Mixed Micelles of Surface Active Ionic Liquid (SAIL)–Octylphenol Ethoxylate: A Novel Reaction Medium for Selective Oxidation of Toluene to Benzaldehyde

Ionic liquids have been found to be suitable alternatives to volatile organic solvents in chemical transformation. Through a proper choice of cations and anions, the properties of an ionic liquid can be tuned so that it resembles an amphiphile. Such specially designed molecules are known as surface-active ionic liquids (SAIL). Like conventional surfactants, SAIL also form aggregates in an aqueous medium. Studies show that the mixing of SAIL with conventional surfactants leads to synergistic micellization. However, very few reports are available on the application of such systems as reaction media. Present study focuses on the application of mixed micelles of 1-tetradecyl-3-methylimidazol-1-ium bromide, ([C₁₄mim]Br) with nonionic surfactant, Octylphenol ethoxylate with 10 moles of ethylene oxide (OPE-10). Enhanced solubilization and selective catalytic oxidation of toluene using hydrogen peroxide as an oxidant and tungstic acid as a catalyst have been studied in detail using this system.     

Transforming Vulnerability Indexing for Saltwater Intrusion into Risk Indexing through a Fuzzy Catastrophe Scheme

Mapping vulnerability to Saltwater Intrusion (SWI) in coastal aquifers is studied in this paper using the GALDIT framework but with a novelty of transforming the concept of vulnerability indexing to risk indexing. GALDIT is the acronym of 6 data layers, which are put consensually together to invoke a sense of vulnerability to the intrusion of saltwater against aquifers with freshwater. It is a scoring system of prescribed rates to account for local variations; and prescribed weights to account for relative importance of each data layer but these suffer from subjectivity. Another novelty of the paper is to use fuzzy logic to learn rate values and catastrophe theory to learn weight values and these together are implemented as a scheme and hence Fuzzy-Catastrophe Scheme (FCS). The GALDIT data layers are divided into two groups of Passive Vulnerability Indices (PVI) and Active Vulnerability Indices (AVI), where their sum is Total Vulnerability Index (TVI) and equivalent to GALDIT. Two additional data layers (Pumping and Water table decline) are also introduced to serve as Risk Actuation Index (RAI). The product of TVI and RAI yields Risk Indices. The paper applies these new concepts to a study area, subject to groundwater decline and a possible saltwater intrusion problem. The results provide a proof-of-concept for PVI, AVI, RAI and RI by studying their correlation with groundwater quality samples using the fraction of saltwater (f_sea), Groundwater Quality Indices (GQI) and Piper diagram. Significant correlations between the appropriate values are found and these provide a new insight for the study area.

     

Lichtenstein herniotomy

All standard methods of hernia repair involve suturing together tissues which are not normally in apposition. This violates the basic surgical principle that tissue must never be approximated under tension and accounts for an unacceptable number of failures. Total reinforcement of the inguinal floor with a sheet of suitable biomaterial and employment of a "tension-free" technique is a more effective approach. Since June 1984, 3250 primary inguinal hernias have been repaired at the Lichtenstein Hernia Institute by the open tension-free technique using Marlex mesh. All operations were performed under local anesthesia. Patients were discharged from the hospital within two or four hours after the operation. The patients were followed from one to 8 years by physician examination. The follow-up rate was 87%. There were four recurrences. The causes of recurrence and how to avoid them are discussed.     

Mass‐transfer enhancement in single drop extraction in the presence of magnetic nanoparticles and magnetic field

Magnetite nanoparticles with an average particle size of 28.8 nm were synthesized, coated with oleic acid, and characterized using various techniques such as DLS, FT‐IR, SEM, XRD, VSM, and UV‐Vis analysis. A nanofluid consisting of synthesized nanoparticles and 5 wt % acetic acid in toluene as the dispersed phase was prepared and used in the chemical test system, Toluene‐Acetic Acid‐Water, for the single drop extraction in the presence and absence of an external oscillating magnetic field. Influences of various operating and design parameters such as nanoparticle concentration, drop diameter, and the applied current and frequency on the overall mass‐transfer coefficients for the mass‐transfer direction from d→c were investigated carefully. The obtained results were used to propose a general correlation for the mass‐transfer enhancement. It was found that the maximum mass‐transfer enhancement compared with that obtained in the absence of nanoparticles and the oscillating magnetic field is about 259%. © 2016 American Institute of Chemical Engineers AIChE J, 62: 4466–4479, 2016     

Silica aerogel/epoxy nanocomposites: Mechanical,vibrational, and morphological properties

The present study was an attempt to examine the effects that adding silica aerogel (SA) nanoparticles to epoxy would exert on its mechanical, vibrational, and morphological properties. Neat epoxy was consecutively combined with 1, 2, and 4 wt% of SA nanoparticles. A number of tests of mechanical properties were then performed on the samples, including tests of tensile, bending, compressive, dynamic mechanical thermal, hardness, and Izod impact. Vibration and water uptake tests were also conducted on the samples. The highest modulus and strength values were found in the nanocomposite sample with 4 wt% of SA, and the highest toughness and elongation values were detected in the sample with 1 wt% of SA. Furthermore, adding the SA nanoparticles to the epoxy improved the energy absorption and hardness of the epoxy matrix. The findings from the tests of dynamic mechanical thermal and vibration properties demonstrated that, with an increase in the nanoparticles content in the samples, the values of storage modulus and natural frequency increased while the values of tan δ and damping ratios decreased. A comparison between the values of natural frequency from the vibration test and the values from the Euler–Bernoulli beam theory showed a good agreement between the theoretical and experimental results.     

