantly enhanced dielectric property originates from the noncovalent functionalization of the SWCNTs that ensures good dispersion of the f‐SWCNTs in the polymer matrix. The f‐SWCNTs also acted as a reinforcing filler, thereby enhancing the mechanical properties of the composites. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013     

Polyurethane nanocomposites with click‐coupled nanodiamonds exhibiting enhanced mechanical and shape memory effects

Poly(?‐caprolactone)diol (PCL)–functionalized nanodiamonds (f‐NDs) were synthesized using a click chemistry reaction between the azide‐moiety PCL and alkyne‐moiety NDs and were incorporated into shape memory polyurethane (PU) at f‐ND concentrations of 0, 0.5, 1, and 2 wt % to produce high‐performance shape memory nanocomposites. The PU/f‐ND nanocomposites exhibited better shape recovery, shape recovery stress, and breaking stresses than pure PU. Shape recovery of greater than 95% was demonstrated for all the nanocomposites in the third cycle, and the shape recovery stresses increased significantly with the f‐ND content. These enhanced mechanical and shape recovery properties are ascribed to increased interactions between the f‐NDs and PU matrix due to incorporation of click‐coupled f‐NDs. The click‐coupled NDs can be used as nanofillers to enhance the mechanical and shape memory properties of polymers. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45465.     

Delta-opioid stimulation by BW373U86 promotes autonomic reactivity to stressors and alters attention-related cardiac responses in rabbits.

The nonpeptide δ-opioid agonist BW373U86 (3 to 300 μg/kg) was tested in rabbits for effects on heart rate, cardiac orienting and Pavlovian conditioned responses to tones, and unconditioned cardiac and somatomotor responses to signaled and unsignaled shocks. BW373U86 did not alter shock-evoked somatomotor reflexes and had few effects on the development or retention of Pavlovian conditioned heart rate discrimination. However, BW373U86 appeared to modulate cardiac conditioning indirectly, by facilitating sympathetic reflexes evoked by the signaled stressor, and the dose effect was ∪-shaped within the dose range tested. The pronounced tachycardiac effect of BW373U86 was completely blocked, or rapidly reversed, by the selective δ-opiate antagonist naltrindole. BW373U86 was more potent in increasing signaled than unsignaled shock-evoked tachycardia, suggesting release of an endogenous substance (e.g., a δ-opioid) because of the Pavlovian conditioning contingency. (PsycINFO Database Record (c) 2010 APA, all rights reserved)