Efficient MgO-doped CaO sorbent pellets for high temperature CO2 capture

Novel MgO-doped CaO sorbent pellets were prepared by gel-casting and wet impregnation. The effect of Na⁺ and MgO on the structure and CO₂ adsorption performance of CaO sorbent pellets was elucidated. MgO-doped CaO sorbent pellets with the diameter range of 0.5-1.5 mm exhibited an excellent capacity for CO₂ adsorption and adsorption rate due to the homogeneous dispersion of MgO in the sorbent pellets and its effects on the physical structure of sorbents. The results show that MgO can effectively inhibit the sintering of CaO and retain the adsorption capacity of sorbents during multiple adsorption-desorption cycles. The presence of mesopores and macropores resulted in appreciable change of volume from CaO (16.7 cm³∙mol⁻¹) to CaCO₃ (36.9 cm³∙mol⁻¹) over repeated operation cycles. Ca2Mg1 sorbent pellets exhibited favorable CO₂ capture capacity (9.49 mmol∙g⁻¹), average adsorption rate (0.32 mmol∙g⁻¹∙min⁻¹) and conversion rate of CaO (74.83%) after 30 cycles.     

基于蚁群聚类算法的离群挖掘方法

离群挖掘是数据挖掘研究的重要内容,在实际生活中获得广泛应用。该文首先给出了离群数据的量化定义,并用基于蚁群的聚类学习方法,产生了状态空间的整体特征。然后结合具体的设备对象,提出了离群数据的挖掘方法。最后进行了实验验证,结果表明该文提出的方法是有效的。     

甲醇羰基化合成甲酸甲酯研究

在高压反应釜中对甲醇羰基化合成甲酸甲酯进行了研究。结果表明 ,在一氧化碳体积分数为 99.9% ;甲醇质量分数为 99.5% ,压力为 3 .8MPa时 ,催化剂甲醇钠浓度以 0 .4 mol/L,温度 80℃为佳 ,此时采用浓度为2 mol/L的不同助剂 (吡啶、DMF、二甲基亚砜 )可使甲酸甲酯的时空收率达 2 84 g/(L· h)以上 ,比不加助剂时分别增至 1 .2 6～ 1 .1 3倍     

Field investigation and numerical simulation of the seismic triggering mechanism of the Tahman landslide in eastern Pamir,Northwest China

Bulletin of Engineering Geology and the Environment - Landslides are one of the most common geological hazards in many parts of the world, which have brought catastrophic consequences to mankind....     

基于节点持续传输准则的认知传感器网络信道分配策略

在异构分级式认知传感器网络中,为提高数据分组的传输成功率,提出将节点划分为具备持续传输条件和不具备持续传输条件两类,两类节点分别以牺牲较多能耗和分配较优信道的方式提高数据分组的传输成功率,并由此得到一种集中式信道分配策略.为了降低节点在信息传输过程中每比特平均能耗,对数据分组自适应调节机制进行了优化,确保不具备持续传输条件的节点得到最优的传输数据分组大小.仿真结果证明,提出的分配策略和优化机制能够有效提高能量的使用效率,改善网络性能.     

建筑节能的文化性与艺术性--浅谈蒙中医院建筑设计的节能策略

本文将限制因素转变为建筑创作的创新点,将生态节能理念植根于设计思维中,成为自然流淌于建筑师笔尖的艺术灵感与文脉传承,进而创造出张弛有序的总体布局、繁简适度的特色空间。本文从体型节能、布局节能、空间节能、结构节能、装饰节能等不同方面,介绍了蒙中医院综合楼的几项建筑节能策略：双L布局、袋状流线、特色中庭、米字形绗架、遮阳百叶。从艺术与节能、文化与节能的视角审视建筑节能,探究建筑节能的设计策略。     

Precursor effect on catalytic properties of Mo-based catalyst for sulfur-resistant methanation

The catalytic activity of Mo-based catalysts prepared from (NH₄)₆Mo₇O₂₄ and (NH₄)₂MoS₄ was compared in the sulfur resistant methanation process. The catalyst using oxide precursor had relatively higher activity than the catalyst using sulfide precursor, and the presulfidation procedure almost had no effect on the catalytic performance of the catalyst using oxide precursor. In view of the characterization results, it could be supposed that the amorphous MoS₂ was more active for sulfur-resistant methanation than the crystalline MoS₂. The molybdenum sulfides and oxides with lower valence states (Mo⁴⁺, Mo⁵⁺) could be responsible for the catalytic activity and make a possible contribution to the carbon monoxide methanation in the reaction condition.     

Controllable Fe/HCS catalysts in the Fischer-Tropsch synthesis: Effects of crystallization time

The Fischer–Tropsch synthesis (FTS) continues to be an attractive alternative for producing a broad range of fuels and chemicals through the conversion of syngas (H₂ and CO), which can be derived from various sources, such as coal, natural gas, and biomass. Among iron carbides, Fe₂C, as an active phase, has barely been studied due to its thermodynamic instability. Here, we fabricated a series of Fe₂C embedded in hollow carbon sphere (HCS) catalysts. By varying the crystallization time, the shell thickness of the HCS was manipulated, which significantly influenced the catalytic performance in the FTS. To investigate the relationship between the geometric structure of the HCS and the physic-chemical properties of Fe species, transmission electron microscopy, X-ray diffraction, N₂ physical adsorption, X-ray photoelectron spectroscopy, hydrogen temperature-programmed reduction, Raman spectroscopy, and Mössbauer spectroscopy techniques were employed to characterize the catalysts before and after the reaction. Evidently, a suitable thickness of the carbon layer was beneficial for enhancing the catalytic activity in the FTS due to its high porosity, appropriate electronic environment, and relatively high Fe₂C content.