2,4,6-Triphenyl- thiazolo[3,2-a]-s-Triazine as a Stabilizer for single base propellant

2,4,6-Triphenyl-2,3,4,7-tetrahydro-thiazolo[3,2-a]-s-triazine is used as a stabilizer for single base propellant and gave good results with the stability tests. Comparing the results of the stability and storage tests at 80°C, 90°C and 100°C with the results of the same tests after using diphenylamine instead of the thiazolo compound gave the same results without difference between the two stabilizers.     

An area-efficient VLSI implementation for programmable FIR filters based on a parameterized divide and conquer approach

In this paper, we propose an optimal VLSI implementation for a class of programmable FIR filters with binary coefficients, whose architecture is based on a parameterized divide and conquer approach. The proposed design is shown to be easily extendable to FIR filters with multibit coefficients of arbitrary sign. The area efficiency achieved in comparison to direct form realization is demonstrated by VLSI implementation examples, synthesized in TSMC 0.18-μm single poly six metal layer CMOS process using state-of-art VLSI EDA tools. The possible saving in average power consumption is estimated using gate-level power analysis. Suggestions for applications and topics for further research conclude the paper.     

On the Dieudonné Theorem in Reflexive Banach Spaces

The converse part of the Dieudonné theorem on the closedness of the difference of two closed convex sets is establish. It is proved that, in a reflexive Banach setting, the sufficient conditions given by Dieudonné when applied for the weak topology, are also necessary.     

Some Semiconductor Properties of Carboxymethyl Cellulose-Copper Complexes

Metal chelates of three grades of carboxymethyl cellulose (CMC) (LI-L3) with Cu(II) ions, either originating from CuCl₂ or CuSO₄, were prepared and characterized by elemental analysis, infrared spectra, and electrical conductivity studies. The results showed that the degree of substitution of CMCs and the origin of the Cu(II) ion have a profound effect on the amount of metal included in the polymer complexes and the structure and the electrical conductivity of the prepared complexes. CMC acts as a uninegatively charged bidentate ligand when it is chelated with Cu(II) of CuCl₂ via the carboxymethyl group and exhibits the formula Cu(L)₂, whereas it acts as a binegatively charged bitentate ligand when it is chelated with CuSO₄ via the carboxymethyl and secondary hydroxyl groups and exhibits the formula CuL.2H₂O. The investigation revealed that the electrical conductivity depends on the temperature and has two maximum peaks. The values of the activation energy for the conductivity of CMC and their complexes indicated that the samples changed from a low-semiconductor to a high-semiconductor property with heating. It is found that CMC-Cu(II) complexes formed from CuSO₄ exhibit a high-semiconductor property compared to complexes derived from CuCl₂.     

Measurement of Power Frequency Fluctuations Using the FFT

A new method for detecting fluctuations in the fundamental frequency component of a power system, by relating it to a leakage coefficient in the FFT, is presented. The phenomenon of leakage in the FFT is used advantageously to increase spectral resolution. The leakage coefficient is a quantitative measure of the deviation from the fundamental frequency component with respect to the sampling frequency. Theoretical aspects are considered along with a method for on-line implementation.     

Application of active power sensitivity to frequency and voltage variations on load shedding

The occurrence of a large disturbance in a power system can lead to a decline in the system frequency and bus voltages due to a real and reactive power deficiency or due to the formation of islands with generation–load imbalance. Load shedding is an emergency control action that can prevent a blackout in the power system by relieving the overload in some parts of the system. This paper shows that rate of change of frequency can be utilized to determine the magnitude of generation–load imbalance, while the rate of change of voltage with respect to active power can be utilized to identify the sensitive bus for load shedding. The frequency, voltages and their rate of change can be obtained by means of measurements in real-time from various devices such as digital recorders or phasor measurement units or these parameters can be estimated from the voltage data by other means such as an optimal estimation method like Kalman filtering. The rate of change of system frequency, along with the equivalent system inertia may be used to estimate the magnitude of the disturbance prior to each load shedding step. The buses with a higher rate of change of voltage may be identified as the critical ones for load shedding and load can be first shed at these buses, depending on the change in the power flow at each bus. This application is tested on the IEEE 30 bus system and the preliminary results demonstrate that it is feasible to be used in load shedding to restore system voltage and frequency.     

