基于氧化石墨烯/金纳米棒复合基底的SERS性能分析

以具有拉曼散射表面活性的金纳米棒(AuNRs)与氧化石墨烯(GO)溶液混合。通过控制AuNRs的尺寸、用量,抽滤制得氧化石墨烯/金纳米棒(GO/AuNRs)复合薄膜。利用紫外-可见分光光度计、透射电子显微镜(TEM)对制得的GO/AuNRs进行了表征和分析,并且采用拉曼光谱研究GO/AuNRs基底的表面增强散射(SERS)效应。结果表明,GO/AuNRs基底的SERS性能能够对芳香烃类大分子物质起到信号增强的作用。以罗丹明B(RhB)为探针分子验证其拉曼增强效应,在超微量浓度时依然具有较强的拉曼信号,增强因子达到2250。     

直孔阳极支撑体及阳极功能层的制备方法及其单电池性能

采用海藻酸盐离子凝胶法制备直孔Ni–YSZ阳极支撑体,制备了一体化的Ni–YSZ阳极支撑体及阳极功能层(AFL).直孔Ni–YSZ阳极支撑体内分布着大量直通孔道,孔径约为80μm,采用浆料旋涂法在其上制备的Ni–YSZ阳极功能层厚度为130μm.而采用一体化法制备的阳极支撑体,其孔道呈发散状分布,孔径在20～60μm之...     

微米粉体制备阳极支撑的YSZ薄膜

采用微米级YSZ(摩尔分数8%Y2O3稳定的ZrO2)粉体在NiO/YSZ阳极支撑体上成功地制备了致密的电解质薄膜.对微米级YSZ粉体进行球磨处理,分析和讨论了球磨对YSZ粉体及薄膜性能的影响.用浆料旋涂法制得45μm厚的致密薄膜,电池700 ℃时开路电压(OCV)达到1.13 V.以氢气为燃料,以静态环境空气为氧化气体,单电池在700、750、800 ℃的最大比功率分别为221、364、528 mW/cm2.电池阻抗谱结果表明电池的性能主要由电极决定.     

阳极功能层对燃料电池性能的影响

用浆料旋涂法在阳极支撑体上制备了阳极功能层(AFL).研究了AFL厚度对电池输出性能的影响.实验结果表明:AFL降低了阳极支撑体/电解质界面的接触电阻,增加了阳极的三相反应界面,但是AFL厚度的增加导致了界面接触电阻和气相扩散阻抗的增大.AFL的最佳厚度为4 μm.采用4 μm的AFL和La0.7Sr0.3MnO3/Sm0.2Ce0.8O1.9阴极,电池在700、750、800 ℃的输出性能分别为794、1016、1235 mW/cm2.     

Optical super-resolution effect induced by nonlinear characteristics of graphene oxide films

In this work, we focus on the optical super-resolution effect induced by strong nonlinear saturation absorption (NSA) of graphene oxide (GO) membranes. The third-order optical nonlinearities are characterized by the canonical Z-scan technique under femtosecond laser (wavelength:800 nm, pulse width:100 fs) excitation. Through controlling the applied femtosecond laser energy, NSA of the GO films can be tuned continuously. The GO film is placed at the focal plane as a unique amplitude filter to improve the resolution of the focused field. A multi-layer system model is proposed to present the generation of a deep sub-wavelength spot associated with the nonlinearity of GO films. Moreover, the parameter conditions to achieve the best resolution (~l/6) are determined entirely. The demonstrated results here are useful for high density optical recoding and storage, nanolithography, and super-resolution optical imaging.     

