The EuQoS system: a solution for QoS routing in heterogeneous networks [Quality of Service based Routing Algorithms for Heterogeneous Networks]

EuQoS is the acronym for "end-to-end quality of service support over heterogeneous networks", which is a European research project aimed at building an entire QoS framework, addressing all the relevant network layers, protocols, and technologies. This framework, which includes the most common access networks (xDSL, UMTS, WiFi, and LAN) is being prototyped and tested in a multidomain scenario throughout Europe, composing what we call the EuQoS system. In this article we present the novel QoS routing mechanisms that are being developed and evaluated in the framework of this project. The preliminary performance results validate the design choices of the EuQoS system, and confirm the potential impact this project is likely to have in the near future     

Alumina coating on dense tungsten powder by fluidized bed metal organic chemical vapour deposition

In order to study the feasibility of coating very dense powders by alumina using Fluidized Bed Metal Organic Chemical Vapour Deposition (FB-MOCVD), experiments were performed on a commercial tungsten powder, 75 microm in median volume diameter and 19,300 kg/m3 in grain density. The first part of the work was dedicated to the experimental study of the tungsten powder fluidization using argon as carrier gas at room temperature and at 400 degrees C. Due to the very high density of the tungsten powder, leading to low initial fixed bed heights and low bed expansions, different weights of powder were tested in order to reach satisfactory temperature profiles along the fluidized bed. Then, using argon as a fluidized bed former and aluminium acetylacetonate Al(C5O2H7)3 as a single source precursor, alumina thin films were deposited on tungsten particles at a low temperature range (e.g., 370-420 degrees C) by FB-MOCVD. The influence of the weight of powder, bed temperature and run duration was studied. Characterizations of the obtained samples were performed by various techniques including scanning electron microscopy (SEM) coupled with Energy Dispersive X-ray Spectroscopy (EDS) analyses, Field Emission Gun SEM (FEG-SEM) and Fourier Transform InfraRed (FT-IR) spectroscopy. The different analyses indicated that tungsten particles were uniformly coated by a continuous alumina thin film. The thickness of the film ranged between 25 and 80 nm, depending on the coating conditions. The alumina thin films were amorphous and contained carbon contamination. This latter may correspond to the adsorption of species resulting from incomplete decomposition of the precursor at so low deposition temperature.     

Fe(PyTACN)‐Catalyzed cis‐Dihydroxylation of Olefins with Hydrogen Peroxide

A family of iron complexes with general formula [Fe(II)(^R,Y,XPyTACN)(CF₃SO₃)₂], where ^R,Y,XPyTACN=1‐[2′‐(4‐Y‐6‐X‐pyridyl)methyl]‐4,7‐dialkyl‐1,4,7‐triazacyclononane, X and Y refer to the groups at positions 4 and 6 of the pyridine, respectively, and R refers to the alkyl substitution at N‐4 and N‐7 of the triazacyclononane ring, are shown to be catalysts for efficient and selective alkene oxidation (epoxidation and cis‐dihydroxylation) employing hydrogen peroxide as oxidant. Complex [Fe(II)(^Me,Me,HPyTACN)(CF₃SO₃)₂] ( 7 ), was identified as the most efficient and selective cis‐dihydroxylation catalyst among the family. The high activity of 7 allows the oxidation of alkenes to proceed rapidly (30 min) at room temperature and under conditions where the olefin is not used in large amounts but instead is the limiting reagent. In the presence of 3 mol% of 7 , 2 equiv. of H₂O₂ as oxidant and 15 equiv. of water, in acetonitrile solution, alkenes are cis‐dihydroxylated reaching yields that might be interesting for synthetic purposes. Competition experiments show that 7 exhibits preferential selectivity towards the oxidation of cis olefins over the trans analogues, and also affords better yields and high [syn‐diol]/[epoxide] ratios when cis olefins are oxidized. For aliphatic substrates, reaction yields attained with the present system compare favourably with state of the art Fe‐catalyzed cis‐dihydroxylation systems, and it can be regarded as an attractive complement to the iron and manganese systems described recently and which show optimum activity against electron‐deficient and aromatic olefins.     

