On principal component analysis, cosine and Euclidean measures in information retrieval

Clustering groups document objects represented as vectors. An extensive vector space may cause obstacles to applying these methods. Therefore, the vector space was reduced with principal component analysis (PCA). The conventional cosine measure is not the only choice with PCA, which involves the mean-correction of data. Since mean-correction changes the location of the origin, the angles between the document vectors also change. To avoid this, we used a connection between the cosine measure and the Euclidean distance in association with PCA, and grounded searching on the latter. We applied the single and complete linkage and Ward clustering to Finnish documents utilizing their relevance assessment as a new feature. After the normalization of the data PCA was run and relevant documents were clustered.     

Browsing the information highway while driving: three in-vehicle touch screen scrolling methods and driver distraction

Distraction effects of three alternative touch screen scrolling methods for searching music tracks on a mobile device were studied in a driving simulation experiment with 24 participants. Page-by-page scrolling methods with Buttons or Swipe that better facilitate resumption of visual search following interruptions were expected to lead to more consistent in-vehicle glance durations and thus on less severe distraction effects than Kinetic scrolling. As predicted, Kinetic scrolling induced decreased visual sampling efficiency and increased visual load compared with Swipe, increased experienced workload compared with both Buttons and Swipe, as well as decreased lane-keeping accuracy compared with baseline. However, Buttons did not significantly excel Kinetic with any metric but on subjective ratings. Based on the results, we do not recommend the use of kinetic scrolling with in-vehicle touch screen displays in the manner used in the experiment. Instead, page-by-page swiping seems to suit significantly better for in-vehicle displays due to its systematic nature and low levels of pointing accuracy required for scrolling the pages.     

Phenolic Composition and Antioxidant Capacity of Bilberry (<Emphasis Type="Italic">Vaccinium myrtillus</Emphasis>) Leaves in Northern Europe Following Foliar Development and Along Environmental Gradients

Bilberry is a characteristic field layer species in the boreal forests and is an important forage plant for herbivores of the North European ecosystem. Bilberry leaves contain high levels of phenolic compounds, especially hydroxycinnamic acids, flavonols, catechins, and proanthocyanidins. We investigated the phenolic composition of bilberry leaves in two studies, one following foliar development in forest and open areas, and the other along a wide geographical gradient from south to north boreal forests in Finland. An analysis of bilberry leaves collected in open and forest areas showed that major phenolic changes appeared in the first stages of leaf development, but, most importantly, synthesis and accumulation of flavonoids was delayed in the forest compared to the high light sites. Sampling along a geographical gradient in the boreal zone indicated that leaves from higher latitudes and higher altitudes had greater soluble phenolic and flavonol levels, higher antioxidant capacity, and lower contents of chlorogenic acid derivatives. The ecological significance of the results is discussed.     

Structure formation mechanisms in consolidating pigment coatings—Simulation and visualisation

Microstructure development in consolidating pigment coating layers was studied in terms of particle flocculation and clustering mechanisms utilising a 3D particle dynamics model. The model includes hydrodynamic forces, colloidal interactions as well as the Brownian motion. The influence of colloidal interactions and drying strategy on the coating layer thickness development and internal solid concentration gradients, was investigated. A low particle surface potential resulted in the formation of porous particle networks, which impeded the shrinkage of the coating layer. At higher surface potentials particles arranged into denser structures, whereby the solids concentration profile could be controlled by the drying. Low electrostatic double layer thicknesses allowed sharp concentration gradients to form as result of the applied drying strategy. At high double layer thicknesses, the structure formation was similar regardless of drying strategy. This work elucidates the combined effect of drying conditions and colloidal suspension properties on coating microstructure development. Furthermore, the results aid in the understanding of how coating suspension additives may influence the structure development of the coating layer.     

Characterization of polyesters prepared from three different phthalic acid isomers by CID-ESI-FT-ICR and PSD-MALDI-TOF mass spectrometry