基于交替浸渍法对La0.65Sr0.35MnO3氧电极的性能优化

氢能以其高效、清洁、可再生的优点成为化石能源的有效替代者,而可逆固体氧化物电池(RSOC)既可利用氢气输出电能,也可电解H₂O产生氢气,对其研究具有十分重要的意义。本文对RSOC的氧电极进行了研究,在La_0.65Sr_0.35MnO₃(LSM)氧电极的基础上,采用溶液交替浸渍法将Sm_0.2Ce_0.8O_1.9(SDC)和Sm_0.5Sr_0.5CoO_3-δ(SSC)纳米粒子引入LSM氧电极中。800℃时,交替浸渍1次的LSM-SDC-SSC1氧电极的极化电阻为0.49Ω·cm²,是纯LSM电极(1.12Ω·cm²)的43%。SDC和SSC的浸渍顺序对电极形貌和性能的影响随着浸渍次数的增加逐渐减弱,交替浸渍2次的LSM-SDC-SSC2氧电极具有最低的极化过电位和极化电阻。800℃时,Ni-(Y₂O₃     

直通孔陶瓷在固体氧化物燃料电池中的应用

采用海藻酸钠自组装法制备了具有定向直通孔道的氧化钇稳定氧化锆(YSZ)支撑体,向多孔支撑体内部浸渍Ni纳米粒子得到固体氧化物燃料电池的阳极。结果表明:YSZ支撑体的孔径随固相含量的增大而减小,同时也随着CaCl₂溶液浓度的增大而减小。使用氢气为燃料、空气为氧化剂,Ni–YSZ/YSZ/LSM–SDC电池在650℃的开路电压在1 V以上,800℃时的最大功率密度为225 m W/cm²。通过调节阳极的孔隙率及电解质厚度有望大幅度提高电池的输出性能,实现直通孔陶瓷在固体氧化物燃料电池上的应用。     

酒醅发酵过程的多参数自动监测系统

为了监测酒醅发酵过程中的温度、湿度、酸碱度、含氧量,设计一个实时自动监测系统包括测控计算机子系统、无线数据接收转发及接收器、多路多参数子系统、发酵参数测量传感器组。该过程主要由传感器组检测,经由导线到信号变送器,再由多路多参数智能子系统相应信息输入无线信号发送器发送,在接收端有无线信号接收器送至计算机控制系统。传感器的使用使得多路多参数系统的工作情况通过模拟信号由模数转换器完成翻译、时序等工作,由单片机进行控制最终输入。     

AlGaInAs/InP应变补偿多量子阱激光器

为了优化在长距离光纤通讯系统中采用的1.31μm波长的量子阱激光器,对AlGaInAs/InP材料的有源区应变补偿的量子阱激光器进行了设计研究。采用应变补偿的方法,根据克龙尼克-潘纳模型理论计算出量子阱的能带结构,设计出有源区由1.12%的压应变AlGaInAs阱层和0.4%的张应变AlGaInAs垒层构成。使用ALDS软件对所设计出的器件进行了建模仿真,对其进行了阈值分析和稳态分析。结果表明,在室温25℃下,该激光器具有9mA的低阈值电流和0.4W/A较高的单面斜率效率;在势垒层采用与势阱层应变相反的适当应变,可以降低生长过程中的平均应变量,保证有源区良好的生长,改善量子阱结构的能带结构,提高对载流子的限制能力,降低阈值电流,提高饱和功率,改善器件的性能。     

Super-resolution longitudinally polarized light needle achieved by tightly focusing radially polarized beams

Based on the vector diffraction theory, a super-resolution longitudinally polarized optical needle with ultra-long depth of focus (DOF) is generated by tightly focusing a radially polarized beam that is modulated by a self-designed ternary hybrid (phase/amplitude) filter (THF). Both the phase and the amplitude patterns of THF are judiciously optimized by the versatile particle swarm optimization (PSO) searching algorithm. For the focusing configuration with a combination of a high numerical aperture (NA) and the optimized sine-shaped THFs, an optical needle with the full width at half maximum (FWHM) of 0.414λ and the DOF of 7.58λ is accessed, which corresponds to an aspect ratio of 18.3. The demonstrated longitudinally polarized super-resolution light needle with high aspect ratio opens up broad applications in high-density optical data storage, nano-photolithography, super-resolution imaging and high-efficiency particle trapping. This work has been supported by the National Natural Science Foundation of China (Nos.61575139, 61605136, 51602213 and 11604236), and the Youth Foundation of the Taiyuan University of Technology (No.2015QN066). This paper was recommended by the 9th International Conference on Information Optics and Photonics (CIOP 2017). E-mail:niezhongquan@tyut.edu.cn