Selective Transport of Bismuth Ions through Supported Liquid Membrane

A new supported liquid membrane (SLM) system was prepared for the selective transport of bismuth ions from the aqueous feed into the aqueous permeate phase. The support of the SLM was a thin porous polypropylene or polyvinylidene fluoride membrane impregnated with diisooctyldithiophosphinic acid (Cyanex 301) as mobile carrier in 4‐chloroacetophenon as organic solvent. Cyanex 301 acts as a highly selective carrier for the uphill transport of bismuth ions through the SLM. In the presence of HNO₃ as a metal ion acceptor in the strip solution, the transport of bismuth ions into the strip side reached 70 % of the initial feed concentration after 3.5 hours. The selectivity and efficiency of bismuth transport from aqueous solutions containing different mixtures of cations were investigated. In the presence of P₂O₇^2– ions as suitable masking agent in the feed solution, the interfering effects of other cations were completely eliminated. The selective transport of bismuth through SLM is superior to liquid‐liquid extraction or through bulk liquid membranes. This is due to the high efficiency. The SLM reduces the solvent requirements, combines extraction and stripping operations in a single process and allows the use of highly selective extractants. The system may be applied to samples containing very low bismuth concentrations.     

Software reuse issues and perspectives

Software reuse could be implemented at several levels including the specification level, design level, program/subprogram library level, code level, and object-code level. However, reuse has a distinct definition for each of the above-mentioned levels. Moreover, the techniques applied to organize and manage reuse is different from one level to another. What's more, the complexity of the reuse methods and techniques increases as it moves from the specification level to the code and object-code levels. On the positive side, the time and space efficiency resulting from the application of reuse techniques improves in the same direction. Specification and design levels are at higher levels of abstraction than the other reuse levels, therefore their potential for accommodating reuse is greater and their adaptation to new applications can be simpler. However, the reuse process of the specification and design levels ultimately involves coding (be it system-generated or manual), testing, and debugging. On the other hand, reuse at code and object-code levels essentially eliminates coding and overall testing, hence it is more economical where a large collection of reusable software is organized in a software library     

PBSVM: Partitioning and biased support vector machine for vocal fold pathology assessment using labeled and unlabeled data sets

Most of the existing classification methods, used for voice pathology assessment, are built based on labeled pathological and normal voice signals. This paper studies the problem of building a classifier using labeled and unlabeled data. We propose a novel learning technique, called Partitioning and Biased Support Vector Machine Classification (PBSVM), which tries to utilize all the available data in two steps: (1) a new heuristically partition-based algorithm, which extracts high quality pathological and normal samples from an unlabeled set, and (2) a more principle approach based on biased formulation of support vector machine, which is fairly robust to mislabeling and unbalance data problem. Experiments with wavelet-based energy features extracted from sustained vowels show that the new recognition scheme is highly feasible and significantly outperform the baseline classical SVM classifier, especially in the situation where the labeled training data is small.     

Research trends in gender differences in higher education and science: a co-word analysis

The aim of this study is to map and analyze the structure and evolution of the scientific literature on gender differences in higher education and science, focusing on factors related to differences between 1991 and 2012. Co-word analysis was applied to identify the main concepts addressed in this research field. Hierarchical cluster analysis was used to cluster the keywords and a strategic diagram was created to analyze trends. The data set comprised a corpus containing 652 articles and reviews published between 1991 and 2012, extracted from the Thomson Reuters Web of Science database. In order to see how the results changed over time, documents were grouped into three different periods: 1991–2001, 2002–2007, and 2008–2012. The results showed that the number of themes has increased significantly over the years and that gender differences in higher education and science have been considered by specific research disciplines, suggesting important research-field-specific variations. Overall, the study helps to identify the major research topics in this domain, as well as highlighting issues to be addressed or strengthened in further work.     

Experimental Investigation on the Removal of p-Toluic Acid from Aqueous Solution using Functionalized Polymeric Sorbent

Polystyrene-divinylbenzene copolymer (PsDVB) was covalently functionalized with monoethanolamine (MEA), diethanolamine (DEA), and triethanolamine (TEA) by a simple method. The functionalized sorbents were characterized in terms of functionality and morphology, and used for the removal of p-toluic acid (p-TA) from aqueous solution. It was found that DEA-PsDVB has higher adsorption capacity than MEA- and TEA-PsDVB due to more accessible nitro and hydroxyl groups on its surface. Further investigation on the adsorptive properties of DEA-PsDVB indicated that the maximum uptake of p-TA occurred at the optimum pH of 5.3. The kinetics data was successfully represented by the pseudo-first-order model, and the behavior of the adsorption isotherms followed the Freundlich model well. Thermodynamic studies showed that the adsorption of p-TA onto DEA-PsDVB was an endothermic and spontaneous process along with the positive change in entropy. The regeneration of DEA-PsDVB was performed with 0.1 M NaOH solution, and results showed that 99% of the initial capacity was conserved after eight successive adsorption/regeneration cycles.     

Two-parameter TSCSP method for solving complex symmetric system of linear equations

We introduce a two-parameter version of the two-step scale-splitting iteration method, called TTSCSP, for solving a broad class of complex symmetric system of linear equations. We present some conditions for the convergence of the method. An upper bound for the spectral radius of the method is presented and optimal parameters which minimize this bound are given. Inexact version of the TTSCSP iteration method (ITTSCSP) is also presented. Some numerical experiments are reported to verify the effectiveness of the TTSCSP iteration method and the numerical results are compared with those of the TSCSP, the SCSP and the PMHSS iteration methods. Numerical comparison of the ITTSCSP method with the inexact version of TSCSP, SCSP and PMHSS are presented. We also compare the numerical results of the BiCGSTAB method in conjunction with the TTSCSP and the ILU preconditioners.     

Immobilization of palladium on benzimidazole functionalized mesoporous silica nanoparticles: catalytic efficacy in Suzuki–Miyaura reaction and nitroarenes reduction

Journal of Porous Materials - Benzimidazole functionalized mesoporous silica nanoparticles immobilized Pd(0)/Pd(II) has been proposed as an efficient catalyst for the one-pot preparation of biaryls...     

Contact dynamic modeling of a liquid droplet between two approaching porous materials

A computational fluid dynamics model based on a finite difference solution to mass and momentum conservation equations (Navier–Stokes equations) for a liquid droplet transport between two porous or nonporous contacting surfaces (CSs) is developed. The CS dynamic (equation of motion) and the spread of the incompressible liquid available on the primary surface for transfer are coupled with the Navier–Stokes equations. The topologies of the spread dynamic between and inside both surfaces (primary and CSs) are compared with experimental data. The amount of mass being transferred into the CS, predicted by the model, is also compared to the experimental measurements. The impact of the initial velocity on the spread topology and mass transfer into the pores is addressed. © 2014 American Institute of Chemical Engineers AIChE J, 60: 2346–2353, 2014     

The Acute Toxicity of SiO2 and Fe3O4 Nano-particles on Daphnia magna

Silicon - SiO2 nano-particles are applied in different industries such as ceramic producing, glass making, cosmetic products, medicines, magnetic mixtures, heat and electric insulators and glazing...