Structured Estolides: Control of Length and Sequence

Using ester-forming reactions such as carbodiimide coupling and a modified Yamaguchi symmetrical anhydride method, a variety of estolides based on 17-hydroxy oleic and 17-hydroxy stearic acid have been prepared. These hydroxy fatty acids are produced in good yields from hydrolysis of sophorolipids, which are in turn derived from fermentation of fats and oils. Since the estolides are formed one unit, or ester bond, at a time, their length and sequence can be precisely controlled. The key to this control is the use of protecting groups at either the carboxylic or hydroxy end of the starting hydroxy fatty acids. Two mono-protected dimers, for example, when combined in a fragment-condensation approach, give a tetramer with no “contamination” from estolides of other lengths. This methodology opens the way to functionalized estolides, and several variants were prepared: hybrid estolides, containing non-fatty acid moieties such as amino acids; polymerizable estolides, containing a norbornene unit; and non-linear estolides that extend from a branched core such as glycerol or pentaerythritol. With the benzoyl chloride-mediated symmetrical anhydride method, yields for individual coupling steps ranged from 75 to 93%. Mention of trade names or commercial products in this publication is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the US Department of Agriculture.     

Civil Liabilities for Unsafe Foods in Bangladesh and Australia: A Comparative Perspective on Consumer Protection

The statutory laws concerning food safety, which allow the consumers affected by unsafe foods to claim compensation for their loss or damage in Bangladesh, are flawed in several respects. These flaws are argued to have harmful impacts on consumer protection. The ineffective legislation in the absence of application of the common law principles of negligence has left the consumers virtually helpless in securing remedies for their injuries. This article endeavors to critically examine the ambiguities and shortcomings in the Consumer Rights Protection Act 2009 (Bangladesh) looking through the prisms of the Australian Consumer Law 2010 and relevant case law from major common law jurisdictions. It discovers a number of weaknesses in the legislation of Bangladesh and provides specific suggestions for strengthening the civil liability provisions from the perspective of consumer protection by preventing their contraventions and providing adequate compensation.     

Error probability of fast frequency hopping spread spectrum withBFSK modulation in selective Rayleigh and selective Rician fadingchannels

The performance of noncoherent reception in fast frequency hopped spread-spectrum (FFH-SS) communication systems operating through noisy, fading multipath channels is investigated. Systems operating with binary frequency-shift keying (BFSK) modulation and noncoherent demodulation are examined under the assumption of very slow fading. These analyses demonstrate the frequency hopping benefits in selective channels. Expressions are derived for the bit error rate in the context of selective Rayleigh and selective Rician fading channels, as a function of channel and system parameters     

Surge characteristics of a twisted pair

We used the method of moments (MoM), which is a numerical electromagnetic field computation method, to study the surge characteristics of twisted pair single‐phase electric power lines. The results show that wires stranded with less than several turns per meter have almost the same surge characteristics as parallel lines, but the surge impedance decreases in tens of % when the number of strands increases. To verify the simulation results, we measured the surge characteristics of a model line of twisted pair experimentally, and there is good accordance between them. It is possible to simulate the surge in twisted pair covered with polymer dielectric insulators by MoM. Moreover, we studied the surge characteristics of twisted pair which is inserted into a metal tube. According to the results, the effect of the strand is smaller than that in free space without the metal pipe. There are two propagation modes in common mode: fast surge and slow surge. Few influences of the number of strands on the surge velocity occur in the fast propagation surge, but the increase of the surge impedance and the slowdown of the propagation speed are caused by twining in the slow propagation mode. © 2009 Wiley Periodicals, Inc. Electr Eng Jpn, 167(3): 1–9, 2009; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20737     

Clickable Lipids: Azido and Alkynyl Fatty Acids and Triacylglycerols

Hydroxy fatty acids (FAs), which were isolated from glycolipids that can be prepared fermentatively from fats and oils, have been synthetically modified to contain azide and alkyne functional groups. These particular functional groups were chosen because they can participate in a copper-catalyzed reaction that combines them to form a 1,4-triazole, known as a “click” reaction, which has been widely used in a variety of fields but remains underutilized in FA chemistry. Depending on the starting hydroxy FA, these groups can be close to the carboxy unit (using 3-hydroxydecanoate) and hence the polar glycerol group, or distant from it (using 17-hydroxyoctadecanoate). These structural alternatives will impart different properties to the triacylglycerols that are subsequently prepared from the modified FA. Finally, the click reaction was used to conjugate triacylglycerols to each other and to other molecules such as a glycolipid or a protected amine.     

Dynamical Comparison of Several Third-Order Iterative Methods for Nonlinear Equations

There are several ways that can be used to classify or compare iterative methods for nonlinear equations, for instance; order of convergence, informational efficiency, and efficiency index. In this work, we use another way, namely the basins of attraction of the method. The purpose of this study is to compare several iterative schemes for nonlinear equations. All the selected schemes are of the third-order of convergence and most of them have the same efficiency index. The comparison depends on the basins of attraction of the iterative techniques when applied on several polynomials of different degrees. As a comparison, we determine the CPU time (in seconds) needed by each scheme to obtain the basins of attraction, besides, we illustrate the area of convergence of these schemes by finding the number of convergent and divergent points in a selected range for all methods. Comparisons confirm the fact that basins of attraction differ for iterative methods of different orders, furthermore, they vary for iterative methods of the same order even if they have the same efficiency index. Consequently, this leads to the need for a new index that reflects the real efficiency of the iterative scheme instead of the commonly used efficiency index.     

