Fabrication of direct Z-scheme FeIn2S4/Bi2WO6 hierarchical heterostructures with enhanced photocatalytic activity for tetracycline hydrochloride photodagradation

A series of direct Z-scheme FeIn₂S₄/Bi₂WO₆ hierarchical heterostructures with intimate interface contacts were synthesized by in-situ growth route and characterized by systematical analyses. All as-prepared FeIn₂S₄/Bi₂WO₆ nanocomposites showed significantly enhanced photocatalytic activity towards photodegradation for the removal of tetracycline hydrochloride (TCH) in comparison with individual FeIn₂S₄ and Bi₂WO₆. Meanwhile, the highest photocatalytic degradation activity can be achieved by modulating adding amount of FeIn₂S₄ in FeIn₂S₄/Bi₂WO₆ nanocomposites and the optimized component ratio of FeIn₂S₄ to Bi₂WO₆ is determined to be 10 wt%. The enhanced photocatalytic activity could be ascribed to efficient separation between photogenerated holes and electrons based on the construction of direct Z-scheme system. The high photocatalytic stability of resultant 10 wt% FeIn₂S₄/Bi₂WO₆ nanocomposites was revealed through six successive recycling reactions. The main intermediate generated during TCH photodegradation was explored by HPLC-MS. Besides, the direct Z-scheme photocatalytic mechanism was confirmed by band position analysis, electron spin resonance (ESR) and active species capture experiment.     

深孔薄壁件挤压模CAD系统

介绍了利用ActiveXAutomation技术，以VB为开发工具，并采用参数化绘图研究开发的深孔薄壁件挤压模CAD系统。     

Design consideration of photocatalytic oxidation reactors using TiO2-coated foam nickels for degrading indoor gaseous formaldehyde

In the design process of the photocatalytic oxidation (PCO) reactor using TiO₂-coated foam nickels, the optimum of catalyst film thickness, light intensity and flow velocity were considered. A model was developed to study the effect of catalyst film thickness on photocatalytic degradation of formaldehyde by a TiO₂-coated foam nickel at continuous flow mode. In this model, external mass transfer and internal molecule diffusion-reaction were considered. A first-order kinetics equation was used to account for the photocatalytic reaction. Two exponential equations were employed to describe the distribution of light intensities in foam nickels and catalyst films, respectively. Validated with experimental data, the model can be used to predict the optimal thickness of catalyst films. A method for determining appropriate light intensities was proposed and discussed. The appropriate light intensity can be obtained by giving a margin, regarded as an excess coefficient, to the light intensity calculated based on the assumption of complete use of excited electron–hole pairs. The excess coefficient needs to be determined experimentally. In addition, the optimal flow velocity of PCO reactors could be consistent with the required one by changing the windward area of foam nickels. Based on the theoretical analyses, a novel PCO reactor containing 15 parallel-connected cells was designed. Each reaction cell was composed of an UV lamp and a TiO₂-coated tubular foam nickel. The performance of the reactor was tested by degrading gaseous formaldehyde at an indoor concentration level. The results showed that the reactor had low pressure loss and good degradation capability.     

IrO2-pH微电极的研制及钢筋/混凝土界面pH的测量

采用电化学阳极氧化和高温碳酸盐氧化两种方法制备 IrO2-pH微电极，其特点是对氢离子响应快、线性范围宽、机械性能好、具有长期稳定性 .考察了该电极的pH响应特性、化学成分、机械性能等.结果表明，这种IrO2-pH微电极 适用于钢筋/混凝土界面pH值的原位测量.     

汽车NVH控制橡胶减震元件行业的现状与发展

汽车的NVH(Noise,Vibration and Harshness,即噪声、振动和不平顺性)特性是汽车的五大性能指标之一(另外四个性能指标为:安全性、经济性、环保性和可靠性)。汽车的NVH控制是通过控制汽车中有关     

原位STM研究钢筋在模拟混凝土孔溶液中腐蚀和缓蚀动态行为

应用STM原位观察在不同氯离子浓度和pH值以及加入缓蚀剂前后的模拟混凝土孔溶液中的钢筋表面微观形貌．在pH=12．40的混凝土模拟孔溶液中，钢筋表面趋向均一，钝化膜的薄弱部分得到强化；在含3．5％NaCl，pH=10．40的混凝土模拟孔溶液中由于局部腐蚀的发生，可观察到不规则的沉积物的形成、生长；LD-2型复合缓蚀剂能消除腐蚀活性，促使表面微观缺陷消亡，增加钝化膜的耐蚀能力．研究结果说明，STM可在纳米尺度上观察表面形貌变化，可成为原位研究钢筋在模拟混凝土孔溶液中腐蚀和缓蚀的动态行为的重要手段．     

TWC LOGD: A portal for linked open government data ecosystems

International open government initiatives are releasing an increasing volume of raw government datasets directly to citizens via the Web. The transparency resulting from these releases not only creates new application opportunities but also imposes new burdens inherent to large-scale distributed data integration, collaborative data manipulation and transparent data consumption. The Tetherless World Constellation (TWC) at Rensselaer Polytechnic Institute (RPI) has developed the Semantic Web-based TWC LOGD portal to support the deployment of linked open government data (LOGD). The portal is both an open source infrastructure supporting linked open government data production and consumption and a vibrant community portal that educates and serves the growing international open government community of developers, data curators and end users. This paper motivates and introduces the TWC LOGD Portal and highlights innovative aspects and lessons learned.     

Reprocessing the MODIS Leaf Area Index products for land surface and climate modelling

Land surface and climate modelling requires continuous and consistent Leaf Area Index (LAI). High spatiotemporal resolution and long-time record data are more in demand nowadays and will continue to be in the future. MODIS LAI products meet these requirements to some degree. However, due to the presence of cloud and seasonal snow cover, the instrument problems and the uncertainties of retrieval algorithm, the current MODIS LAI products are spatially and temporally discontinuous and inconsistent, which limits their application in land surface and climate modelling. To improve the MODIS LAI products on a global scale, we considered the characteristics of the MODIS LAI data and made the best use of quality control (QC) information, and developed an integrated two-step method to derive the improved MODIS LAI products effectively and efficiently on a global scale. First, we used the modified temporal spatial filter (mTSF) method taking advantage of background values and QC information at each pixel to do a simple data assimilation for relatively low quality data. Then we applied the post processing-TIMESAT (A software package to analyze time-series of satellite sensor data) Savitzky-Golay (SG) filter to get the final result. We implemented the method to 10 years of the MODIS Collection 5 LAI data. In comparison with the LAI reference maps and the MODIS LAI data, our results showed that the improved MODIS LAI data are closer to the LAI reference maps in magnitude and also more continuous and consistent in both time-series and spatial domains. In addition, simple statistics were used to evaluate the differences between the MODIS LAI and the improved MODIS LAI.     

智能优化策略的比较

智能优化是从诸多新兴学科衍生出来的前沿科学，本文研究了智能优化的策略，对计算智能策略进行了分析比较，并举出了在工程实践中用这些策略进行智能优化的实例，从中得出有意义的结论。