Author Keywords: trimethylaluminium hydrolysate; stereoregular; poly(propylene oxide); fractionation; end-group analysis; cyclic oligomers 相似文献
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1.
2.
Partially stereoregular poly(propylene oxide) samples were synthesized via reactions catalysed by a preformed analytically defined trimethylaluminium hydrolysate. These samples were fractionated into two contrastingly different fractions.
1. (i) D-polymers: This fraction constituted the major part (up to 90%). It mainly contained cyclic low molecular weight oligomers (MW < 1000). The linear chains found in D-polymers had hydroxyl end groups. No double bonds could be detected spectroscopically.
2. (ii) K-polymers: This fraction was high molecular weight stereoregular polymer. Stepwise thermal precipitation from dilute isooctane solution of K-polymers yielded a succession of fractions which differed in melting point. It appears that the phase equilibria during the thermal precipitations were not controlled by the molecular weights of species.
3.
On Similarity Measures for Multimedia Database Applications 总被引:1,自引:1,他引:0
A multimedia database query consists of a set of fuzzy and boolean (or crisp) predicates, constants, variables, and conjunction,
disjunction, and negation operators. The fuzzy predicates are evaluated based on different media criteria, such as color,
shape, layout, keyword. Since media-based evaluation yields similarity values, results to such a query is defined as an ordered
set. Since many multimedia applications require partial matches, query results also include tuples which do not satisfy all
predicates. Hence, any fuzzy semantics which extends the boolean semantics of conjunction in a straight forward manner may
not be desirable for multimedia databases. In this paper, we focus on the problem of ‘given a multimedia query which consists of multiple fuzzy and crisp predicates, how to provide the user with a meaningful
overall ranking.’ More specifically, we study the problem of merging similarity values in queries with multiple fuzzy predicates. We describe
the essential multimedia retrieval semantics, compare these with the known approaches, and propose a semantics which captures
the retrieval requirements in multimedia databases.
Received 13 August 1999 / Revised 13 May 2000 / Accepted in revised form 26 July 2000 相似文献
4.
Proton Transport in Electrospun Hybrid Organic–Inorganic Membranes: An Illuminating Paradox 下载免费PDF全文
Leslie Dos Santos Manuel Maréchal Armel Guillermo Sandrine Lyonnard Simona Moldovan Ovidiu Ersen Ozlem Sel Hubert Perrot Christel Laberty‐Robert 《Advanced functional materials》2016,26(4):594-604
Chemistry and processing have to be judiciously combined to structure the membranes at various length scales to achieve efficient properties for polymer electrolyte membrane fuel cell to make it competitive for transport. Characterizing the proton transport at various length and space scales and understanding the interplays between the nanostructuration, the confinement effect, the interactions, and connectivity are consequently needed. The goal here is to study the proton transport in multiscale, electrospun hybrid membranes (EHMs) at length scales ranging from molecular to macroscopic by using complementary techniques, i.e., electrochemical impedance spectroscopy, pulsed field gradient‐NMR spectroscopy, and quasielastic neutron scattering. Highly conductive hybrid membranes (EHMs) are produced and their performances are rationalized taken into account the balances existing between local interaction driven mobility and large‐scale connectivity effects. It is found that the water diffusion coefficient can be locally decreased (2 × 10?6 cm2 s?1) due to weak interactions with the silica network, but the macroscopic diffusion coefficient is still high (9.6 × 10?6 cm2 s?1). These results highlight that EHMs have slow dynamics at the local scale without being detrimental for long‐range proton transport. This is possible through the nanostructuration of the membranes, controlled via processing and chemistry. 相似文献
5.
A dual-series-based solution is obtained for the scattering of an H-polarized plane wave from a slitted infinite circular cylinder coated with absorbing material from inside or outside. For both cases, numerical results are presented for the radar cross section and comparisons are given for two different realistic absorbing materials. The radar cross-section dependencies are also given for the aspect angle of the scatterer and the thickness of the absorbing layer 相似文献
6.
Atıcı Ramazan Sağır Selçuk Emelyanov Leonid Ya Lyashenko Mykhaylo 《Wireless Personal Communications》2021,118(4):2239-2251
Wireless Personal Communications - In the present study, the results obtained by incoherent scatter radar (ISR) and empirical models (NeQuick2 and IRI-2016) of the variations in mid-latitude... 相似文献
7.
8.
Stoica P Selén Y Sandgren N Van Huffel S 《IEEE transactions on bio-medical engineering》2004,51(9):1568-1578
We introduce the knowledge-based singular value decomposition (KNOB-SVD) method for exploiting prior knowledge in magnetic resonance (MR) spectroscopy based on the SVD of the data matrix. More specifically, we assume that the MR data are well modeled by the superposition of a given number of exponentially damped sinusoidal components and that the dampings alphakappa, frequencies omegakappa, and complex amplitudes rhokappa of some components satisfy the following relations: alphakappa = alpha (alpha = unknown), omegakappa = omega + (kappa- 1)delta (omega = unknown, delta = known), and rhokappa = Ckapparho (rho = unknown, ckappa = known real constants). The adenosine triphosphate (ATP) complex, which has one triple peak and two double peaks whose dampings, frequencies, and amplitudes may in some cases be known to satisfy the above type of relations, is used as a vehicle for describing our SVD-based method throughout the paper. By means of numerical examples, we show that our method provides more accurate parameter estimates than a commonly used general-purpose SVD-based method and a previously suggested prior knowledge-based SVD method. 相似文献
9.
V. M. Chumarev A. Ya. Dubrovskii I. P. Pazdnikov Yu. Yu. Shurygin N. I. Sel’menskikh 《Russian Metallurgy (Metally)》2008,(6):459-463
The content of metal and oxide phases that form during aluminothermic melting of a mixture of ilmenite and rutile concentrates is studied by X-ray diffraction, electron probe, and metallographic analyses. The main components of the high-grade ferrotitanium melted from the crude ore are represented by the solid solutions of oxygen and iron in titanium and the Ti4Fe2O phase, which is not reduced to TiO2. It has been shown experimentally that rich ferrotitanium (60–70% Ti) containing <5 wt % oxygen cannot be produced by the aluminothermic melting of the crude ore. 相似文献
10.
In this study, polypropylene (PP) nonwoven fabric which can be used as topsheet layer of an absorbent hygienic product was modified by natural based antibacterial agents. Antibacterial herbal agents (cinnamaldehyde, geraniol, phenylethyl alcohol) were sprayed by ethanol or applied by means of polylactic acid (PLA) and polycyclohexene oxide (PCHO) based polymers prepared by three different chemical methods. Characterization of synthesized materials was conducted via thermogravimetric analysis (TGA), differential thermal analysis (DTA), and scanning electron microscopy–energy dispersive X–ray spectroscopy (SEM-EDX). Besides characterization, antibacterial and pH buffering performances of antibacterial polymers alone and on PP fabric were tested by antibacterial and pH tests. Effects of antibacterial treatments on air permeability and absorption period of nonwoven fabrics were also analyzed. According to the results, biopolymers changed the thermal stability of PP nonwoven fabric. Antibacterial performances can be ranked as cinnamaldehyde, geraniol, and phenylethyl alcohol from the best. Besides a slight decrease about liquid absorption performance, all of the treated topsheet fabrics are sufficient for an absorbent hygienic product. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48302. 相似文献