Diffusional behavior of multi-arm star polymers by H pulsed field gradient spin-echo NMR method

The diffusional behavior of multi-arm star-shaped p(tBMA) was investigated in a concentration range from dilute to semidilute region with ¹H pulsed field gradient spin-echo NMR (PFGSE-NMR). An 142-arm star-shaped p(tBMA) showed two diffusional mode, which reflected the coexistence of liquid ordering phase and liquid phase near the ordering transition. On the other hand, for star-shaped p(tBMA) with 55 arms showed a single diffusional relaxation in all concentration ranges during observation time. In the semidilute region, the relationship between the diffusion coefficient against the polymer concentration was affected strongly not only the arm number but also liquid ordering structure.     

Synthesis of polyethylene oxide end‐capped with perfluoroalkyl groups/polystyrene prototype brushes

Polystyrene (PS)/poly(ethylene oxide) (PEO) prototype brushes were prepared by alternating free‐radical copolymerization of methacryloyl‐terminated PS and α‐vinylbenzyl‐ω‐hydroxy or α‐vinylbenzyl‐ω‐perfluoroalkyl (R_f) PEO macromonomers with the addition of Lewis acid (SnCl₄). It was found from their dilute‐solution properties that PS/PEO end‐capped with R_f (PBR_f), and PS/PEO having OH groups at terminal ends (PBOH) prototype brushes formed a single molecule in benzene and aggregates in chloroform, respectively. However, the brush PBOH formed a single molecule in N,N‐dimethylformamide. Such aggregation behaviors seemed to be caused by the interaction between hydroxy groups of PEO chain ends. The brush PBOH was also converted into PBR_f‐type brush by chemical modification, using corresponding acid chloride. The substitution of R_f groups was ～70% due to slipping of terminal hydroxy groups into PEO internal domains. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 772–778, 2006     

A super-dynamic flip-flop circuit for broad-band applications up to24 Gb/s utilizing production-level 0.2-μm GaAs MESFETs

This paper describes a novel dynamic flip-flop (FF) circuit that can operate 30% faster than conventional clocked inverter-type FFs. A new wideband clock buffer is introduced to cover the FF operation range. An 8- to 24-Gb/s decision circuit and a 9- to 26-GHz 1/2 frequency divider were developed utilizing production-level 0.2-μm GaAs MESFET technology     

NRZ operation at 40 Gb/s of a compact module containing an MQW electroabsorption modulator integrated with a DFB laser

NRZ operation at 40 Gb/s has been successfully performed using a very compact module of a multiple-quantum-well (MQW) electroabsorption modulator integrated with a distributed-feedback (DFB) laser. While the DFB laser is injected with a constant current, the integrated MQW electroabsorption modulator is driven with a 10-Gb/s electrical NRZ signal. A clearly opened eye diagram has been observed in the modulated light from the modulator. And a receiver sensitivity of -27.2 dBm at 10/sup -9/ has been experimentally confirmed in the bit-error-rate (BER) performance.     

Analysis and application of a novel model for estimating powerdissipation of optical interconnections as a function of transmissionbit error rate

This paper proposes a novel model for estimating power dissipation of optical/electrical interconnections as a function of transmission bit error rate. This model is applied to a simplified optoelectronic transmitter and receiver configuration in which a photodetector is directly connected to the decision circuit. It is analytically verified that this configuration can achieve error-free operation with low power under practical operating conditions. A comparison between optical and electrical interconnections based on this simplified configuration is performed. This result shows the interconnection length and bit rate at which optical interconnection is superior in terms of power dissipation to electrical interconnection, Only optical interconnections achieve error-free operation with 40 mW power dissipation at a transmission bit rate of 10 Gb/s and an interconnection length over 7 m     

Polymer structure formed in radiation-induced graft polymerization

Methacrylic acid (MAA) and methyl methacrylate (MMA) were grafted onto nylon 6, cellulose triacetate, cotton, viscose rayon, and polyester fibers, and the stereoregularities of the grafted polymers were determined. The graft polymerization was carried out with preirradiation techniques using γ-rays from a Co 60 source. The grafted copolymers were then separated from the homopolymers by Soxhlet extraction. The grafted (branch) polymers were isolated from the trunk polymers by acid hydrolysis and their stereoregularity was determined with a 100 MHz NMR spectrometer. The stereo-regularity of PMAA or PMMA grafted onto viscose rayon or cotton fiber was different from that of the polymers formed in ordinary radical polymerization.     

An 80-Gb/s optoelectronic delayed flip-flop IC using resonanttunneling diodes and uni-traveling-carrier photodiode

This paper describes an 80-Gb/s optoelectronic delayed flip-flop (D-FF) IC that uses resonant tunneling diodes (RTDs) and a uni-traveling-carrier photodiode (UTC-PD). A circuit design that considers the AC currents passing through RTDs and UTC-PD is key to boosting circuit operation speed. A monolithically fabricated IC operated at 80 Gb/s with a low power dissipation of 7.68 mW. The operation speed of 80 Gb/s is the highest among all reported flip-flops. To clarify the maximum operation speed, we analyze the factors limiting circuit speed. Although the bandwidth of UTC-PD limits the maximum speed of operation to 80 Gb/s at present, the circuit has the potential to offer 100-Gb/s-class operation     

Seasonal development of Leptotrombidium akamushi (Acari: Trombiculidae) under field temperatures

Engorged larvae of Leptotrombidium akamushi (Brumpt), a vector of scrub typhus, were reared in small plastic containers placed on the ground and fed fresh eggs of the collembolan Sinella curviseta Brook. Engorged larvae obtained in October developed into deutonymphs through protonymphs approximately 1 mo before winter and became dormant in the cold winter season (approximately 3 mo). Most deutonymphs developed into tritonymphs in April and adults in May. Females began laying eggs in mid-June and the numbers of unfed larvae showed a peak in August. The mites reared from July rapidly developed into adults by August, and laid eggs in September. Larvae were most abundant in October, and adults became dormant in the winter. The same adults laid eggs from early May to late June and, upon hatching, the larval population peaked in early July of the 2nd summer. Most larvae died before the 2nd winter. Eggs hatched approximately 3 wk after oviposition and longevity of unfed larvae was 2 mo. Because of this very short incubation period, L. akamushi larvae occur in the summer, whereas L. pallidum Nagayo, Miyagawa, Mitamura & Tamiya, and L. scutellare Nagayo, Miyagawa, Mitamura, Tamiya & Tenjin occur in the autumn, although 3 species lay eggs from May to August.