排序方式: 共有18条查询结果,搜索用时 0 毫秒
1.
2.
A novel poly(N-isopropylacrylamide)-based sandwich-typed hydrogel,which was featured with both ends of linear poly(N-isopropylacrylamide)(PNIPAM)chains being grafted onto cross-linked PNIPAM chains,was successfully prepared in a three-step process by a method of sequential synthesis.The proposed hydrogel displays faster and hydration/dehydration dynamic response to temperature cycling owing to linear PNIPAM chains to form big-pore structure.This work may lead to high attraction for targeting drug delivery systems,polymeric pump,sensors and so on. 相似文献
3.
温度感应式开关膜的接枝率对其开关特性的影响 总被引:1,自引:0,他引:1
利用等离子体诱导填孔接枝聚合法将聚(N-异丙基丙烯酰胺)(PNIPAM)接枝聚合在聚偏氟乙烯(PVDF)微孔膜上制备了一系列具有较宽接枝率范围的温度感应式开关膜。系统地研究了接枝率对膜的温度感应开关特性的影响。结果表明,开关膜的接枝率对膜的过滤通量、温度感应开关系数和膜孔径感温变化倍数都有十分重要的影响,接枝率在小于等于2.81%时。温度感应开关系数和膜孔径感温变化倍数均随接枝率增加而增加;而对于接枝率大于等于6.38%的膜,膜开关系数和膜孔径感温变化倍数总是趋近于1。膜不具备温度感应开关特性,为了获得预期的开关性能。必须将膜的接枝率控制在适当的范围。 相似文献
4.
简要综述了感温型凝胶微粒的微观结构,及其制备方法和影响其膨胀—收缩性能的主要因素等方面的研究进展。迄今凝胶微粒按微观结构可分为均质型和核—壳型两大类。制备均质结构凝胶微粒常采用无皂轧液聚合;制备核—壳结构时,常先采用无皂轧液合成核颗粒,再在核表面通过包缚或接枝分别形成交联式或线形凝胶壳层。为了使凝胶微粒有较大的体积膨胀率和温度感应速度,常在制备壳层时在单体溶液中加入一些离子基团。凝胶微粒的温度感应特性会随化学环境的变化而不同。 相似文献
5.
Monodisperse microspheres (mean diameter 200–300 nm) with polystyrene cores and poly(acrylamide-co-butyl methacrylate) shells were prepared by using a free radical polymerization method. Moreover, the effect of mixed solvent on the preparation, morphology and monodispersity was investigated. The experimental results showed that solubility parameter of butyl methacrylate and solvent affected mainly the molding of monodisperse core-shell microspheres. When the microspheres were fabricated in a sequential synthesis process, addition of hydrophilic and organic solvent including butyl methacrylate led to spherical degree of the particles becoming worse, and the mean diameter of the microspheres decreased and the monodispersity became better with increasing the crosslinker methylenebisacrylamide dosage. 相似文献
6.
7.
A novel thermo-responsive hydrogel column, featured with both ends of linear poly(N-isopropylacrylamide) (PNIPAM) chains being grafted onto cross-linked PNIPAM chains, was reported. The laterally sandwich-typed hydrogel columns were fabricated by radical polymerization in a three-step process using a method of ice-melting synthesis. The initiating path, morphology and thermoresponsive characteristics of the prepared hydrogel columns were experimentally studied. The results show that the hydrogel column obtained by the initiator inside part has more quick swelling and deswelling rates responsing to temperature cycling than other hydrogels owing to linear PNIPAM chains to form supermacroporous structure. The proposed hydrogel structure provide a new mode of the phase transition behavior for thermo-sensitive "smart" or "intelligent" monodisperse micro-actuators, which is highly attractive for targeting drug delivery systems, chemical separations, and sensors and so on. 相似文献
8.
9.
引 言随着油田水处理技术的发展 ,除油旋流器的使用越来越普遍 .油滴粒径是影响油水分离旋流器性能的一个重要因素 ,它直接影响到旋流器的分离效率及含油污水处理能力 ,防止油滴破碎是油水分离旋流器研究者们共同感兴趣的问题 ,本文研究了旋流器进口粒径变化与旋流器各段分离效率之间的关系以及进口流量、分流比等对旋流器各段边壁油滴粒径的影响 .1 实验装置实验流程如图 1所示 .清水由螺杆泵输送 ,通过螺杆泵可以调节旋流器的进口流量 .油由计量泵注入螺杆泵入口管线中 ,与水充分混合 ,通过调节计量泵的流量可以调节油水混合物的油含量 … 相似文献
10.