Synthesis of new hyperbranched urethane-acrylates and their evaluation in UV-curable coatings

Three series of hyperbranched urethane-acrylates (HB-UA), based on aliphatic hyperbranched polyesters and polyethyleneglycol acrylate, were prepared and evaluated for use in UV-curable coatings. UV-curing kinetics were monitored by FT-IR spectroscopy. The thermal and mechanical properties of UV-cured HB-UA were investigated by means of differential scanning calorimetry (DSC) and dynamic mechanical analysis (DMA) and correlated to the mechanical properties of coatings (hardness and flexibility). These new HB-UA's are very reactive and did not show oxygen inhibition. Obtained coatings have good mechanical properties and solvent resistance.     

Triple-product optical processor for analysis of pulse-repetition and carrier frequencies of radar signals

A triple-product acousto-optic processor output was studied analytically and numerically. The processor is capable of detecting the carrier frequency and the modulation envelope of a signal.     

Rheological properties of hydroxyl‐terminated and end‐capped aliphatic hyperbranched polyesters

The rheological behavior of two series of aliphatic hyperbranched (HB) polyesters, based on 2,2‐bis(hydroxymethyl)propionic acid (bis‐MPA) and di‐trimethylol propane (Di‐TMP) as a tetrafunctional core, was studied. The effect of the size (pseudo‐generation number, from second to eight) and structure on the melt rheological properties was investigated for a series of hydroxyl‐terminated HB polyesters. In addition, the influence of the nature and degree of modification of the terminal OH groups in a series of fourth‐generation polyesters end‐capped with short and long alkyl chains and some aryl groups on the rheological properties was analyzed. The time–temperature superposition procedure was applied for the construction of master curves and for the analysis of the rheological properties of HB polyesters. The data obtained from WLF analysis of the HB polyesters showed that the values of the thermal coefficient of expansion of free volume α_f and the fractional free volume at the glass transition temperature, f_g, increase with increasing size of the HB polyesters. It was shown that the modified HB polyesters exhibited lower T_g and T_G′=G″ temperatures, above which viscous became dominant over elastic behavior. From an analysis of the master curves of the modified HB polyesters, it was observed that with increasing degree of modification, both storage and loss modules and complex dynamic viscosity and apparent energy for viscoelastic relaxation decrease, because of reduced intermolecular hydrogen interactions. They do not exhibit a plateau of rubbery behavior, which confirms that no entanglements are present and that the molar masses are below the critical molar mass. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41479.     

A study on the Co-W activated Ni electrodes for the hydrogen production from alkaline water electrolysis - Energy saving

Hydrogen is considered to be the most promising candidate as a future energy carrier. One of the most used technologies for the electrolytic hydrogen production is alkaline water electrolysis. However, due to high energy requirements of about 4.5-5 kWh/Nm³ H₂ in most industrial electrolysers, the cost of hydrogen produced in such a way is high. There are various attempts to overcome this problem, like zero-gap cell geometry, development of new diaphragm materials, development of new electrocatalytic materials for electrodes, etc.In continuous search to improve this process using advanced electrocatalytic materials for the hydrogen evolution reaction (HER), based on transition metal series, catalyst based of cobalt and wolfram was investigated as cathode material. On the basis of the results of our experiments, there is a strong indication that the Co-W catalyst reduces energy needs per mass unit of hydrogen produced for more than 20% in some cases. Objective of this work was to investigate the electrocatalytic efficiency using quasi-potentiostatic, galvanostatic and impedance spectroscopy techniques. Results are presented to show the Tafel slopes, the exchange current densities, the apparent energy of activation, the apparent electrochemical surface and the stability of Co-W catalyst. Results suggest to significant catalytic performance not only from the increase of the real surface area of electrodes, but also from the true catalytic effect of the Co-W catalyst.     

Computation of high-frequency and time characteristics of corona noise on HV power line

This work presents an algorithm for the computation of frequency and time characteristics of the corona noise in power-line carrier communications. In the frequency domain, the corona noise is represented with a power spectral density and with a Gaussian noise voltage with variable root mean square value in the time domain. Simulations results are compared with measurements on an actual 400-kV power line.     

Electrocatalytic activation of Ni electrode for hydrogen production by electrodeposition of Co and V species

Hydrogen is considered to be the most promising candidate as a future energy carrier. One of the most used technologies for the electrolytic hydrogen production is alkaline water electrolysis. Electrode materials used in alkaline water electrolysis are mainly made from Ni or Ni-based alloys due to their desirable mechanical and chemical stability in hot and alkaline solution. Considerable research effort has been conducted on enhancement of electrocatalytic activity of Ni electrodes.     

Design of Adaptive Multimode RF Front-End Circuits

Migration towards higher data rates and higher capacities for multimedia applications, and provision of various services (text, audio, video) from different wireless standards with the same device require integrated designs that work across multiple standards, can easily be reused, and achieve maximum hardware share at minimum power consumption. This can be achieved by using adaptive circuits that are able to trade off power consumption for performance. The design of an adaptive multimode image-reject downconverter (oscillator and two mixers) is presented in this paper. In the highest performance mode, the image-reject downconverter (the quadrature mixers) has an IIP3 of +5.5 dBm, a single-side band noise figure of 13.9dB and a conversion gain of 1.4 dB, while drawing 10mA from a 3 V supply. The adaptive oscillator achieves -123 dBc/Hz phase noise at 1MHz offset from a 2.1 GHz carrier with a bias current of 6 mA in the highest performance mode. Adaptivity in the downconverter is achieved by trading off RF performance for current consumption, ranging from 10 mA for the relaxed mode (e.g., DECT) to 20 mA in the highest performance mode (e.g., DCS1800) of operation     

Raising efficiency of hydrogen generation from alkaline water electrolysis – Energy saving

This paper presents an attempt to make the alkaline electrolytic production of hydrogen more efficient by adding in situ activating compounds in ionic and complex form. Cobalt and tungsten based ionic activators (i.a.), added directly into the electrolyte during the electrolytic process, reduce energy requirements per mass unit of hydrogen produced for about 15%, compared to non-activated system, for a number of current densities in a wide temperature range. Energy saving is higher at higher temperatures and on higher current densities. Structural and morphological characteristic of deposit formed on the cathode during the electrolytic process reveal very interesting and unique pattern with highly developed surface area and uniform distribution of the pores. Obtained deposit also exhibit a long term stability.     

Design of multistandard adaptive voltage-controlled oscillators

A multistandard/multiband adaptive voltage-controlled oscillator (VCO) satisfying the phase-noise requirements of both second- and third-generation wireless standards is described in this paper (1.8-GHz DCS1800, 2.1-GHz wide-band code division multiple access, and 2.4-GHz wireless local area network, Bluetooth, and digital enhanced cordless telecommunications standards). The design procedure for the VCO is based on an adaptive phase-noise model. A factor of 12 reduction in power consumption with a phase-noise tuning range of 20 dB is demonstrated by adapting the VCO bias to the desired application. The VCO achieves -123-, -110-, and -103-dBc/Hz phase noise at 1-MHz offset in a 2.1-GHz band at supply currents of 6, 1.2, and 0.5 mA, respectively