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排序方式: 共有3717条查询结果,搜索用时 187 毫秒
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Kamalesh Pal Amitava Mukherjee Md. Motin Seikh Parthasarathi Bera Arup Gayen 《Ceramics International》2021,47(10):14798-14808
Synthesis of nanocrystalline pristine and Mn-doped calcium copper titanate quadruple perovskites, CaCu3?xMnxTi4?xMnxO12 (x = 0, 0.5, and 1.0) by modified citrate solution combustion method has been reported. Powder X-ray diffraction patterns attest the phase purity of the perovskite materials. Average particle sizes of all the materials obtained from the Scherrer's formula are in the range of 55–70 nm. The specific surface areas for all the perovskites obtained from BET isotherms are found to be low as expected for the condensed oxide systems and fall in the range of 13–17 m2 g?1. Transmission electron microscopy studies show a reduction in particle size of CaCu3Ti4O12 with increase in Mn doping. Ca and Ti are present in +2 and +4 oxidation states in all the materials as demonstrated by X-ray photoelectron spectroscopy analyses. Cu2+ gets reduced in CaCu3Ti4O12 with higher Mn content. Mn is observed to be present only in +3 oxidation state. All the materials have been examined to be active in CO oxidation as well as H2 production from methanol steam reforming. CaCu3Ti4O12 with ~14 at.% Mn is found to show best catalytic activities among these materials. A comprehensive analysis of the catalytic activities of these perovskites toward CO oxidation and H2 production from MSR reveal the cooperative activity of copper-manganese in the doped perovskites and it is more effective at lower manganese content. 相似文献
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Karishma Tiwari Pulak Sarkar Solagna Modak Harwinder Singh Sumit Kumar Pramanik Santanu Karan Amitava Das 《Advanced materials (Deerfield Beach, Fla.)》2020,32(8):1905621
Separation membranes with higher molecular weight cut-offs are needed to separate ions and small molecules from a mixed feed. The molecular sieving phenomenon can be utilized to separate smaller species with well-defined dimensions from a mixture. Here, the formation of freestanding polyimine nanofilms with thicknesses down to ≈14 nm synthesized via self-assembly of pre-synthesized imine oligomers is reported. Nanofilms are fabricated at the water–xylene interface followed by reversible condensation of polymerization according to the Pieranski theory. Polyimine nanofilm composite membranes are made via transferring the freestanding nanofilm onto ultrafiltration supports. High water permeance of 49.5 L m-2 h−1 bar−1 is achieved with a complete rejection of brilliant blue-R (BBR; molecular weight = 825 g mol−1) and no more than 10% rejection of monovalent and divalent salts. However, for a mixed feed of BBR dye and monovalent salt, the salt rejection is increased to ≈18%. Membranes are also capable of separating small dyes (e.g., methyl orange; MO; molecular weight = 327 g mol−1) from a mixed feed of BBR and MO. Considering a thickness of ≈14 nm and its separation efficiency, the present membrane has significance in separation processes. 相似文献
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Microsystem Technologies - This paper represents low power and high speed design issues of Hamming code generation and error detection circuit using complementary metal oxide semiconductor (CMOS)... 相似文献
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Sharma Rachit Kumar Sarkar Prabir Singh Harpreet 《Clean Technologies and Environmental Policy》2020,22(6):1269-1284
Clean Technologies and Environmental Policy - Manufacturing organizations are under continuous pressure to implement sustainability in their activities. There is a need to identify the... 相似文献
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Mukherjee R. Memik S. O. 《Very Large Scale Integration (VLSI) Systems, IEEE Transactions on》2006,14(11):1165-1174
Thermal effects are becoming an important factor in the design of integrated circuits due to the adverse impact of temperature on performance, reliability, leakage, and chip packaging costs. Making all phases of the design flow aware of this physical phenomenon helps in reaching faster design closure. In this paper, we present an integrated approach to thermal management in architectural synthesis. Our synthesis flow combines temperature-aware scheduling and binding based on feedback from thermal simulation. We show that our flow is effective in preventing hotspot formation and creating an even thermal profile of the resources. Our integrated thermal management technique on average reduces the peak temperature of the resources by 7.34 degC when compared to a thermal unaware flow without increasing the number of resources across our set of benchmarks 相似文献
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S. Sarkar P. Mohan Raj S. Chakraborty G. Phanikumar K. Chattopadhyay P. Dutta 《Journal of Materials Science》2003,38(1):155-164
A three dimensional, transient model is developed for studying heat transfer, fluid flow and mass transfer for the case of a single-pass laser surface alloying process. The numerical study is performed in a co-ordinate system fixed to the laser which moves with a constant scanning speed. The coupled momentum, energy and species conservation equations are solved using a finite volume technique. Phase change processes are modelled using a fixed-grid enthalpy-porosity technique, which is capable of predicting the continuously evolving solid-liquid interface. The three-dimensional model is able to predict the species concentration distribution inside the molten pool during alloying, as well as in the entire cross section of the solidified alloy. Corresponding experimental results show a good qualitative agreement with the numerical predictions with regard to pool shape and final composition distribution. 相似文献
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Summary This paper proposes the use of special sensitivities, called nodal sensitivities, as error indicators and estimators for numerical analysis in mechanics. Nodal sensitivities are defined as rates of change of response quantities with respect to nodal positions. Direct analytical differentiation is used to obtain the sensitivities, and the infinitesimal perturbations of the nodes are forced to lie along the elements. The idea proposed here can be used in conjunction with general purpose computational methods such as the Finite Element Method (FEM), the Boundary Element Method (BEM) or the Finite Difference Method (FDM); however, the BEM is the method of choice in this paper. The performance of the error indicators is evaluated through two numerical examples in linear elasticity. 相似文献