State of the art on high-temperature thermal energy storage for power generation. Part 2—Case studies

Power generation systems are attracting a lot of interest from researchers and companies. Storage is becoming a component with high importance to ensure system reliability and economic profitability. A few experiences of storage components have taken place until the moment in solar power plants, most of them as research initiatives. In this paper, real experiences with active storage systems and passive storage systems are compiled, giving detailed information of advantages and disadvantages of each one. Also, a summary of different technologies and materials used in solar power plants with thermal storage systems existing in the world is presented.     

An efficient and lightweight method for Service Level Agreement assessment

Traditional approaches to on-line end-to-end Service Level Agreement (SLA) assessment have focused on the estimation of network QoS parameters. These approaches, however, face a trade-off between accuracy and the amount of resources needed to achieve such accuracy. This paper offers an alternative approach, where instead of estimating QoS parameters, we propose an effective and lightweight solution for directly detecting SLA violations. Our solution monitors the Inter-Packet Arrival Time (IPAT) at an end-point, wherein current IPAT distributions are periodically compared with a set of reference IPAT distributions as the main basis for detecting SLA violations. A mapping of the IPAT distribution with the current network conditions is derived, and a training algorithm that dynamically acquires the set of reference IPAT distributions is designed. For the comparison of the IPAT distributions, we propose a variant of the Hausdorff Distance algorithm. Our variant provides a better accuracy than the traditional Hausdorff Distance, while presenting linear complexity. Our proposal is validated in a real testbed, by comparing the SLA violations detected and the resources required in terms of bandwidth, with other existing alternatives as well as with perfect knowledge of current network QoS status.     

Mesoporous Silica: A Suitable Adsorbent for Amines

Mesoporous silica with KIT-6 structure was investigated as a preconcentrating material in chromatographic systems for ammonia and trimethylamine. Its adsorption capacity was compared to that of existing commercial materials, showing its increased adsorption power. In addition, KIT-6 mesoporous silica efficiently adsorbs both gases, while none of the employed commercial adsorbents did. This means that KIT-6 Mesoporous silica may be a good choice for integrated chromatography/gas sensing micro-devices.     

Managing interdomain traffic in Latin America: a new perspective based on LISP [Topics in Network and Service Management]

The characteristics of Latin American network infrastructures have global consequences, particularly in the area of interdomain traffic engineering. As an example, Latin America shows the largest de-aggregation factor of IP prefixes among all regional Internet registries, being proportionally the largest contributor to the growth and dynamics of the global BGP routing table. In this article we analyze the peculiarities of LA interdomain routing architecture, and provide up-to-date data about the combined effects of the multihoming and TE practices in the region. We observe that the Internet Research Task Force initiative on the separation of the address space into locators and identifiers can not only alleviate the growth and dynamics of the global routing table, but can also offer appealing TE opportunities for LA. We outline one of the solutions under discussion at the IRTF, the Locator/Identifier Separation Protocol, and examine its potential in terms of interdomain traffic management in the context of LA. The key advantage of LISP is its nondisruptive nature, but the existing proposals for its control plane have some problems that may hinder its possible deployment. In light of this, we introduce a promising control plane for LISP that can solve these issues, and at the same time has the potential to bridge the gap between intradomain and interdomain traffic management.     

On the challenges of establishing disjoint QoS IP/MPLS paths across multiple domains

MPLS is being actively adopted as the core switching infrastructure at the intradomain level. This trend is mainly attributable to the undeniable potential of MPLS in terms of virtual private networks (VPNs) management, traffic engineering (TE), QoS delivery, path protection, and fast recovery from network failures. However, little progress has been made to attain the expected extension of MPLS label-switched paths (LSPs) across domain boundaries. Among the problems that remain unsolved is how to efficiently find and establish primary and protection interdomain LSPs for mission-critical services subject to QoS constraints. This article explores the major limitations hindering the deployment of these kinds of LSPs across multiple domains, in the context of the current interdomain network model. We describe the critical problems faced by the research community, and present our vision on how to rationally overcome some of the problems exposed. Our perspective is that we should be prepared for rather coarse-grained solutions as long as we need to coexist with the current interdomain network model