An integrated model for optimisation of production and quality costs

Whether an industrial organisation is involved with production of new goods or engaged in reverse logistics to recycle used products, the items produced that do not meet specifications can cost the organisation in many different ways. The administrative expenses of handling returned items and the cost of reworking the items that have failed in plant quality control or returned by customers can be of concern to the manufacturers. While these are measurable costs, there are other costs such as loss of customers’ good will which are hard, if not impossible, to estimate. The model presented in this paper is aimed at optimising the measurable cost of reworking/scrapping the off-specification items as well as the cost of adjusting manufacturing processes with the aim of reducing or eliminating rejected pieces. The adjustment of process specification in relation to customer specification is a strategy that can affect production and quality cost. Consideration for optimal production specification is one of the elements of the model presented in this paper. In the proposed model, the direct cost of poor quality has been represented by a symmetrical truncated loss function. We have considered investment to adjust the mean and variance of the process. A numerical example is presented to demonstrate how the model can work in a real-world setting.     

Quality and consumer acceptability of salt and phosphate enhanced goat loin from goats fed varying levels of pine bark

Goat loins (n = 22) were evaluated to test effects of 0, 15, and 30% dietary pine bark (PB) and salt, water, and phosphate enhancement on shelf-life, shear force (WBSF) and consumer acceptability. No interactions existed between PB and enhancement. Dietary PB did not affect objective color, but enhancement increased a* and b* values (P < 0.05). Thiobarbituric acid reactive substances (TBARS) increased from d 1 to d 5 of storage (P < 0.0001), but were not affected by PB or enhancement. The WBSF for 30% PB was less than that of 0% PB (P = 0.0199), and enhancement decreased WBSF (P = 0.0010). Texture, flavor, and overall acceptability were greater (P < 0.05) for 15 and 30% PB compared to 0% PB. Enhanced loin samples had greater appearance, aroma, texture, flavor, and overall acceptability scores (P < 0.05). Results indicated that enhancement improved tenderness and consumer acceptability of goat loin, and PB had minimal impact on goat loin quality.     

2-Fatty Acrylic Acids: New Highly Derivatizable Lipophilic Platform Molecules

This paper reports the incorporation of an alpha-methylene unit into fatty acid skeletons. Since the new olefin is conjugated with the carboxylate, it is susceptible to 1,4-(Michael) additions. We have used multifunctional thiols and amines for additions at the methylene. The resulting products possess clusters of functionality grouped at one end of a hydrophobic tail. These structural patterns will be of use in the design of new types of bio-based surfactants and polymers. One particularly promising pattern of functionality that can be obtained through oxidation and reduction chemistry is a 2-fatty 1,2,3-propanetriol, or a lipophilized glycerol moiety.     

Low-Temperature Crystallization for Separating Monoacetylated Long-Chain Sophorolipids: Characterization of Their Surface-Active and Antimicrobial Properties

Pseudohyphozyma (formerly Rhodotorula) bogoriensis synthesizes long-chain-length (22-carbon chain) sophorolipids (22:0-SL) that are variously acetylated at the 6′- or/and 6″-carbons of the sophorose unit. In this paper, we describe a low-temperature crystallization protocol that preferentially separates the 6′-monoacetylated 22:0-SL (6′-Ac₁-22:0-SL) from a parental mixture of 22:0-SL containing a majority (64.7%) of the 6′,6″-diacetylated moiety (6′,6″-Ac₂-22:0-SL), as deduced from high-pressure-liquid-chromatography evaporative-light-scattering-detection (HPLC-ELSD) and LC/Q-TOF-MS analyses. Tensiometry measurements using the Wilhelmy plate method yielded minimum-surface-tension (SFT_min) and critical-micelle-concentration (CMC) values of 34.6 ± 1.0 mN m⁻¹ and 0.014 mM, respectively, for 6′-Ac₁-22:0-SL (CRYSTAL) fraction and 34.9 ± 1.0 mM m⁻¹ (SFT_min) and 0.018 (CMC) for the hexane precipitate (Hx-PRCP) fraction containing a high concentration (89.2%) of the diacetylated 6′,6″-Ac₂-22:0-SL after crystal removal. In contrast, the SFT_min and CMC of the well-studied 16-18 carbon (C_16-18)-SL of Starmerella bombicola were 35–37.2 mN m⁻¹ and 0.05-(>0.3) mM, respectively. Individually, the purified CRYSTAL and Hx-PRCP fractions exhibited a similar degree of strong growth-inhibition activity against Cutibacterium (formerly Propionibacterium) acnes as determined by an agar-plate zone of inhibition assay. Study on the growth inhibition of oral health-related bacteria, i.e., Streptococcus mutans and Lactobacillus acidophilus, showed that, depending on the bacteria and strains tested, the CRYSTAL fraction was either slightly better than or equally effective as the Hx-PRCP fraction in inhibiting cell growth.