Radiophotoluminescence phenomenon in copper-doped aluminoborosilicate glass

Radiophotoluminescence phenomena have been widely investigated on various types of materials for dosimetry applications. We report that an aluminoborosilicate glass containing 0.005 mol% copper exhibits intense photoluminescence in the visible region induced by X-ray and γ-ray irradiation. The luminescence is assigned to the 3d⁹4s¹ → 3d¹⁰ transition of Cu⁺. The proportionality of the intensity of the induced photoluminescence to the irradiation dose was confirmed up to 0.5 kGy using ⁶⁰Co γ-ray irradiation. Based on the spectroscopic results, a potential mechanism was proposed for the enhancement of the photoluminescence. The exposure to the ionizing radiation generates electron-hole pairs in the glass, and the electrons are subsequently captured by the Cu²⁺ ions, which are converted to Cu⁺ and emit the luminescence. For the glass containing 0.01 mol% copper, the pronounced enhancement of the photoluminescence was not observed because the reverse reaction, ie, the capture of the holes by the Cu⁺ ions, becomes prominent. The photoluminescence induced by the irradiation was stably observed for the glasses kept at room temperature and even for the glasses heat-treated at 150°C. However, the induced photoluminescence could be eliminated by the heat treatment at a temperature at 500°C, and the glass returned to the initial pre-irradiation state. The Cu-doped aluminoborosilicate glass is a potential candidate for use in dosimetry applications.     

Effect of the size of nuclei on crystallization behavior of Li2O · 2SiO2 glass

Crystallization peak temperature was measured for Li₂O · 2SiO₂ glass with various number densities of nuclei induced by long heat-treatment (405 h) at 460°C. Its crystallization process of Li₂O · 2SiO₂ glass was simulated numerically in order to examine the effect of the initial size of nuclei on crystallization behavior, and the relationship between crystallization peak temperature and the number density of nuclei in the glass was considered. It was found that the effect of nuclei size is not significant when the heat-treatment temperature is lower than 460°C. By considering the effect of nuclei size, number density of nuclus was evaluated by DTA method accurately.     

Formation and crystallization of gels in the Na2O-SiO2-TiO2-ZrO2 system

5Na₂O·95(SiO₂ + TiO₂ + ZrO₂) gels together with Na₂O-MO₂ gels (MO₂ = SiO₂, TiO₂, ZrO₂) were synthesized and effect of Na₂O addition to the gel formation and crystallization behavior were studied. From Si(OC₂H₅)₄, Ti(iso-OC₃H₇)₄, Zr(n-OC₃H₇)₄ and NaOCH₃ solutions in EtOH without H₂O, transparent, opaque and heterogeneous gels were obtained. By SEM observation, it was found that the opague bulk gels, rich in TiO₂ or ZrO₂ component, contain agglomerated spherical particles of less than 10 m diameter. Crystallization temperature (Tc) measured by DTA decreased sharply from 1258°C (SiO₂) to 613°C (30Na₂O·70SiO₂) due to the increasing non-bridging oxygens in the Na₂O-SiO₂ system. But in the Na₂O-TiO₂ and Na₂O-ZrO₂ systems, Tc increased as Na₂O content was increased up to 10 mol%. The thermal stability, defined by Tc/TL ratio, decreased from Tc/TL = 0.77 (SiO₂) to 0.57 (5Na₂O·95SiO₂) or increased from Tc/TL = 0.30 (TiO₂) to 0.67 (30Na₂O·70TiO₂) with Na₂O addition. In the 5Na₂O·95(SiO₂ + TiO₂ + ZrO₂) system maximum Tc was 891°C at 5Na₂O·76SiO₂·19ZrO₂ composition and decreased as TiO₂ or ZrO₂ contents increased. Compared with the SiO₂-TiO₂-ZrO₂ gels, Tc of the 5 mol%Na₂O containing gels (Na₂O-SiO₂-TiO₂-ZrO₂) was lower in SiO₂ rich composition and higher in TiO₂ or ZrO₂ rich compositions. It is assumed that addition of Na₂O changed the structure of amorphous TiO₂ and ZrO₂ someway to increase their thermal stability or amorphous forming ability. After DTA run up to 1000°C, cystalline phases precipitated in the 5Na₂O·95(SiO₂ + TiO₂ + ZrO₂) gels were determined by XRD analysis.     

