Polyethylene oxide-polypropylene oxide -polyethylene oxide derived porous carbon materials with different molecular weights as ORR catalyst in alkaline electrolytes

Polyethylene oxide (PEO)-polypropylene oxide (PPO)-polyethylene oxide block copolymer having different molecular weights are used as precursors of carbon materials to prepare Hollow -Derivatives carbon material as an electrocatalyst through block copolymer self-assembly. The composition and microstructure of the prepared catalysts are shown by Raman spectroscopy, X-ray diffraction (XRD), Test of nitrogen adsorption and desorption curves, High resolution transmission electron microscopy (HR-TEM) and scanning electron microscopy (HR-SEM). Oxygen was passed into alkaline electrolyte solution until the solution reached saturation state. With molecular weight increasing, the obtained sample gradually changed from block to hollow and spherical. When the molecular weight was 12600 g mol^?1, the evenly hollow carbon nanocages was acquired (C-12600). In O₂ saturated alkaline electrolyte (0.1 M KOH solution), C-12600's limited current density，half-wave potential and initial potential are 5.23 mA cm^?2@0.4 V, 0.72 V and 0.81 V, respectively. And most important is that half-wave potential and onset potential have barely change after 2000 cycles of cyclic voltammetry. As a result, the porous carbon materials exhibited excellent electrocatalytic activity while maintaining high stability in alkaline KOH solution.     

Prediction of atherosclerosis diseases using biosensor-assisted deep learning artificial neuron model

Neural Computing and Applications - In the present medical era, the major cause of the rise in death rate worldwide is atherosclerosis disease and this diagnosis is complicated because initial...     

ZnO微／纳米纤维的静电纺丝及其表征

以聚乙烯吡咯烷酮(PVP)为络合剂与醋酸锌[Zn(CH3COO)2]反应制得前驱体溶液,用静电纺丝法制备了PVP／Zn(CH3COO)2纤维,经煅烧得到具有微孔结构的氧化锌(ZnO)微／纳米纤维。对所制备纤维分别采用差热-热重分析、红外光谱分析、X射线衍射分析、扫描电镜等手段进行了表征。结果表明: PVP/Zn(CH3COO)纤维表面光滑,直径约300-700 nm,经700℃煅烧后,可得到ZnO微／纳米纤维。     

对模拟纵向数据集缺失值处理的几种方法比较

运用SAS9．0、数据模拟技术,分别模拟纵向完整数据集和具有各种缺失率的随机缺失数据集,采用多重填补法（MI）、期望值最大化法（EM）和回归插补法（Regression）对各缺失数据集进行处理,对结果进行比较和分析。结果表明,对不同缺失率的数据集,MI、EM和Regression法对缺失值的处理各有优劣。     

改变规则以提升高等院校理工类实验课的授课效果

分析了高等院校理工类实验课多年来无法达到预期目标的原因,提出了改变现有实验课的授课方法,以提高学生对实验课的重视程度,激励学生自主完成实验的全部环节,使学生的实践操作能力、分析问题和解决问题的能力有较大程度地提高;提出的实验课考核新方式,不仅可以较为公正地评判每名学生的实验技能,还可以减轻学生的课业负担,给学生更多的自主学习及实践锻炼的机会。     

基于IPv6的校园网建设研究与思考

IPv6协议以其庞大的地址空间等优势已成为下一代互联网的核心协议,现有的IPv4网络逐步向IPv6过渡已势在必行。结合现有校园网的实际与需求,提出了IPv6校园网的整体设计和建设规划,并进行了相关的部署和典型通信场景的实验,为同类院校建设IPv6校园网提供了理论依据和实践经验。     

单山包和多山包绕流数值模拟研究

本文分别采用标准k-e模型、重整化数群k-e模型(RNG k - e )和雷诺应力模型(RSM)对 二维单山包和多山包绕流进行了数值模拟,并将单山包和多山包绕流计算模拟结果与实验结果做对比 分析。结果表明:(1)三种模型计算结果与实验数据基本吻合。对于单山包和多山包绕流数值模拟, 三种模型是适用的。(2)不论平均速度,湍流动能还是回流区长度,k-e两方程模型计算结果都略好 于二阶矩模型(RSM)o (3)在充分发展湍流条件下数值模拟山包绕流,标准k-e模型计算模拟结果 比RNG k一e模型略好。     

Research in the Development of Finite Element Software for Creep Damage Analysis

This paper reports the development of finite element software for creep damage analysis. Creep damage deformation and failure of high temperature structure is a serious problem for power generation and it is even more technically demanding under the current increasing demand of power and economic and sustainability pressure. This paper primarily consists of three parts： （1） the need and the justification of the development of in-house software; （2） the techniques in developing such software for creep damage analysis; （3） the validation of the finite element software conducted under plane stress, plane strain, axisymmetric, and 3 dimensional cases. This paper contributes to the computational creep damage mechanics in general.     

基于DSP的激光跟踪仪数据通信及处理模块设计

以DSP TMS320F28335为核心设计了数据通信及处理模块。该模块采用硬件协议栈芯片W5300实现与上位机的TCP/IP通信,同时利用双口RAM实现与电控系统主控板的数据通信,与主控板通信的实时性由同步时钟触发外部中断的方式实现。根据误差补偿算法,该模块可实现对激光跟踪测量系统所测量的大气参数、激光干涉测距、激光绝对测距、方位角和俯仰角信息的误差补偿。