Crystallographic characteristics and microwave dielectric properties of Ni-modified MgTa2O6 ceramics

Ni²⁺ modified MgTa₂O₆ ceramics with a trirutile phase and space group P4₂/mnm were obtained. The correlations between crystallographic characteristics and microwave dielectric performance of MgTa₂O₆ ceramics were systematically studied based on the chemistry bond theory (PVL theory) for the first time. The results indicate that the introduction of Ni²⁺ causes a change in polarizability and the Mg–O bond ionicity, which contributes to the variation of dielectric constant. Moreover, the lattice energy, and packing fraction, full width at half maximum of the Raman peak of Ta–O bond, as the quantitative characterization of crystallographic parameters, regulate the dielectric loss of MgTa₂O₆ ceramics in GHz frequency band. In addition, the study of sintering behavior shows that the densification and micromorphology are the crucial factors affecting the microwave dielectric performance. Typically, Ni²⁺ doping on the A-site of MgTa₂O₆ can effectively promote the Q × f values to 173,000 GHz (at 7.43 GHz), which ensures its applicability in 5G communication technology.     

Investigation of crystal characteristics,Raman spectra,and microwave dielectric properties of Mg1-xZnxTa2O6 ceramics

Mg_(1-x)Zn_xTa₂O₆ (x = 0.00?0.08) dielectric ceramics were synthesized via the traditional solid-state reaction method. We used XRD and Rietveld refinement to demonstrate that a pure Mg_(1-x)Zn_xTa₂O₆ phase with trirutile structure was formed. Zn²⁺ substitution helped to decrease the Raman full width at half width of the A_1g mode at 703 cm^?1, which resulted in an increase in the order and rigidity of the TaO₆ octahedron, this in turn contributed to improving the Q×f values. Additionally, the introduction of Zn²⁺ significantly promoted grain growth and increased the dense, and the molecular polarizability, these factors lead to a higher permittivity. Moreover, enhanced Ta-O bond energy resulted in a more stable TaO₆ octahedron in the Mg_(1?x)Zn_xTa₂O₆ system, which contributed to enhanced τ_f values via substitution of Zn²⁺ doped on the A-site. Correspondingly, the microwave dielectric properties were significantly improved for 0.04-doped samples, obtaining: ε_r = 27, Q × f = 185,000 GHz (at 7.47 GHz), τ_f =32 ppm/°C.     

Microwave drying performance of lignite with the assistance of biomass-derived char

Microwave lignite drying with assistance of biomass-derived char was addressed and effect of bio-char on drying rate and energy consumption was investigated in this work. Effective diffusion coefficient and activation energy for the drying process were also analyzed. The results indicated the drying process was largely dependent on the variation of sample temperature. Bio-char originated from pine wood was most favorable for lignite drying, considering its better promoting effect and advanced security. There existed an optimal bio-char addition ratio for drying process at different power. The corresponding optimal ratio was 10% at 231?W and 15% at 385?W, at which the biggest drying rate and the least energy consumption were reached. It was compared lignite drying initiated at 385?W was better for energy conservation. Effective diffusivity was improved and activation energy was simultaneously reduced, with the addition of bio-char. The minimum activation energy was 15.54?W?·?g^?1, which was gained at bio-char addition ratio of 10%. The results revealed the effect of bio-char on depressing activation energy could rival that of metal-based additives. The drying process with assistance of microwave and bio-char could present technical and economical benefits on lignite upgrading.     

天然气合成油技术发展动向

介绍了天然气合成油技术，天然气石油特征及代表性工艺过程，叙述了天然气合成油发展前景。     

新型海洋涂料技术

本文综述了符合时代要求的海洋涂料新技术及其发展趋势。     

液压集成块校核软件的编制和应用

本文叙述了液压集成块校核软件的编制思想和方法，并重点介绍了编制过程中所使用的相关技术，同时给出部分源程序。     

PKI技术在社保电子政务中的应用

背景和意义劳动保障部门作为统一管理和组织协调社会劳动力,统筹城乡就业,规划、引导劳动力市场的发展,组织建立健全就业服务体系,负责社会保障基金的缴纳、记录、核算、支付的部门,运用信息技术来实现劳动保障管理工作的电子化、自动化和网络化,更科学、更迅速、更准确地汇集、加工、传递、运用各类信息,是社会保障电子政务系统建设的重要内容,也是加快由行政管理向社会服务转化的突破口。随着社会保障电子政务系统建设的不断深入以及网络技术的发展,基于Internet的网上应用已逐步开展。如参保单位的网上申报、网上缴费以及信息查询等。这…