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1.
Synthesis and optical transmission of MgB2 thin films on optically transparent glass are reported. In the 400–1000 nm regime as deposited films show high metallic reflectivity
and very little transmission. After deposition, the films were annealed ex situ and rendered superconducting with T
c of 38 K, approaching that of the bulk material. The reaction conditions where quite soft ∼10 min at 550°C. The optical absorption
coefficient, α and photon energy, E followed a Tauc-type behavior,
= _T (E - E_g )(\alpha E)^{1/2} = \beta _T (E - E_{\rm g} ). The band gap (E
g) was observed to peak at 2.5 eV; but, the slope parameter β
T
behaved monotonically with reaction temperature. Our results indicate that an intermediate semiconducting phase is produced
before the formation of the superconducting phase; also optical measurements provide valuable information in monitoring the
synthesis of MgB2 from its metallic constituents. In addition these films have interesting optical properties that may be integrated into optoelectronics. 相似文献
2.
Sergiu Cecoltan Izabela-Cristina Stancu Diana Maria Drăguşin Andrada Serafim Adriana Lungu Cătălin Ţucureanu Iuliana Caraş Vlad Constantin Tofan Aurora Sălăgeanu Eugeniu Vasile Romain Mallet Daniel Chappard Cristin Coman Mircea Istodorescu Horia Iovu 《Journal of materials science. Materials in medicine》2017,28(10):153
3.
Jiwon Lee Bryan S. Der Christos S. Karamitros Wenzong Li Nicholas M. Marshall Oana I. Lungu Aleksandr E. Miklos Jianqing Xu Tae Hyun Kang Chang-Han Lee Bing Tan Randall A. Hughes Sang Taek Jung Gregory C. Ippolito Jeffrey J. Gray Yan Zhang Brian Kuhlman George Georgiou Andrew D. Ellington 《American Institute of Chemical Engineers》2020,66(3):e16864
We used the molecular modeling program Rosetta to identify clusters of amino acid substitutions in antibody fragments (scFvs and scAbs) that improve global protein stability and resistance to thermal deactivation. Using this methodology, we increased the melting temperature (Tm) and resistance to heat treatment of an antibody fragment that binds to the Clostridium botulinum hemagglutinin protein (anti-HA33). Two designed antibody fragment variants with two amino acid replacement clusters, designed to stabilize local regions, were shown to have both higher Tm compared to the parental scFv and importantly to retain full antigen binding activity after 2 hr of incubation at 70°C. The crystal structure of one thermostabilized scFv variants was solved at 1.6 Å and shown to be in close agreement with the RosettaAntibody model prediction. 相似文献
4.
由于欧洲议会 96/92 EC的指示 ,欧洲正在引入供电竞争。如果供电公司能开发出有区别的电价和服务工作的一揽子规定 (以下按原文直译为费率 -服务包 )奉献给用户群 ,那么电力市场的自由化将使用户得益。新出现和快速变化的营业对供电商代表一种挑战性的新的市场机会。适用于竞争市场条件的新的费率和服务工作的快速设计提出走一条非传统的途径。供电商与用户合作开发的负荷测量工程所产生的实验性的响应费率 ,可能有助于将新的费率 -服务产物迅速推向市场。这些产物包括用于热力储存、自动发电用户所发的电力、实时定价和动态费率以及各种“绿色费率”的创新的费率 -服务包。 相似文献
5.
6.
Summary The axial diffusion of a passive scalar field (e.g. temperature) in Poiseuille flow through a duct is considered, taking account of leakage of heat through the duct boundary. The cases of the two-dimensional channel and the pipe of circular cross-section are considered in detail, and it is shown that (i) the centroid of the scalar field moves (asymptotically) with a velocity intermediate between the mean and the maximum flow rates and increases with increasing wall conductance, and (ii) the effective diffusivity in the flow direction is a decreasing function of wall conductance.The temperature field downstream of a maintained heat source is determined as a function of wall conductance. 相似文献
7.
Vlad F. Avram Imen Chamkha Eleonor sander-Frostner Johannes K. Ehinger Romulus Z. Timar Magnus J. Hansson Danina M. Muntean Eskil Elmr 《International journal of molecular sciences》2021,22(1)
Statins are the cornerstone of lipid-lowering therapy. Although generally well tolerated, statin-associated muscle symptoms (SAMS) represent the main reason for treatment discontinuation. Mitochondrial dysfunction of complex I has been implicated in the pathophysiology of SAMS. The present study proposed to assess the concentration-dependent ex vivo effects of three statins on mitochondrial respiration in viable human platelets and to investigate whether a cell-permeable prodrug of succinate (complex II substrate) can compensate for statin-induced mitochondrial dysfunction. Mitochondrial respiration was assessed by high-resolution respirometry in human platelets, acutely exposed to statins in the presence/absence of the prodrug NV118. Statins concentration-dependently inhibited mitochondrial respiration in both intact and permeabilized cells. Further, statins caused an increase in non-ATP generating oxygen consumption (uncoupling), severely limiting the OXPHOS coupling efficiency, a measure of the ATP generating capacity. Cerivastatin (commercially withdrawn due to muscle toxicity) displayed a similar inhibitory capacity compared with the widely prescribed and tolerable atorvastatin, but did not elicit direct complex I inhibition. NV118 increased succinate-supported mitochondrial oxygen consumption in atorvastatin/cerivastatin-exposed platelets leading to normalization of coupled (ATP generating) respiration. The results acquired in isolated human platelets were validated in a limited set of experiments using atorvastatin in HepG2 cells, reinforcing the generalizability of the findings. 相似文献
8.