Comparison of enteral nutrition with combined enteral and parenteral nutrition in post-pancreaticoduodenectomy patients: a pilot study

Background  

Many clinical studies have demonstrated that early postoperative enteral nutrition (EN) improved the postroperative course. Post-pancreaticoduodenectomy (PD), patients tend to suffer from postoperative nausea, abdominal distention, and diarrhoea, causing difficulty in the introduction of EN. In this pilot study, we investigated the appropriate nutritional mode post-pancreatic surgery.     

A Three-Dimensional Formulation for Synthetic Aperture Radar Images of Ocean Waves in Orbital Motions

An analytic model of the ocean surface SAR images with a three-dimensional framework is developed following the formalism presented by Swift and Wilson (1979); a trochoidal swell propagates through a uniform field of Bragg-type distributed scatterers. Two- dimensional SAR images are calculated for the interpretation and prediction of actual SAR images of the ocean surface as a function of ocean wave amplitude, wave frequency, propagation direction, and radar frequency, off-nadir angle of the antenna, and spatial resolutions.     

Thermodynamics of antimony,arsenic, and tin in CaO—CaF2 melts

In view of the importance of tramp element contamination of steel products through a large volume of scrap consumption in the near future, the thermodynamic behaviour of Sb, As, Sn and Cu in CaO—CaF₂ melts under reducing conditions was studied by examining the dependences of distribution of each element between Cu, Ag or Sn alloys and CaO—CaF₂ melts on the CaO activity, oxygen partial pressure and temperature around 1 500°C. As a result, the reaction products on treatment by Ca compounds were demonstrated to be Ca₃Sb₂, Ca₃As₂, Ca₂Sn and CaCu. Experimentally obtained distributions were extrapolated to lower oxygen partial pressures less than 10^?18 atm to estimate the feasibility of removing those tramp elements from molten iron. It is thermodynamically indicated that if the prevailing oxygen partial pressure of the environment is below 10^?23 atm, these impurities, except Cu, would be substantially removed from molten steel.     

Frequent development of murine T-cell lymphomas with TcR alpha/beta+, CD4-/8- phenotype after implantation of human inflammatory breast cancer cells in BALB/c nude mice

Tumors developed quite frequently in some of the visceral organs, including spleen and liver, in BALB/c nude mice upon subcutaneously xenografting surgical specimens from five different inflammatory breast cancer patients. All of these tumors developed within two and a half months to one year after the subcutaneous inoculation of surgical specimens. From these tumors, five independent transplantable tumors, including tMK-2, tHK-1, tYK-1, tYK-2 and tTY-1 have been established. Chromosome analysis, morphologic studies by light and electron microscopy and phenotype analysis indicated that these tumors are of mouse origin. The tMK-2 tumor was highly metastatic to the spleen and liver when it was subcutaneously transplanted into the right scapular region. In addition, the region where the tMK-2 tumor cells were subcutaneously inoculated showed an apparently inflammatory process represented by erythema. After subcutaneous inoculation into the right scapular region, tHK-1, tYK-1, 2, and tTY-1 tumors also metastasized to some of the visceral organs, including spleen and liver. From these tumors, in vitro cell lines were established. The cells grew in a stromal-cell dependent manner under in vitro culture conditions. The cells were again tumorigenic at the inoculated region and metastasized to various organs, including liver and spleen, of BABL/c nude mice. Histological examination revealed that the tumors showed features of malignant lymphoma. Phenotypically, these five tumors expressed early T lymphocyte markers as revealed by anti-mouse anti-TcR alpha/beta, anti-CD3, CD4 and CD8 monoclonal antibodies. To our knowledge, these cell lines are the first T-cell lines showing the phenotype of extrathymically differentiated T-cells in the liver.