全文获取类型
收费全文 | 51470篇 |
免费 | 5332篇 |
国内免费 | 2660篇 |
专业分类
电工技术 | 3601篇 |
技术理论 | 5篇 |
综合类 | 3790篇 |
化学工业 | 8102篇 |
金属工艺 | 3152篇 |
机械仪表 | 3469篇 |
建筑科学 | 4472篇 |
矿业工程 | 1673篇 |
能源动力 | 1619篇 |
轻工业 | 3598篇 |
水利工程 | 1074篇 |
石油天然气 | 2461篇 |
武器工业 | 462篇 |
无线电 | 6095篇 |
一般工业技术 | 6132篇 |
冶金工业 | 1943篇 |
原子能技术 | 519篇 |
自动化技术 | 7295篇 |
出版年
2024年 | 192篇 |
2023年 | 872篇 |
2022年 | 1683篇 |
2021年 | 2413篇 |
2020年 | 1808篇 |
2019年 | 1444篇 |
2018年 | 1628篇 |
2017年 | 1745篇 |
2016年 | 1544篇 |
2015年 | 2200篇 |
2014年 | 2606篇 |
2013年 | 3190篇 |
2012年 | 3612篇 |
2011年 | 3632篇 |
2010年 | 3343篇 |
2009年 | 3062篇 |
2008年 | 3014篇 |
2007年 | 2901篇 |
2006年 | 2711篇 |
2005年 | 2361篇 |
2004年 | 1749篇 |
2003年 | 1672篇 |
2002年 | 1832篇 |
2001年 | 1591篇 |
2000年 | 1271篇 |
1999年 | 1125篇 |
1998年 | 798篇 |
1997年 | 649篇 |
1996年 | 653篇 |
1995年 | 481篇 |
1994年 | 392篇 |
1993年 | 332篇 |
1992年 | 262篇 |
1991年 | 172篇 |
1990年 | 115篇 |
1989年 | 108篇 |
1988年 | 90篇 |
1987年 | 46篇 |
1986年 | 46篇 |
1985年 | 23篇 |
1984年 | 22篇 |
1983年 | 17篇 |
1982年 | 13篇 |
1981年 | 14篇 |
1980年 | 12篇 |
1979年 | 7篇 |
1970年 | 1篇 |
1969年 | 1篇 |
1959年 | 4篇 |
1951年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Feng Wenran Li Zhen Chen Yingying Chen Jinyang Lang Haoze Wan Jianghong Gao Yan Dong Haitao 《Journal of Materials Science》2022,57(3):1881-1889
Journal of Materials Science - Although chalcogenide materials continue to generate considerable interest due to great potentials for various optoelectronic devices, annealing for a long time in... 相似文献
3.
Zhen Hong Mingshan Xue Yidan Luo Zuozhu Yin Chan Xie Junfei Ou Fajun Wang 《应用聚合物科学杂志》2021,138(2):49657
With the continuous development of bionics, such as, geckos and virginia creeper with both superhydrophobic and super-adhesive, the surface wetting and super-adhesive properties of various porous materials have attracted extensive attention of the scientific and medical communities. Here, the honeycomb polyurethane (PU) porous films with strong adhesion were successfully prepared by microphase separation method and the effects of growth parameters on their microstructure and adhesive strength to ice were investigated. It was found that a high relative humidity (e.g., 100%) and a low solution concentration (e.g., 2%) facilitated the formation of ordered honeycomb PU porous films, and as-prepared PU pores with average pore diameter as small as 5 μm are better ordered and more uniform than these in related documents. Although the contact angle of water droplets on the surface of PU porous films increased from the premodification value of 85–130° to more than 160° after surface modification with polydopamine (PDA), the corresponding rolling angle remained approximately constant (180°), indicating that the surface of PU porous films has strong adhesion similar to geckos and virginia creeper. Furthermore, at lower temperature, the PU porous films exhibited the high adhesive strength of 142.13 kPa on ice, which was strongly dependent on the porous microstructures and surface compositions. The improved adhesive behavior to ice of honeycomb PU porous films modified with PDA provides new strategies for surface modification of materials and potential applications in medical domain. 相似文献
4.
Chenhui Ding Marion Breunig Jana Timm Roland Marschall Jürgen Senker Seema Agarwal 《Advanced functional materials》2021,31(49):2106507
Covalent organic frameworks (COFs) show advantageous characteristics, such as an ordered pore structure and a large surface area for gas storage and separation, energy storage, catalysis, and molecular separation. However, COFs usually exist as difficult-to-process powders, and preparing continuous, robust, flexible, foldable, and rollable COF membranes is still a challenge. Herein, such COF membranes with fiber morphology for the first time prepared via a newly introduced template-assisted framework process are reported. This method uses electrospun porous polymer membranes as a sacrificial large dimension template for making self-standing COF membranes. The porous COF fiber membranes, besides having high crystallinity, also show a large surface area (1153 m2 g−1), good mechanical stability, excellent thermal stability, and flexibility. This study opens up the possibility of preparation of large dimension COF membranes and their derivatives in a simple way and hence shows promise in technical applications in separation, catalysis, and energy in the future. 相似文献
5.