Fatigue and fracture properties of thin metallic foils

Metallic thin foils are essential structural parts in microsystems,which may be subjected to fatigue loading caused by thermal fluctuations and mechanical vibrations influencing their reliability in numerous engineering applications. It is well known that the fatigue properties of bulk material cannot be adopted for small scaled structures. For a better understanding of the `size-effect' in the present investigation fatigue crack growth near threshold in the high cycle fatigue regime and associated fracture processes were studied. Free- standing rolled and electrodeposited Cu-, Mo- and Al foils of thickness from 20 m to 250 m in different conditions have been tested in a special experimental set up operating at R=–1 and a testing frequency of 20 kHz. At a given constant strain value the fatigue crack growth behaviour has been recorded accompanied by intermittent observation of the change of the dislocation structure in the vicinity of the growing crack by use of the electron channeling contrast imaging (ECCI)-technique in a scanning electron microscope (SEM). In a load shedding technique fatigue threshold stress intensity factor values have been derived and compared with data of bulk material. Typical crack growth features were detected depending on thickness and grain sizes of the foils. Various criteria (compliance, extent of plastic zones and plastic strain gradients) were selected for the explanation of this anomalous behaviour. Additionally fractomicrographs of uniaxial strained and fatigued foils have been studied to obtain further insight of the effect of dimensional constraint.     

Modelling Energy Dissipation Over Stepped-gabion Weirs by Artificial Intelligence

The hydraulics of energy dissipation over stepped-gabion weirs is investigated by carrying out a series of laboratory experiments, building models to explain the experimental data, and testing their robustness by using the data reported by other researchers. The experiments comprise: six different stepped-gabion weirs tested in a horizontal laboratory flume, a wide range of discharge values, two weir slopes (V:H): 1:1 and 1:2, and gabion filling material gravel size (porosity equal to 38 %, 40 % and 42 %). These experimental setups were selected to ensure the development of both the nappe and skimming flow regimes within the measured dataset. The models developed for computing energy dissipation over stepped-gabion weirs comprise: multiple regression equations based on dimensional analysis theory, Artificial Neural Network (ANN) and Gene Expression Programming (GEP). The analysis shows that the measured data capture both flow regimes and the transition in between them and above all, and by using all of the data, it may be possible to identify the range of each regime. Energy dissipation modelled by the ANN formulation is successful and may be recommended for reliable estimates but those by GEP and regression analysis can still serve for rough-and-ready estimates in engineering applications.     

Friction Parameters for Flows in Nearly Flat Tidal Channels

A numerical study of friction parameters associated with nearly flat tidal channels is reported. Such empirical parameters are often back-calculated using complex flow equations through a procedure referred to as “inverse problems.” However, estimates of friction parameters of tidal channels are liable to substantial uncertainties if water levels are used in their inverse problems. Even if the parameters are optimized by mathematically comparing gauged and simulated values, the inverse problem must satisfy the quality conditions of “uniqueness,” “identifiability,” and “stability.” To obtain an insight into the problem, this paper focuses on flows where these conditions may not hold. The study concludes that friction parameters can be unidentifiable if the inverse problem employs gauged high tide water levels, because the effect of storage on water level dominates over friction. Gauged discharge values render identifiable, stable, and unique estimates of friction parameters even at high tides, but this is not a practical proposition. Low tide levels should be used to determine friction parameters, as the use of high-tide water levels can make friction parameters, and subsequently simulated discharge values, anomalous.     

Bioavailability Prediction of Polycyclic Aromatic Hydrocarbons in Field-Contaminated Sediment by Mild Extractions

Assessing the bioavailability of a group of polycyclic aromatic hydrocarbons (PAHs) coexisting in a field-aged contaminated sediment was examined using mild extractions by isopropanol- and ethanol-water solutions at concentrations of 5–100%, using extraction durations from 1?h?to?7?days. At a given solvent concentration, an initial rapid phase of PAH desorption was generally observed during the first 12?h, followed by a subsequent slower phase of desorption. A similar biphasic desorption was evident with increases in solvent concentration. PAH removal by various mild extractions was compared with PAH biodegradation by indigenous microorganisms. The removal of individual PAHs using 1-day 70% ethanol extraction was closely correlated to corresponding PAH removal via biodegradation, suggesting the possibility of using alcohol-water solution to simultaneously predict the bioavailability of multiple PAHs in aged sediments to indigenous microorganisms.