Polyesters prepared from the same diol, 2-butyl-2-ethyl-1,3-propanediol, but different phthalic acid isomers, phthalic, isophthalic, and terephthalic acid, were characterized by collision-induced dissociation electrospray ionization Fourier transform ion cyclotron resonance (CID-ESI-FT-ICR) and postsource-decay matrix-assisted laser desorption/ionization time-of-flight (PSD-MALDI-TOF) mass spectrometry. Sodiated dihydroxyl-terminated polyester oligomers containing five repeating units at m/z 1634 were selected as precursor ions for dissociation studies. Two main mechanisms occurred in the fragmentation of all of the polyesters, since dissociation of the oligomers was initiated by hydrogen rearrangement or transesterification reactions. Polyesters prepared from different phthalic acid isomers could be distinguished by their fragmentation behavior. Polyester prepared from phthalic acid was easily identified by using both CID-ESI-FT-ICR and PSD-MALDI-TOF mass spectrometry. However, distinguishing between the polyesters prepared from isophthalic and terephthalic acid succeeded marginally only with CID-ESI-FT-ICR mass spectrometry. Molecular dynamics calculations were used to obtain an idea of the fragmentation behavior of the polyesters. The low-energy structures of the precursor ions were determined, and the coordination of the oxygen atoms of the polyester oligomers to the sodium cation was examined more closely. Both the experimental and the theoretical studies showed that the sodium ion affinity of polyester changed with the phthalic acid isomer.     

Fixation of distal femoral osteotomies with self-reinforced poly(L/DL)lactide 70 : 30/bioactive glass composite rods. An experimental study on rats

Self-reinforced poly(L/DL)lactide 70:30/bioactive glass [SR-P(L/DL)LA/bioactive glass] composite rods, 2 mm in diameter and 36 mm in length, were implanted into the dorsal subcutaneous tissue of 16 rats. Osteotomies of the distal femur were fixed with these rods (2 x 15 mm) in 64 other rats. The follow-up times varied from one week to one year. After sacrifice, three-point bending and shear tests, and molecular weight measurements were performed for subcutaneously placed rods. Radiological, histological, histomorphometrical, microradiographic, and oxytetracycline-fluorescence studies of the osteotomized and intact control femora were performed. At 24 weeks the mechanical properties had decreased significantly. Thirty-nine osteotomies healed uneventfully. One of the 64 evaluated osteotomies showed signs of infection at six weeks, and there were 19 non-unions and six delayed unions. In 20 operations the fixation was loose and out of these 14 non-unions were observed. No gross signs of inflammatory or foreign-body reactions were observed. The present investigation showed that the mechanical strength and fixation properties of SR-P(L/DL)LA/bioactive glass composite rods are suitable for fixation of cancellous bone osteotomies in rats as long as the operative technique is correct. The present article is the first report on the application of SR-P(L/DL)LA/bioactive glass composite rods for fixation of cancellous bone osteotomies.     

Processing characteristics of tin and tungsten oxides relevant to production of gas sensors

Tungsten trioxide and two types of tin dioxide were compacted at different pressures and then sintered at different temperatures in order to study how the microstructure formed is dependent on these parameters. The structures were studied using dilatometric and porosimetric techniques and also using electron microscopy. X-ray diffraction was used to ascertain the completeness of the decomposition reaction of SnSO₄ being converted to SnO₂. Tin dioxide, which was prepared from tin sulphate by calcining, was characterised by a large specific surface area. For all three materials studied the mean pore size was found to increase and the specific surface area was found to decrease with increasing sintering temperature. In the case of WO₃ the total pore volume decreased markedly as the sintering temperature was increased from 900 to 1000° C. However, in the case of SnO₂, the total pore volume remained almost constant in the sintering temperature range of 600 to 1500° C. In the case of SnO₂ derived from SnSO₄ the sintered density was about 45% of the theoretical value while for the conventionally made SnO₂ the sintered density was about 55% of the theoretical value. The sintered density of WO₃ was found to show a marked increase, from 55% to 70% of the theoretical value, as the sintering temperature was raised from 1000 to 1100° C.     

Direct synthesis of carbon nanofibers on the surface of copper powder

A novel approach to synthesize carbon nanofibers (CNFs) directly on the surface of metal μm-sized particles to evenly disperse the carbon nanomaterials in a composite material was proposed. As a metal matrix, 5–10 μm copper particles were utilized. As a carbon source, C₂H₂, CH₄ and CO were examined. The best conditions were found to be in C₂H₂ (30 cm³/min) and H₂ (260 cm³/min) atmosphere at the temperature of 750 °C. The composites based on copper and CNFs prepared by vacuum hot pressing showed the increase in hardness from 35 to 60 kg/mm² almost retaining pure copper electrical properties.     

Electrical capacitance tomography as a monitoring tool for high-shear mixing and granulation

Electrical capacitance tomography (ECT) was utilized for monitoring of high-shear mixing and high-shear granulation processes. A finite element method (FEM)-based reconstruction algorithm was utilized to take into account the specific geometrical characteristics of the experimental set-up. Two-dimensional ECT tomograms, mixing index curves and permittivity fractions were computed based on the measurements, and their suitability in the analysis of the processes was assessed. It was found that the different mixing processes and the different granulation processes could be analyzed based on these quantities.