Recently, the successful synthesis of wafer-scale single-crystal graphene, hexagonal boron nitride (hBN), and MoS2 on transition metal surfaces with step edges boosted the research interests in synthesizing wafer-scale 2D single crystals on high-index substrate surfaces. Here, using hBN growth on high-index Cu surfaces as an example, a systematic theoretical study to understand the epitaxial growth of 2D materials on various high-index surfaces is performed. It is revealed that hBN orientation on a high-index surface is highly dependent on the alignment of the step edges of the surface as well as the surface roughness. On an ideal high-index surface, well-aligned hBN islands can be easily achieved, whereas curved step edges on a rough surface can lead to the alignment of hBN along with different directions. This study shows that high-index surfaces with a large step density are robust for templating the epitaxial growth of 2D single crystals due to their large tolerance for surface roughness and provides a general guideline for the epitaxial growth of various 2D single crystals. 相似文献
6.
Yujie Chen Yiping Song Zhen Zhang Yali Chen Qiliang Deng Shuo Wang 《Advanced functional materials》2021,31(41):2104885
Various products, including foods and pharmaceuticals, are sensitive to temperature fluctuations. Thus, temperature monitoring during production, transportation, and storage is critical. Facile indicators are required to monitor temperature conditions via color changes in real time. This study aimed to prepare and apply thiol-functionalized covalent organic frameworks (COFs) as a novel indicator for monitoring thermal history and temperature abuse. The COFs underwent obvious color changes from bright yellow to purple after exposure to different temperatures for varying durations. The reaction kinetics are analyzed under isothermal conditions, which reveal that the order of reaction rates is k−20°C < k4°C < k20°C < k35°C < k55°C. The activation energy (Ea) of the COFs is calculated using the Arrhenius equation as 50.71 kJ moL−1. The COFs are capable of sensitive color changes and offer a broad temperature tracking range, thereby demonstrating their application potential for the monitoring of temperature and time exposure history during production, transportation, and storage. This excellent performance thermal history indicator also shows promise for expanding the application field of COFs. 相似文献
7.
9.
The exploitation of recycled carbonaceous catalysts from renewable biomass resources such as chitin is a crucial issue for the development of the sustainable society. In this article, the chitin-based N and O doped carbon microspheres (ChC) were fabricated by a simple dissolution, sol–gel transformation, and the carbonization methods. Subsequently, the novel magnetic Ag-Fe3O4@chitin-based carbon microspheres catalyst (MChC) was successfully constructed through the in situ redox reaction. The as-prepared MChC possessed rich micropores with high-surface area, and a narrow size distribution (50–120 μm). The Ag-Fe3O4 nanoparticles were immobilized through the interaction with C, N, and O atoms in the pores of MChC. The reduction of 4-nitrophenol was applied to evaluate the catalytic activity of MChC. 4-Nitrophenol (4-NP) could be fully reduced to 4-aminophenol (4-AP) in 5 min with the catalyst MChC-45. Moreover, MChC could be collected in solution with an external magnet in 8 s and remained relatively high-catalytic activity after 10 cycle times. This work provided novel ideas for the fabrication of doped carbon material from biomass and promoted its utilization in nanocatalytic applications. 相似文献
10.
Nengbing Long Yanqing Fu Tianxiang Xu Dashuang Ding Shaoqian Zhang Shengzhi Sun Shiliang Kang Tiefeng Xu Shixun Dai Qiuhua Nie Changgui Lin 《Journal of the European Ceramic Society》2021,41(8):4584-4589
The confinement of CsPbX3 (X = Cl, Br, and I) perovskite nanocrystals (NCs) in a stabilized inorganic glass matrix is a new strategy for improving their long-term stability and promoting their applications in the optoelectronic field. Here, in situ nanocrystallization strategy is developed to precipitate CsPbBr3?xIx NCs with arbitrary I/Br ratio among an elaborately designed GeS2–Sb2S3-based chalcogenide glass matrix. Spherical CsPbBr3?xIx NCs are homogeneously distributed in the glass matrix after thermal treatment. The photoluminescence (PL) spectra show that the emission peaks of CsPbBr3?xIx NCs can be tuned from 570 nm to 722 nm with the replacement of Br by I. The fs transient absorption (TA) spectra reveal that there exists some structural defects in the NCs, leading to short PL decay life. This work would shed light on confining CsPbX3 NCs into glassy matrices, facilitating their future applications in photoelectronic fields. 相似文献