Loss modeling and thermal measurement in planar inductors-a case study

This paper covers the experimental investigation and theoretical calculation of losses in a planar inductor under load. Finite-element software is used to perform the loss calculations. Thermally controlled experiments are performed for a range of frequencies to validate the corresponding finite-element method loss calculations. The thermal dependence of the loss mechanisms is also considered.     

Type synthesis of spatial mechanisms on the basis of spatial single loop structural groupsTypensynthese räumlicher mechanismen auf der grundlage räumlicher einfach geschlossener strukturgruppen

This paper describes the basis for a new method of type synthesis of spatial mechanisms with the use of single-loop structural groups having zero degrees of freedom. Applying the binary system, the value 0 is used for R (revolute) and 1 is used for P (prismatic) pairs. The five-link spatial groups are described by codes both in the binary and decimal systems. All other groups are reduced to the basis of five-link spatial groups. In these cases two-degree-of-freedom and three-degree-of-freedom kinematic pairs are transformed to one-degree-of-freedom pairs, and these transformations are also described by codes in the binary and decimal systems. This method of coding can be programmed for digital computation and applied towards the automatic type synthesis in the design of spatial mechanisms. The system is equally clear for alphanumeric or for graphical display. To the designer it defines the diagram of the mechanism, pointing out the frame, the mobile links, the types of the kinematic pairs and their mutual disposition in the mechanism configuration.     

Electrophilic chlorination of methane over superacidic sulfated zirconia

Catalytic chlorination of methane was studied over SO ₄ ^2– /ZrO₂, Pt/SO ₄ ^2– /ZrO₂, and Fe/Mn/SO ₄ ^2– /ZrO₂ solid superacid catalysts. The reactions were carried out in a continuous flow reactor under atmospheric pressure, at temperatures below 240°C, with a gaseous hourly space velocity of 1000 ml/g h and a methane to chlorine ratio of 4 to 1. At 200°C with 30% chlorine converted the selectivity in methyl chloride exceeds 90%. At more elevated temperatures, the selectivity decreases but stays above 80% in methyl chloride at 225°C using the sulfated zirconia catalysts. The selectivity can be enhanced by adding platinum to sulfated zirconia catalysts. An iron and manganese-doped catalyst exhibited excellent selectivities at somewhat lower conversions. Methyl chloride is obtained at 235°C in selectivities greater than 85%. No chloroform or carbon tetrachloride is formed. The electrophilic insertion involves electron-deficient metal-coordinated chlorine into the methane C-H bond.Catalysis by solid superacids, 29. For part 28 see ref. [14].     

The granulomatous response in murine Schistosomiasis mansoni does not switch to Th1 in IL-4-deficient C57BL/6 mice

IL-4 plays an important role in polarizing inflammation toward a Th2 response. It remains uncertain, however, whether IL-4 also serves to prevent expression of Th1 inflammation. Therefore, using a genetically pure C57BL/6 IL-4-deficient mouse, we studied the role of IL-4 in regulating the production of IFN-gamma and Th1 inflammation in the granulomas of mice infected with Schistosoma mansoni. In contrast to normal animals, IL-4 mutant mice generated smaller liver granulomas that contained fewer eosinophils and no mast cells. Collagenase-dispersed granuloma cells were analyzed by flow cytometry and cultured in vitro to measure cytokine and Ig production. Compared with control granuloma cells, IL-4-/- cells secreted only small quantities of IL-5 and IL-10. Also, there was impaired expression of the IL-4-dependent molecules IgE and IgG1 as well as B cell surface class II and CD23. Yet the granulomas of IL-4 -/- animals produced little IFN-gamma, IgG2a, or other molecules associated with Th1 inflammation even after Ag or anti-CD3 stimulation. Splenocytes from IL-4 -/- animals stimulated with schistosome Ag also failed to produce a Th1 response. Our data show that most aspects of the Th2 response in murine schistosomiasis are highly dependent on IL-4 production. But in the absence of IL-4, neither the natural local granulomatous response to schistosome ova nor the systemic response to soluble egg Ag switches to the type 1 phenotype. Thus the production of IL-4 early in the inflammatory response is not the only factor preventing Th1 expression in inflammation.     

