Phase behavior,density, and crystallization of polyethylene in n‐pentane and in n‐pentane/CO2 at high pressures

The phase behavior and volumetric properties of polyethylene (PE) in solutions of n‐pentane and n‐pentane/CO₂ were studied in a temperature (T) range of 370–440 K at pressures up to 60 MPa. Measurements were conducted with a variable‐volume view‐cell system equipped with optical sensors to monitor the changes in the transmitted light intensity as the P or the T of the system was changed. Lower‐critical‐solution‐temperature‐type behavior was observed for all of the liquid–liquid (L–L) phase boundaries, which shifted to higher pressures in solutions containing CO₂. The solid–fluid (S–F) phase boundaries were investigated over a P range of 8–54 MPa and took place in a narrow T range, from 374 to 378 K in this P interval. The S–F phase boundary showed a unique feature in that the demixing temperatures showed both increasing and decreasing trends with P depending on the P range. This was observed in both the PE/n‐pentane and PE/n‐pentane/CO₂ mixtures. The density of these solutions were measured as a function of P at selected temperatures or as a function of T at selected pressures that corresponded to the paths followed in approaching the phase boundaries (S–F or L–L) starting from a homogeneous one‐phase condition. The data showed a smooth variation of the overall mixture density along these paths. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2201–2209, 2003     

Use of Warranties on Highway Projects: A Real Option Perspective

Since the introduction of warranty provisions in federal highway jobs, more and more state departments of transportation (DOTs) have considered the use of such provisions to protect their initial investment. This paper describes the pros and cons of warranty contracting in highway construction based on a survey of warranty practices in the United States. In particular, the need for state DOTs to buy a warranty for a well-built project is questioned. As an alternative, this paper introduces the warranty option, which gives the DOT the right to buy a warranty only if it becomes necessary at the end of construction. This option is exercised if the performance on site warrants it. This paper describes the mechanics of the warranty option and its advantages over the conventional warranty. A bid evaluation model is also developed for the warranty option approach.     

Preparation and characterization of novel poly(glycidyl methacrylate) beads carrying amidoxime groups

Poly(glycidyl methacrylate) (PGMA) beads with an average size of 350 μm were synthesized by suspension polymerization technique. The PGMA beads were first modified with iminodiacetonitrile (IDAN). Then, the IDAN‐modified beads were subsequently modified by hydroxylamine. The IDAN modification and the conversion of the nitrile groups to amidoxime were followed by FT‐IR spectroscopy. The surface morphology and thermal behavior of the PGMA and its modified forms were also characterized by scanning electron microscopy and thermogravimetric analysis techniques, further confirming modification and amidoximation. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Generic visual analysis for multi- and hyperspectral image data

Multi- and hyperspectral imaging and data analysis has been investigated in the last decades in the context of various fields of application like remote sensing or microscopic spectroscopy. However, recent developments in sensor technology and a growing number of application areas require a more generic view on data analysis, that clearly expands the current, domain-specific approaches. In this context, we address the problem of interactive exploration of multi- and hyperspectral data, consisting of (semi-)automatic data analysis and scientific visualization in a comprehensive fashion. In this paper, we propose an approach that enables a generic interactive exploration and easy segmentation of multi- and hyperspectral data, based on characterizing spectra of an individual dataset, the so-called endmembers. Using the concepts of existing endmember extraction algorithms, we derive a visual analysis system, where the characteristic spectra initially identified serve as input to interactively tailor a problem-specific visual analysis by means of visual exploration. An optional outlier detection improves the robustness of the endmember detection and analysis. An adequate system feedback of the costly unmixing procedure for the spectral data with respect to the current set of endmembers is ensured by a novel technique for progressive unmixing and view update which is applied at user modification. The progressive unmixing is based on an efficient prediction scheme applied to previous unmixing results. We present a detailed evaluation of our system in terms of confocal Raman microscopy, common multispectral imaging and remote sensing.     

