Development and characterization of silicone/phosphorus modified epoxy materials and their application as anticorrosion and antifouling coatings

Epoxy resin is chosen for our present study owing to its exceptional combination of properties such as easy processing, high safety, excellent solvent and chemical resistance, toughness, low shrinkage on cure, good electrical, mechanical and corrosion resistance with excellent adhesion to many substrates. This versatility in formulation made epoxy resins widely applied for surface coatings, adhesives, laminates, composites, potting, painting materials, encapsulant for semiconductor and insulating material for electric devices. There are numerous paint/coating systems based on epoxy resin available for corrosion and fouling prevention. They however are not completely satisfactory in field applications, where high corrosion, fouling and flame resistance are required. The demand for epoxy resin as corrosion/fouling resistant coatings is restricted mainly due to its inferior characteristics like poor impact strength, high rigidity, and moisture absorbing nature besides inadequate flame retardant properties. It is for this reason that silicones and phosphorus-based compounds are used as modifier in this work by intercrosslinking network mechanism (ICN) to obtain epoxy resin with desired properties ideally suitable for field applications for preventing corrosion and fouling with flame retardantancy. The present work involves the development of solvent free silicone/phosphorus modified epoxy coating systems, since solvent free coating systems are widely used for numerous applications due to their lower cost per unit film thickness, freedom from fire and pollution hazard and ability to provide better performance. For the development of coating systems, epoxy resin (X) serves as base material, hydroxyl terminated polydimethylsiloxane (HTPDMS) as modifier, γ-aminopropyltriethoxysilane (γ-APS) as crosslinking agent and dibutyltindilaurate (DBTDL) as catalyst. Polyamidoamine (A), aromatic amine adducts (B) and phosphorus-containing diamine (C) were used as curing agents. The study also describes the evaluation of corrosion resistant behaviour of unmodified epoxy and siliconized epoxy coatings by potentiodynamic polarization method, electrochemical impedance spectroscopy (EIS), salt-spray and antifouling tests. The results are discussed.     

Studies on mechanical,thermal, and morphology of diglycidylether‐terminated polydimethylsiloxane‐modified epoxy–bismaleimide matrices

An epoxy matrix system modified by diglycidylether‐terminated polydimethylsiloxane (DGETPDMS) and bismaleimide (BMI) was developed. Epoxy systems modified with 4, 8, and 12% (by wt) of DGETPDMS were made using epoxy resin and DGETPDMS, with diaminodiphenylmethane as the curing agent. The DGETPDMS‐toughened epoxy systems were further modified with 4, 8, and 12% (by wt) of BMI, namely (N,N′‐bismaleimido‐4,4′‐diphenylmethane). DGETPDMS/BMI/epoxy matrices were characterized using differential scanning calorimetry, thermogravimetric analysis, and heat deflection temperature analysis. The matrices, in the form of castings, were characterized for their mechanical properties, viz. tensile strength, flexural strength, and impact test, as per ASTM methods. Mechanical studies indicate that the introduction of DGETPDMS into epoxy resin improves the impact strength, with reduction in tensile strength, flexural strength, and glass transition temperature, whereas the incorporation of BMI into epoxy resin enhances the mechanical and thermal properties according to its percentage content. However, the introduction of both DGETPDMS and BMI enhances the values of thermomechanical properties according to their percentage content. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 668–674, 2006     

Techniques to tackle state explosion in global predicate detection

Global predicate detection, which is an important problem in testing and debugging distributed programs, is very hard due to the combinatorial explosion of the global state space. The paper presents several techniques to tackle the state explosion problem in detecting whether an arbitrary predicate Φ is true at some consistent global state of a distributed system. We present space efficient online algorithms for detecting Φ. We then improve the performance of our algorithms, both in space and time, by increasing the granularity of the execution step from an event to a sequence of events in each process     

Benchmarking advanced architecture computers

Recently, a number of advanced architecture machines have become commercially available. These new machines promise better cost performance than traditional computers, and some of them have the potential of competing with current supercomputers, such as the CRAY X-MP, in terms of maximum performance. This paper describes the methodology and results of a pilot study of the performance of a broad range of advanced architecture computers using a number of complete scientific application programs. The computers evaluated include:

• 1 shared-memory bus architecture machines such as the Alliant FX/8, the Encore Multimax, and the Sequent Balance and Symmetry
• 2 shared-memory network-connected machines such as the Butterfly
• 3 distributed-memory machines such as the NCUBE, Intel and Jet Propulsion Laboratory (JPL)/Caltech hypercubes
• 4 very long instruction word machines such as the Cydrome Cydra-5
• 5 SIMD machines such as the Connection Machine
• 6 ‘traditional’ supercomputers such as the CRAY X-MP, CRAY-2 and SCS-40.

Seven application codes from a number of scientific disciplines have been used in the study, although not all the codes were run on every machine. The methodology and guidelines for establishing a standard set of benchmark programs for advanced architecture computers are discussed. The CRAYs offer the best performance on the benchmark suite; the shared memory multiprocessor machines generally permitted some parallelism, and when coupled with substantial floating point capabilities (as in the Alliant FX/8 and Sequent Symmetry), provided an order of magnitude less speed than the CRAYs. Likewise, the early generation hypercubes studied here generally ran slower than the CRAYs, but permitted substantial parallelism from each of the application codes.     

