全文获取类型
收费全文 | 507篇 |
免费 | 31篇 |
国内免费 | 3篇 |
专业分类
电工技术 | 24篇 |
化学工业 | 188篇 |
金属工艺 | 17篇 |
机械仪表 | 13篇 |
建筑科学 | 12篇 |
能源动力 | 22篇 |
轻工业 | 43篇 |
水利工程 | 1篇 |
石油天然气 | 1篇 |
无线电 | 56篇 |
一般工业技术 | 87篇 |
冶金工业 | 13篇 |
原子能技术 | 27篇 |
自动化技术 | 37篇 |
出版年
2024年 | 1篇 |
2023年 | 2篇 |
2022年 | 7篇 |
2021年 | 11篇 |
2020年 | 12篇 |
2019年 | 14篇 |
2018年 | 20篇 |
2017年 | 13篇 |
2016年 | 21篇 |
2015年 | 13篇 |
2014年 | 10篇 |
2013年 | 46篇 |
2012年 | 18篇 |
2011年 | 30篇 |
2010年 | 27篇 |
2009年 | 30篇 |
2008年 | 27篇 |
2007年 | 17篇 |
2006年 | 23篇 |
2005年 | 24篇 |
2004年 | 12篇 |
2003年 | 17篇 |
2002年 | 14篇 |
2001年 | 11篇 |
2000年 | 7篇 |
1999年 | 10篇 |
1998年 | 10篇 |
1997年 | 13篇 |
1996年 | 11篇 |
1995年 | 8篇 |
1994年 | 5篇 |
1993年 | 6篇 |
1992年 | 5篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 6篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1981年 | 4篇 |
1980年 | 4篇 |
1979年 | 3篇 |
1974年 | 2篇 |
1972年 | 2篇 |
1971年 | 1篇 |
排序方式: 共有541条查询结果,搜索用时 0 毫秒
1.
Reduction of flash generated in a gas vent is of great concern for manufacturers of electronic parts. The present study proposes a theoretical model for flash generation through consideration of flow characteristics in a gas vent. The model predicts the factors controlling flash, i.e., material parameters such as zero‐shear viscosity, crystallization temperature, thermal conductivity, and heat capacity, and process parameters such as injection and mold wall temperatures, packing pressure, and the clearance of a gas vent. On the other hand, we measure the amount of flash generated in the molding of poly(phenylene sulfide) (PPS) composites containing glass fiber and spherical fillers (CaCO3 or Al2O3). Flash reduces with decreasing size of spherical fillers. These experimental data are successfully interpreted using the flash model. Polym. Eng. Sci., 45:198–206, 2005. © 2005 Society of Plastics Engineers 相似文献
2.
A new frequency divider, called differential injection locking, is proposed. The proposed divider has no transistor stacking to suppress the performance degradation due to supply voltage reduction. It is shown that the proposed frequency divider achieves 2 GHz with 1 V supply voltage and 540 /spl mu/W power consumption. 相似文献
3.
Solitary DFB laser diodes with 174 kHz beat linewidth are applied to a 10 Gbit/s optical BPSK homodyne detection system for the first time: a sensitivity of -38.9 dBm was achieved. A three-electrode laser forms the local oscillator and is modulated with a partial push-pull scheme to improve its frequency response 相似文献
4.
Several onium cations having vinyl group formed ionic liquids after coupling with bis(trifluoromethanesulfonyl)imide. These monomers were polymerized, and the relation between onium cation structure and properties of thus polymerized ionic liquids was investigated. The polymerized ionic liquid having ethylimiadzolium cation unit showed the highest ionic conductivity of around 10−4 S cm−1 at 30 °C among the obtained polymers reflecting the lowest glass transition temperature of −59 °C. These polymers were thermally stable and their decomposition temperatures were about 350 °C. The ionic conductivity of the polymerized ionic liquids decreased by both the addition of lithium bis(trifluoromethanesulfonyl)imide and the polymerization in the presence of cross-linker. However, the polymerized ionic liquid having 1-methylpiperidinium cation structure showed good lithium ion transference number of 0.43 at room temperature. 相似文献
5.
Kunio Mori Wataru Ibashi Hidetoshi Hirahara Yoshiyuki Oishi Masanari Katayama 《应用聚合物科学杂志》1995,58(13):2451-2458
2-Dibutylamino-1,3,5-triazine-4,6-dithiol (DB) and a mixture of DB and triallylisocyanurate (TAIC) were used as a lubricant during steel wire drawing due to a dry process. DB gave a polymer film with 180 nm in thickness to wire surfaces during the wire drawing. The polymer film had a disulfide structure on the backbone and contained a small amount of DB monomer and olygomer. Molecular weight and polymer weight increased with the drawing rate. The mixture of DB and TAIC gave mainly a three-dimensional polymer film with 225 nm in thickness to wire surfaces during drawing. The polymer film insoluble in THF had mono and disulfide structures and contained a small amount of linear polymer, DB, and TAIC. Such tribological polymerizations are estimated as follows: DB produces dithiyl radicals on a nascent surface formed during drawing and in the presence of oxygen and heat. The dithiyl radicals were polymerized by coupling with each other to give disulfide bonds or added to allyl groups in TAIC to give monosulfide bonds. It is concluded that this technique should be possible to use for unifying metal processing and surface treatment. © 1995 John Wiley & Sons, Inc. 相似文献
6.