Dongfang Hu Guodong Han Musango Lungu Zhengliang Huang Zuwei Liao Jingdai Wang Yongrong Yang 《Advanced Powder Technology》2017,28(9):2306-2316
Bubble and particle motion behaviors are investigated experimentally in a gas solid fluidized bed with liquid spray on the side wall. The particles used in the experiment are classified as Geldart B particles. The results reveal that when the fluid drag force is less than the liquid bridge force between particles, liquid distribute all over the bed. Bubble size increases as the increase of inter-particle force, then decreases owing to the increase of particle weight with increasing liquid flow rate. When the fluid drag force is greater than the liquid bridge force, liquid mainly distribute in the upper part of the bed. And it is difficult for the wet particles to form agglomerates. Bubble size decreases with increasing liquid flow rate due to the increasing of minimum fluidization velocity. Besides, the acoustic emission (AE) measurements illustrate that the liquid adhesion and evaporation on particles could enhance the particles motion intensity. Consequently, the bubble and particle behaviors change due to the variation in fluidized gas velocity and liquid flow rate should be seriously considered when attempting to successfully design and operate the side wall liquid spray gas solid fluidized bed. 相似文献
9.
P. Sfirloaga M. Poienar I. Malaescu A. Lungu C.V. Mihali P. Vlazan 《Ceramics International》2018,44(6):5823-5828
The physico-chemical properties of substituted perovskites materials have been analyzed with the aim of studying the relationships between structure and properties in this class of materials. Investigations were carried out into the effect of substitution in lanthanum manganites La1–xCaxMnO3 (x = 0; 0.05; 0.1; 0.15) materials obtained through sol-gel method followed by heat treatment at low temperatures and X-ray diffraction, into the surface area thereof, as well as into transmission electron microscopy for purposes of morpho-structural characterization. The results indicated a well-crystallized Pm-3m perovskite-type structure, and 20 nm average crystallite sizes for all samples. By means of complex impedance measurements in the 20 Hz–2 MHz frequency range, the electrical conductivity was determined at temperatures between 30 °C and 120 °C; the results showed that the conductivity obeys a Jonscher's universal law. It was found that below 10 kHz, the dc component of the conductivity increases with temperature for all samples, indicating that electrical conduction processes are activated thermally, in agreement with Mott's variable-range hopping (VRH) model; the model parameters (hopping distance and hopping energy) were also determined. In the high frequency range (f > 200 kHz) the ac conductivity is attributed to charge carriers hopping between the nearest neighboring states, in agreement with the correlated barrier hopping (CBH) model. Using this model, the energy band gap values: 0.364 eV, 0.372 eV and 0.424 eV of the substituted samples were found. 相似文献
10.
Brindusa Balanuca Raluca Stan Adriana Lungu Eugeniu Vasile 《Designed Monomers and Polymers》2017,20(1):10-17
Lately, renewable resources received great attention in the macromolecular compounds area, regarding the design of the monomers and polymers with different applications. In this study the capacity of several modified vegetable oil-based monomers to build competitive hybrid networks was investigate, taking into account thermal and mechanical behavior of the designed materials. In order to synthesize such competitive nanocomposites, the selected renewable raw material, camelina oil, was employed due to the non-toxicity and biodegradability behavior. General properties of epoxidized camelina oil-based materials were improved by loading of different types of organic-inorganic hybrid compounds – polyhedral oligomeric silsesquioxane (POSS) bearing one (POSS1Ep) or eight (POSS8Ep) epoxy rings on the cages. In order to identify the chemical changes occurring after the thermal curing reactions, FT-IR spectrometry was employed. The new synthesized nanocomposites based on epoxidized camelina oil (ECO) were characterized by dynamic mechanical analyze and thermogravimetric analyze. The morphology of the ECO-based materials was investigate by scanning electron microscopy and supplementary information regarding the presence of the POSS compounds were establish by energy dispersive X-ray analysis and X-ray photoelectron spectroscopy. The smooth materials without any separation phase indicates a well dispersion of the Si–O–Si cages within the organic matrix and the incorporation of this hybrid compounds into the ECO network demonstrates to be a well strategy to improve the thermal and mechanical properties, simultaneously. 相似文献