Environmentally sustainable rice husk ash reinforced cardanol based polybenzoxazine bio-composites for insulation applications

Polymer Bulletin - Tri-substituted cardanol based benzoxazine with functionalized rice husk ash (CBz/FRHA) bio-composites were developed using renewable resource materials, and...     

Carbon black–polybenzoxazine nanocomposites for high K dielectric applications

This work involves the development of surface functionalized carbon black (FCB) reinforced polybenzoxazine (PBZ) nanocomposites, using a benzoxazine monomer and varying weight percentages of functionalized carbon black (0.5, 1.0, and 1.5 wt%) through ring opening polymerization via thermal cure. Data from the morphological studies indicate that the nanosized FCB particles are homogeneously distributed in the polybenzoxazine matrix. The incorporation of FCB improves the dielectric constant, electrical conductivity, and reduction in resistivity of the resulting FCB–PBZ nanocomposites when compared to neat PBZ. A significant improvement observed in glass transition temperature and thermal stability of resulting FCB–PBZ nanocomposites, when compared to neat PBZ. POLYM. COMPOS., 35:2121–2128, 2014. © 2014 Society of Plastics Engineers     

Synthesis and characterization of heterocyclic core-based polybenzoxazine matrices

In the present work, four types of heterocyclic core-based polybenzoxazine matrices (HC-PBZ) developed based on pyridine, thiophene, and thiazole and their molecular structure, thermal, flame-retardant and luminescent properties were studied and discussed. The heterocyclic core-based benzoxazine monomers (HC-BZ) were synthesized using two types of phenols (phenol, and 4-hydroxyphenylacetonitrile), and two types of heterocyclic diamines [2,6-Bis-(4-aminophenyl)-4-thiophen-2-yl-pyridine (BATP) and 4-(2-methylthiazol-5-yl)-2,6-bis-(4-aminophenyl)-pyridine (BAMTP)] with formaldehyde through Mannich reaction. The structure of the four HC-BZ monomers was confirmed by various spectral analysis such as Fourier-transform infrared spectroscopy (FTIR), and Nuclear magnetic resonance spectroscopy (¹HNMR and ¹³CNMR). All the four HC-BZ monomers have the maximum range of curing temperature (T _p) between 252 and 267 °C. Data resulted from the thermal studies indicate that the HC-PBZ exhibits better T _g, thermal stability and flame-retardant properties. Among the four HC-PBZ systems the thiazole based system possesses the higher value of T _g of 268 °C and thermal stability when compared to those of other matrices. It was also observed that the HC-BZ monomers and HC-PBZ polymers exhibit a photoluminescent (PL) emission range between 441–445 and 414–417 nm, respectively. Overall, it seems that the thiazole and thiophene based HC-PBZ can be considered as competitive materials for luminescent applications with high thermal and flame-retardant properties. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47134.     

Dependable Traffic Control Strategies for Urban and Freeway Networks

Traffic congestion is a growing problem in many countries around the world. It has been recognized that instead of constructing more roads and freeways to counter this problem it is prudent to improve the utilization of existing road network through a judicious combination of advances in control engineering, communication and information technology. The traffic control architecture proposed in this paper is a combination of communicating Urban Traffic Control Architecture (UTCA) and Freeway Traffic Control Architecture (FTCA). The UTCA combines context-awareness, Cyber-Physical Systems (CPS) principles, and Autonomic Computing System (ACS) principles to optimize traffic congestion and enforce safety in urban traffic network. The UTCA includes a network of adaptive intersection traffic controllers and their immediate supervisory systems, who are also networked. The central piece of each traffic controller is an arbiter, which is a mini CPS. It is aware of the traffic dynamics at the intersection managed by it, by virtue of continuous input from monitoring sensors. Due to this context-awareness ability and its communication ability to exchange traffic information with its neighbors, it can execute policy-based reactions in order to enable safe and efficient traffic throughput at its intersection. Each urban traffic supervisory system is designed with ACS principles in order to minimize downtime caused by environmental emergencies and maximize security of the subsystem under it. A supervisory subsystem will also collect global traffic flow information and contextual constraints from its neighbors. Based on this input it will modify policies and communicate them to its traffic controller for timely adaptation. The urban traffic flowing into freeway traffic will be mediated by Intelligent Ramp Meters (IRM). An IRM interacts with the urban traffic control system and its nearest Intelligent Roadside Unit (IRSU) to regulate the flow of traffic from urban to freeway network. The FTCA consists of a network of mutually interacting IRSUs which monitor traffic flow, communicate with IRMs for providing traffic guidance for freeway drivers. An IRSU will communicate with the vehicles in the zone managed by it in order to provide information on rerouting when road and weather conditions warrant it. It also facilitates exchange of information between vehicles, guide them in lane changes and maintaining safe distance in order to avoid collision.