Metrological characterization of a Primary Vickers Hardness Standard Machine — NIS Egypt

The main goal of NIS is to provide traceability to international measurement standards to help the Egyptian industry to penetrate world markets. One of the most important fields of metrology is hardness measurements. A Primary Vickers Hardness Standard Machine (PVHM) was designed to improve the capabilities to qualify the primary hardness test blocks locally. The machine has been constructed to perform Vickers hardness test for scales HV10, HV20, HV30, and HV50 with expanded uncertainty of ±1.4 %. This standard machine has been metrologically characterized by NIS. In this paper metrological characterization of the machine will be shown. The characterization includes the methods and results of direct verification of influences parameters (test forces, indentation measuring system, indenter and test cycle time), and a comparison with PTB standard machine.     

Reactions with Thiazolo[3,2-b]-s-triazol-3(2H)-ones

5-Aryl-3-carboxymethylthio-1,2,4-triazoles 2 are cyclised to 6-arylthiazolo[3,2-b]-s-triazol-3(2H)-ones 3 . This structural assignment has been based on IR and NMR spectra. 2-Arylmethylene-6-arylthiazolo[3,2-b]-s-triazol-3(2H)-ones 7 were prepared by several methods. Compounds 3 coupled with diazotised anilines to give 2,3-dihydro-6-arylthiazolo[3,2-b]-s-triazole-2,3-dione 2-arylhydrazones 8 . The action of amines on 3a opens the thiazolone ring with the formation of substituted (5-phenyltriazol-3-ylthio)-acetamides 9 .     

Influence of γ-irradiation on proton spin–lattice relaxation of SBR used as antirads and its ESR investigation

Proton spin–lattice relaxation time t₁ was measured on SBR samples with carbon black or kaolin filler using modified linseed oil. The NMR pulse technique at 90MHz was used in the temperature range from 180 to 400 K. The temperature dependence of t₁ indicates that samples filled with carbon black have similar molecular dynamics to the standard unfilled SBR samples. The activation energy for the motion of the main chain for these samples amounts to 16.4kJ/mol. Samples containing linseed oil modified with para-toluidine showed an activation energy of about 14.6kJ/mol and were not affected by γ-irradiation. Values of the minimum relaxation time t^min₁ were increased by γ-irradiation in comparison with a standard SBR sample. ESR measurements carried out at room temperature by means of an X-band spectrometer indicated that unidentified radicals within the rubber were formed during its mastication with vulcanizing additives. The ESR spectra did not change during the vulcanization process. Samples filled with carbon black showed a broadening of the ESR line; this is consistent with the increase in the electrical conductivity.     

Using neural networks in the identification of Preisach-typehysteresis models

The identification process of the classical Preisach-type hysteresis model reduces to the determination of the weight function of elementary hysteresis operators upon which the model is built. It is well known that the classical Preisach model can exactly represent hysteretic nonlinearities which exhibit wiping-out and congruency properties. In that case, the model identification can be analytically and systematically accomplished by using first-order reversal curves. If the congruency property is not exactly valid, the Preisach model can only be used as an approximation. It is possible to improve the model accuracy in this situation by incorporating more appropriate experimental data during the identification stage. However, performing this process using the traditional systematic techniques becomes almost impossible. In this paper, the machinery of neural networks is proposed as a tool to accomplish this identification task. The suggested identification approach has been numerically implemented and carried out for a magnetic tape sample that does not possess the congruency property. A comparison between measured data and model predictions suggests that the proposed identification approach yields more accurate results