Selective modification by ozonation for the surface of polyvinyl chloride (PVC) was evaluated to separate PVC from the other plastics, polyethylene terephthalate (PET), polycarbonate (PC) and polymethyl methacrylate (PMMA), with almost the same density as PVC by the froth flotation process. Ozonation could selectively decrease the contact angles of flexible PVC from 87.5 degrees to 68.4 degrees and rigid PVC from 90.3 degrees to 66.9 degrees, whereas little decreases in the contact angle were observed for other plastics. This would be due to the replacement of the chloride group on the surface of PVC, into hydrophilic functional groups; carbonyl, carboxyl and ester group. The PVC was successfully separated from the other plastics by the froth flotation process after the selective surface modification by ozonation. 相似文献
7.
Toshinobu Yogo Wataru Sakamoto Tadayuki Isaji Koichi Kikuta Shin-ichi Hirano 《Journal of the American Ceramic Society》1997,80(7):1767-1772
Transparent and highly oriented Ba2 NaNb5 O15 (BNN) thin films have been prepared by using metal alkoxides. A homogeneous precursor solution was prepared by the controlled reaction of NaOC2 H5 , Nb(OC2 H5 )5 , and barium metal. The BNN precursor included a molecular-level mixture of NaNb(OC2 H5 )6 and Ba[Nb(OC2 H5 )6 ]2 in ethanol. The alkoxy-derived powder crystallized to a low-temperature phase, and then transformed to orthorhombic BNN (tungsten bronze) at 600°C. BNN precursor films on substrates crystallized to orthorhombic BNN at 800°C via the low-temperature phase. Highly (002) oriented BNN films of tungsten bronze structure were successfully prepared on MgO (100) substrates at 700°C by using BNN underlayer. 相似文献
8.
Catalytic performances of various metal molybdates were tested in the oxidative dehydrogenation of propane to propene with molecular oxygen under an atmospheric pressure. Most of the molybdates tested promoted the selective oxidative conversion of propane to propene and among them cobalt and magnesium molybdates were found highest in the activity and selectivity. It was also found that their catalytic activities were highly sensitive to the catalyst composition, and it turned out that Co0.95MoO
x
and Mg0.95MoO
x
catalysts which have slightly excess molybdenum showed the highest activity in the oxidative dehydrogenation of propane. Under the optimized reaction conditions, higher reaction temperatures and lower partial pressures of oxygen, these catalysts gave 60% selectivity to propene at 20% conversion of propane. Since the molybdates having the surface enriched with molybdenum oxide tended to show high activity for the propane oxidation, surface molybdenum oxide clusters supported on metal molybdate matrix seem to be the active sites for the selective oxidative dehydrogenation of propane. 相似文献
9.
Takashi Kojima Wataru Sakamoto Toshinobu Yogo Takashi Fujii Shin-ichi Hirano 《Journal of the American Ceramic Society》2002,85(9):2212-2216
An in situ composite composed of ceria-stabilized tetragonal zirconia polycrystals (Ce-TZP) and La{Co0.5 Fe0.5 (Fe0.9 Al0.1 )11 }O19 was synthesized from a powder mixture of Ce-TZP, La(Fe0.9 Al0.1 )O3 , Fe2 O3 , Al2 O3 , and CoO. The dense Ce-TZP dispersed with platelike La{Co0.5 Fe0.5 (Fe0.9 Al0.1 )11 }O19 crystals as a second phase were formed after sintering from 1250° to 1350°C. The saturation magnetization of the in situ composite Ce-TZP/La{Co0.5 Fe0.5 (Fe0.9 Al0.1 )11 }O19 was proportional to the mass fraction of the hexaferrite second phase in Ce-TZP. The coercivity of the composite with a 20 mass% of second phase decreased from 9.14 to 2.52 kOe (from 728 to 201 kA/m) after the pulverization of the composite. The susceptibility (χ) increased by 15%–25% under uniaxial stress on the composite. The change of the susceptibility (Δχ/χ) value increased with decreasing the mass fraction of the second phase in the composite. The Δχ was found to increase linearly with applied stress and abruptly change on cracking, which is expected for the application in fracture sensing of the composite. 相似文献
10.
Minoru Tsuda Setsuko Oikawa Akira Yokota Mitsuo Yabuta Wataru Kanai Ken-Ichi Kashiwagi Isamu Hijikata Hisashi Nakane 《Polymer Engineering and Science》1983,23(18):993-999
A dry developable negative working resist composition comprised of poly(methyl isopropenyl ketone) (PMIPK) and 4-methyl-2,6-di(4′-azido-benzylidene) cyclohexanone-1 was examined. The main photochemical product formed in the resist pattern was found to be a secondary amine which crosslinks PMIPK. Post-annealing forms a hydrogen-bonded product which shows a powerful electronic excitation energy quenching effect. The quencher is more powerful than the aromatic compound arising from the azide by post-annealing only. The residual resist thickness of the negative pattern is about 80 percent of the initial thickness of the coating in spite of all the azide compound remaining in the resist coating. The obtained dry developed resist pattern has a high dry etch resistance. Etchings of Si and SiO2 were performed by plasma and reactive ion etching, respectively. 相似文献