Spin Dependent Hopping in Ti Doped La0.67 Ca0.33 MnO3

A systematic investigation of the magnetic and transport properties of Ti doped La0.67Ca0.33MnO3 was reported. The Ti substitution for Mn ions results in a reduction in ferromagnetism and conductivity. The metal-insulator transition temperature is close to Curie temperature which decreases from 274 to 82 K as x increases from 0 to 0.17. The most important effect of Ti doping is to introduce spin clusters in the samples due to the distortion of local lattice and the inhomogeneous magnetic structure induced primarily by the random distribution of Mn ions. A maximum magnetoresistance ratio as large as 90% in 1 T at 122 K was obtained for the sample with x =0. 055, which is four times larger than that obtained for LCMO sample at 272 K. There is a remarkable field-history dependent MR in the cooling process for the doped samples while such phenomenon disappears in the warming run. The resistivity follows well the variable range hopping behavior in paramagnetic state. Both the size effect and spin dependent hopping of carriers between the spin clusters should be considered in this system.     

Plasma properties of laser-ablated St target in air

Ｐｌａｓｍａｐｒｏｐｅｒｔｉｅｓｏｆｌａｓｅｒ－ａｂｌａｔｅｄＳｔｔａｒｇｅｔｉｎａｉｒＷａｎｇＸｉａｎｇ－Ｔａｉ（王象泰）；ＭａｎＢａｏ－Ｙｕａｎ（满宝元）；ＷａｎｇＧｏｎｇ－Ｔａｎｇ（王公堂）；ＦａｎＸｉ－Ｊｕｎ（樊锡君）；ＷａｎｇＪｕｎ（王军）...     

CEMS AND COUPLING EFFECT OF INTERLAYERS IN MULTILAYERED FeSi/Si AMORPHOUS FILMS

Multilayered FeSi/Si amorphous films with fixed FeSi layer thickness and different Si layer thicknesses have been studied by conversion electron Mossbauer spectroscopy at room temperature. The results showed that with decreasing the Si layer thickness, the hyperfine field of samples increased and the thickness of interface dead layers arisen from the atomic interdiffusion effect decreased. These are due to the coupling effect between the magnetic layers. When the Si layers are thinner than 0.88 nm, the direction of the magnetization is out of the film plane.     

多晶材质电子结构及热电性能的模拟

发展了一种研究多晶体系电子态以及热电性质的计算机模拟方法。首先采用相场动力学方法模拟多晶材质图案，再利用其模型序参量构造晶界的势函数，用近自由电子近似构造体系的哈密顿量。求解薛定谔方程得到体系的本征态。通过电荷密度的分布研究电子的限域特征,分析模拟结果发现对于晶界为势垒的情况，电子的基态出现在最大晶粒中；而对于晶界为势阱的情况，电子更容易限域在多个晶粒交叉的晶界附近，由得到的本征能级和波函数可以计算出温差导致的电位差，即得到赛贝克系数随温度的变化。结果表明具有导电晶界的多晶体的赛贝克系数要高于具有导电晶粒的多晶体。     

激光烧蚀硅所生成的等离子体发射光谱特性

报道由Ｑ－开关Ｎｄ：ＹＡＧ激光器产生的１．０６μｍ、１０ｎｓ的脉冲激光辐射大气中的硅靶所产生的等离子体发射光谱的研究结果。当作用在硅靶表面的功率密度为９．３×１０９Ｗ／ｃｍ２时，测定了等离子体在２００～８８０ｎｍ波长范围内的时间分辨发射光谱。估计了等离子体点燃的时间，测定了等离子体中硅原子的推进速度，讨论了等离子体中Ｎ＋离子产生的原因。通过测量等离子体辐射谱线的半高宽随延迟时间的变化．得到等离子体中电子密度随时间的延迟近似地以ｅｘｐ（－ｔ１／２）的关系衰减。     

聚对苯撑齐聚物的中性态和掺杂态的几何结构特征

采用半经验的Austin Model1(AMl）方法,计算了齐聚物poly(p-phenylene）（PPP）的中性态和带电态的几何结构性质。与中性态相比,带电态下其分子结构表现在C－C键的键长及环与环间的扭转角发生显著的改变。单电荷掺杂导致化子元激发,双电荷掺杂产生双极化子,即使增加链长至12PPP,仍在链中产生双极化子而不是两个分立的单极化子。     

基于自定义特征检测模板的快速眼睛定位方法

眼睛准确定位是虹膜识别和人脸识别的重要步骤．介绍了一种适合实时处理的快速眼睛定位方法．利用数学形态学提取头部图像，提出一种新的特征检测模板，再结合投影算法和人脸结构特征定位眼睛．试验结果表明此算法具有很好的实时性、准确性和鲁棒性．     

Co掺杂的ZnO单晶薄膜的分子束外延及其室温铁磁性

研究了Co掺杂的ZnO单晶薄膜的分子束外延、结构、光学和磁学性质.利用分子束外延技术,在蓝宝石(0001)衬底上外延得到Co掺杂的Zn1-xCoxO(0≤x≤0.12)单晶薄膜.光透射谱和原位的X光电子能谱显示Co离子代替了ZnO晶格中部分Zn的位置.Zn1-xCoxO单晶薄膜具有内禀的铁磁性,并且居里温度高于室温.样品的铁磁性随着Co掺杂量x(x≤0.12)的增加而单调增大.     

Nb5+的掺杂引起La0.67Sr0.33MnO3增强的磁电阻效应

将Nb2O5掺杂到用溶胶-凝胶法制备的La0.67Sr0.33MnO3(LSMO)微粉中,XRD测量结果表明所有样品均为单相菱面结构.随着Nb5 掺杂量的增加,材料电阻率发生显著变化.在x=0.06的掺杂样品中得到最高为1110Ω·cm电阻率(x是掺入的Nb离子与母体材料的摩尔比),比LSMO高5个数量级,这是由于晶界处以及颗粒内部增加的自旋相关的散射和隧穿效应所致.Nb5 离子的掺杂使样品的低场磁电阻(LFMR)和高场磁电阻(HFMR)效应都有所增强.77K下,0.1和1T磁场下在x=0.07样品中分别得到25%和42%的磁电阻效应,分别是LSMO样品的2倍和1.7倍.室温下x=0.03样品的磁电阻最大,为7%.其中,LFMR来源于颗粒晶界处电子的自旋相关隧穿及散射作用,而HFMR来源于表面层的自旋非共线结构.     

Effect of Interstitial Atom Nitrogen on Properties of RE2Fe17 Compounds

The electronic structure and atomic magnetic moments of clusters NdFe6, NdFe6N3 and Fe8 with a dumbbell atom-pair in rare earth-transition element compounds NdEFe17Nx(x=0, 3) were studied by spin-polarized MS-Xα method. The results are as follows: There are three negative exchange couplings between Fe(c) and Fe(f) atoms in Nd2Fe17, which occur at their odd parity orbitals. Compared to the results of α-Fe calculated by the MS-Xα method, the low Curie temperature of compounds RE2Fe17 can be explained satisfactorily. (2) There is only one weaker negative exchange coupling orbital leaving in between Fe(c) and Fe(f) sites in Nd2Fe17N3. These results may be helpful for understanding the effect of interstitial atom M(M=N, H or C) in Fe2Fe17Mx on Curie temperature. The other key factors affecting the Fe-Fe exchange coupling in Fe2Fe17 compounds were also discussed.