Mesoporous Co–Mn Spinel Oxides as Efficient Catalysts for Low Temperature Propane Oxidation

Catalysis Letters - A series of mesoporous cobalt–manganese catalysts were successfully synthesized by sol–gel method as efficient catalysts for the propane oxidation. A significant...     

基于光纤技术的采空区发火监测系统的应用

基于光纤技术的采空区发火监测系统由传感器、数据传输、数据分析与控制三大部分构成,研发新一代适合煤矿安全领域应用的先进传感器、并以此为基础构建新型煤矿安全灾害监测预警系统,对于实现煤矿安全发展具有十分重要的意义。     

Bamboo biochar-catalytic degradation of lignin under microwave heating

Abstract

Lignin biochar-catalytic depolymerization using biochar Fe-600, Fe-800, Ni-600, Ni-800 catalysts under microwave-heating (180?°C for 30?min) was explored in an ethanol/formic acid (1:1) media. Non-catalyst depolymerization was also studied and compared with the biochar-catalysts results. Characteristics of the bio-char catalysts were analyze by BET, XRD, and FT-IR. GPC, FT-IR, and MALDI-TOF MS spectrometry were also used to characterize the depolymerization products. The experimental results showed that the S_BET, V_t, and V_mec and average pore diameter of the biochars are considerably dependent on the preparation temperature and type of cation (Ni²⁺ or Fe³⁺). The maximum yield of bio-oil product was obtained as 85?wt% with the addition of biochar Ni-600 and the total amount of oligomers or monomers with a molecular weight of 164 to 446 reaches 80.4%.     

MPTA型原油脱金属剂的工业应用

在对高金属含量原油进行初步评价的基础上，利用SH—Ⅰ型电脱盐试验仪对自主开发的MPTA型原油脱金属剂进行了原油脱金属的实验室研究。结果表明，当MPTA型脱金属剂加入量为250μg／g时，钙的脱除率可达97．4％，并且对其它金属元素，如镍、铁、钠、锰、铝和钒也有明显的脱除效果。该剂在山东恒源石油化工股份有限公司重交沥青车间500kt／a的电脱盐装置上进行原油脱金属工业试验的结果表明，经过二级电脱盐处理后，钙的脱除率达到99．1％，钠的脱除率为94．6％，铁的脱除率为82．9％，并可在一定程度上降低原油中镍和铜的含量。使用MPTA型原油脱金属剂显著降低了一、二级电脱盐装置的电场电流，有利于炼油厂的节能降耗。     

一种基于DSP的声学信号采集系统

传统的数据采集器多采用Inte151系列或Inte196系列的CPU，运算能力差，速度慢，精度低，尤其是浮点运算能力限制了技术指标的进一步提高。有鉴于此，各科研单位及数据采集器产家正积极开发新一代的数据采集器。如采用高性能的嵌入式芯片，或带有数字信号处理功能的芯片等。TI公司的TMS320VC33数字信号处理芯片已能支持高达150MFLOPS的运行速度，是需浮点运算的电子产品应用场合中一种较理想的微处理器件。     

自旋式脱接器在临盘油田的应用

为保障临盘采油厂的大泵井正常生产 ,购进了自旋式脱接器。这种脱接器由上体和下体两部分组成 ,上体包括轨道管和轨道套 ;下体包括接头、挡圈、弹簧、滑套和中心杆。自旋式脱接器可在任意位置和角度对接和脱开 ,对接和脱开时只需下放和上提抽油杆柱即可完成。当泵砂卡时 ,左旋抽油杆柱即可脱开 ,解决了砂卡井脱接器不能脱开的难题。该脱接器可重复对接12 0次以上 ,耐疲劳寿命 7× 10 7次以上     

Structural study of cubic pyrochlores based on quantum mechanical simulation

In the ideal A₂B₂O₆O′ pyrochlore structure, the x-value of O atom position is a variable parameter. In Bi_1.5ZnNb_1.5−xTa_xO₇ (BZNT) cubic pyrochlores, the x-values alter with the different compositions of Nb/Ta. In this work, a series of initial models for BZNT were established by analyzing X-ray diffraction data. Then three structure modifying methods, including Rietveld refinement, Rietveld refinement with energy and geometry optimization based on quantum mechanics, were employed to obtain the precise models using Materials Studio. Moreover, the reflectivities of BZNT were computed by quantum mechanical simulation based on the refined models. Comparing the simulation results from different modifying models with the experimental results, it is found that Rietveld refinement with energy optimization is the most accurate method for BZNT pyrochlores. According to the simulation results, the different reflectivities correspond well with various x-values of O atom positions in BZNT pyrochlores.     

制革用水乳型聚氨酯涂饰剂行业标准的制定

本文概述了制定该标准的背景，对标准的主要内容加以科学的阐述。     

可膨胀波纹管技术在韦15-19井的应用

可膨胀管包括可膨胀实体管和可膨胀波纹管，主要用于在不减小井眼尺寸的情况下封堵各种复杂地层，对损坏套管进行补贴修复，作为各种井筒封隔器以及延长技术套管长度。实体管和波纹管两者膨胀机理不一样，相比之下，可膨胀波纹管技术具有膨胀工艺简单，作业周期短的优点，该技术一直由俄罗斯掌握。中国石化勘探开发研究院经过多年的潜心研究，终于形成了具有自主知识产权的可膨胀波纹管产品及其配套的工艺技术，新研制的可膨胀波纹管壁厚8mm，抗内压强度35MPa，抗外挤强度10MPa，并在江苏油田韦15—19井进行了漏层封堵现场试验，经过扩眼、管串下入、水力膨胀、机械膨胀等工艺后获得圆满成功，标志着我国已经打破了国外公司对该技术的垄断，填补了国内在该领域的技术空白。