Identification by parameter bounds in adaptive control

Approximate solutions are suggested for receding horizon dual control to guarantee acceptable control performance of a plant with large a priori parameter uncertainties under poor excitation by the output reference and to satisfy the requirement of very fast adaptation using knowledge available on sensor and performance in industrial applications of adaptive control. the aim of the paper is to present several levels of interaction between on-line identification and control performance using parameter bounds. an interesting theorem shows that parameter bounding is a necessary part of the solution of the dual control problem. Starting from the complete separation of identification and control, various approximations are presented at different levels of optimality. Finally, the exact solution of the dual control problem is found for static gain adaptation, which implicitly involves a parameter-bounding identification procedure.     

Electrodeposition and dissolution of yttrium-hexacyanoferrate layers

The electrodeposition and dissolution of yttrium-hexacyanoferrate [YHCNFe(II)] were investigated by electrochemical quartz crystal microbalance technique (EQCM). The electrodeposition was carried out by potential cycling or stepping from solutions of Y(NO₃)₃ and K₃[Fe^III(CN)₆] of different concentrations. The ratio of the reactants was also varied. No deposition was found in dilute solutions (c < 10⁻³ mol dm⁻³). The increase of concentrations led to an intense deposition of YHCNFe(II) in the course of reduction of [Fe^III(CN)₆]³⁻. At high concentrations of the reactants a coagulation deposition of YHCNFe(III) at open-circuit has also been detected. During the reduction the first phase is the nucleation which requires saturation or oversaturation in respect to the reacting species near the gold surface. The growth phase is much faster than the formation of nuclei, and its rate depends on the concentration and the concentration ratio of the species. The composition of the deposits has been determined by total reflection X-ray fluorescence (TXRF) spectrometry. From the molar ratio of atomic constituents (K, Y and Fe) of the slightly soluble deposit (solubility: 5 × 10⁻⁵ mol dm⁻³) formed after reduction of Fe(III) a formula K_0.46Y_1.18[Fe^II(CN)₆] can be derived. This value is in good accordance with the molar mass calculated from the results of EQCM experiments which also revealed that the deposit contains ca. 2 mol H₂O/mol YHCNFe(II). The solubility of YHCNFe(III) is substantially higher (s = 2 × 10⁻³ mol dm⁻³), and according to the results of TXRF measurements, its composition is Y[Fe^III(CN)₆]. The reoxidation of YHCNFe(II) takes place in two steps. The first one is a partial oxidation which is accompanied by the desorption of K⁺ ions from the layer. During further oxidation a fast dissolution occurs due to the high solubility of YHCNFe(III).     

The ring transformations of 1,2,3,4-diepoxybutane (2,2′-bioxirane) catalysed by various aluminosilicates

The transformations of a molecule containing two adjacent epoxide rings, 2,2-bioxirane that is, were studied over various acidic aluminosilicates (HZSM-5, HY-FAU, AlMCM-41), for the first time, In the 373–473 K temperature range, in a pulse reactor, a ring-opening–ring-enlargment reaction producing furan only occured over the zeolites and it was the predominant reaction on AlMCM-41 as well. The driving force of this transformation route is water formation via elimination from 2,2-bioxirane. Suprising is the lack of the mono- or dialdehyde, the would-be products of the cleavage of the sterically more hindered C–O bonds – an acid-catalysed reaction typical for alkyl-substituted oxiranes.     

Visually Perceived Distance Judgments: Tablet-Based Augmented Reality Versus the Real World

Does visually perceived distance differ when objects are viewed in augmented reality (AR), as opposed to the real world? What are the differences? These questions are theoretically interesting, and the answers are important for the development of many tablet- and phone-based AR applications, including mobile AR navigation systems. This article presents a thorough literature review of distance judgment experimental protocols, and results from several areas of perceptual psychology. In addition to distance judgments of real and virtual objects, this section also discusses previous work in measuring the geometry of virtual picture space and considers how this work might be relevant to tablet AR. Then, the article presents the results of two experiments. In each experiment, observers bisected egocentric distances of 15 and 30 m in tablet-based AR and in the real world, in both indoor corridor and outdoor field environments. In AR, observers bisected the distances to virtual humans, while in the real world, they bisected the distances to real humans. This is the first reported research that directly compares distance judgments of real and virtual objects in a tablet AR system. Four key findings were: (1) In AR, observers expanded midpoint intervals at 15 m, but compressed midpoints at 30 m. (2) Observers were accurate in the real world. (3) The environmental setting—corridor or open field—had no effect. (4) The picture perception literature is important in understanding how distances are likely judged in tablet-based AR. Taken together, these findings suggest the depth distortions that AR application developers should expect with mobile and especially tablet-based AR.