Particle-based simulation of the interaction between fluid and knitwear

We present a particle-based method to simulate and visualize the interaction of knitwear with fluids. The knitwear is modeled using spring-mass systems and the fluid is modeled using the smoothed particle hydrodynamics method. Two-way coupling is achieved by considering surface tension, capillary, and interparticle forces between the fluid and knitwear. The simulation of fluid and knitwear particles is performed on the graphics processing unit. Photorealistic rendering of knitwear and fluid is achieved by using a hardware-accelerated rasterization-based rendering technique. Our method is able to simulate and visualize the macro- and microstructure of free-form knitwear and reflective and refractive characteristics of the fluid surface.     

Arduino-based slider setup for gas–liquid mass transfer investigations: Experiments and CFD simulations

The implementation of traditional sensors is a drawback when investigating mass transfer phenomena within microstructured devices, since they disturb the flow and reactor characteristics. An Arduino based slider setup is developed, which is equipped with a computer-vision system to track gas–liquid slug flow. This setup is combined with an optical analytical method allowing to compare experimental results against CFD simulations and investigate the entire lifetime of a single liquid slug with high spatial and temporal resolution. Volumetric mass transfer coefficients are measured and compared with data from literature and the mass transfer contribution of the liquid film is discussed.     

Series resistance determination of Au/Polypyrrole/p-Si/Al structure by current–voltage measurements at low temperatures

The current–voltage (I–V) characteristics of Polypyrrole(PPy)/p-Si/Al structure have been investigated as a function of temperature. A modified Norde function combined with conventional forward I–V method has been used to extract the junction parameters including the ideality factor, barrier height and series resistance. Norde function has been compared with the Cheung functions and it has been seen that there is a good agreement with both method for the barrier height values. However, the values of series resistance have very different especially towards to the lower temperatures. This is attributed to non-ideal I–V characteristics of the Au/PPy/p-Si/Al structure and non-pure Thermionic emission theory due to the low temperature effects.     

Curing cycle modification for RTM6 to reduce hydrostatic residual tensile stress in 3D woven composites

Triaxial residual tensile stresses resulting after cooling a 3D woven composite from the curing temperature cause cracking in the resin pockets for weave architectures that have high through‐the‐thickness constraint. We show how curing cycle modifications can reduce the hydrostatic tensile stress generated by thermal mismatch during cooling of Hexcel RTM6 epoxy resin constrained in a quartz tube which simulates extreme constraint in a composite. The modified curing schedule consists of a high temperature cure to just before the glass transition, a lower temperature hold that takes the resin through the glass transition thereby freezing in the zero stress state, followed by high temperature cure to bring the resin to full conversion. We show that this process is sensitive to heating rates and can reduce the zero stress state of non‐toughened RTM6 resin to a temperature similar to a commercial rubber‐toughened resin, Cycom PR520. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43373.     

Increasing single-lap joint strength by adherend curvature-induced residual stresses

Single-lap joint (SLJ) geometry is the most widely used type of adhesive joint geometry. In this joint, peel stresses occur at the overlap ends due to load eccentricity and the presence of shear-free adhesive termination surfaces. These peel stresses, along with the transverse tensile stresses which occur along the overlap longitudinal axes, and adhesive shear stresses, ultimately cause joint failure. Obviously, reductions in these stresses should result in higher joint strength and increased load capacity. To this end, we exploited elastic spring-back capability of (steel) metal adherends by initially forming curved segments of varying arc lengths and radii at overlap ends. These adherends with curved-end sections were then bonded in single-lap configuration, simply by applying sufficient bonding pressure to elastically flatten the curved segments to result in typically flat overlap sections subsequent to adhesive cure and the removal of bonding pressure. Since the elastic adherend overlap ends tend to revert back to their initial curved form, they exert compressive residual stresses on the adhesive layer in the overlap end regions. We determined that the compressive residual stresses induced in this fashion considerably increased the load capacity of SLJs subjected to tension.