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A model for multispecies ion-exchange kinetics based on the Nernst-Planck equation is suggested. It is analyzed in comparison with the “locally-determinate” model described by Hwang and Helfferich [1]. The model makes possible simple computation. The conditions for the occurrence of unusual kinetic curves with a maximum are clarified. The proposed model is developed for different types of kinetic problems and verified by the experimental investigation of a kinetics in ternary systems.  相似文献   
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Using intermediate, liquid-forming compositions in the (Y,La)2O3-AlN system as additives, fully dense Si3N4 ceramics with high strength at high temperature have been obtained by pressureless sintering. The ceramics contain rod-shaped β-Si3N4 with M' or K' solid solutions as grain-boundary phases. The strength of these ceramics is 1150 MPa at 1200°C, and the room-temperature toughness is maintained at }7 MPa·m1/2. Phase relations that are pertinent to the new additive compositions are delineated to rationalize their beneficial effects on sinterability and mechanical properties.  相似文献   
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Conclusions  
1.  Low-carbon martensitic steels such as 10N3M1.5B can be coated by single-phase boride layers with a low brittleness by a conventional boronizing.
2.  Boronizing by low-carbon martensitic steels from daubs at 910°C for 3 h with cooling in air gives a martensitic structure in the bulk of the part.
3.  Chromium alloying of a martensitic steel causes the formation of a brittle FeB boride in the boronized coat.
4.  The introduction of copper oxide into the slip daub makes it possible to control the phase composition and the structure of the boride layer on low-carbon martensitic steels.
Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 6, pp. 13–16, June, 1999.  相似文献   
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Abstract— The development of a compact, efficient VGA projection module to be embedded in mobile devices is reported. The design incorporates laser/laser diode (LD) light sources, Schlieren optics, and a one‐dimensional diffractive spatial optical modulator (SOM). During development, the optical parameters were determined and the relationships between the parameters to optimize the optical specifications were derived. The resulting optimized specifications enable us to manufacture two types of optical modu les as compact as 13 cc and with as little as 10% speckle contrast ratio.  相似文献   
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We present an implementation of a stochastic optimization algorithm applied to location of atomic vacancies. Our method labels an empty point in space as a vacancy site, if the total spatial overlap of a “virtual sphere”, centered around the point, with the surrounding atoms (and other vacancies) falls below a tolerance parameter. A Metropolis-like algorithm displaces the vacancies randomly, using an “overlap temperature” parameter to allow for acceptance of moves into regions with higher overlap, thus avoiding local minima. Once the algorithm has targeted a point with low overlap, the overlap temperature is decreased, and the method works as a steepest descent optimization.Our method, with only two free parameters, is able to detect the correct number and coordinates of vacancies in a wide spectrum of condensed-matter systems, from crystals to amorphous solids, in fact in any given set of atomic coordinates, without any need of comparison with a reference initial structure.  相似文献   
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Siberia's boreal forests represent an economically and ecologically precious resource, a significant part of which is not monitored on a regular basis. Synthetic aperture radars (SARs), with their sensitivity to forest biomass, offer mapping capabilities that could provide valuable up-to-date information, for example about fire damage or logging activity. The European Commission SIBERIA project had the aim of mapping an area of approximately 1 million km2 in Siberia using SAR data from two satellite sources: the tandem mission of the European Remote Sensing Satellites ERS-1/2 and the Japanese Earth Resource Satellite JERS-1. Mosaics of ERS tandem interferometric coherence and JERS backscattering coefficient show the wealth of information contained in these data but they also show large differences in radar response between neighbouring images. To create one homogeneous forest map, adaptive methods which are able to account for brightness changes due to environmental effects were required. In this paper an adaptive empirical model to determine growing stock volume classes using the ERS tandem coherence and the JERS backscatter data is described. For growing stock volume classes up to 80 m3/ha, accuracies of over 80% are achieved for over a hundred ERS frames at a spatial resolution of 50 m.  相似文献   
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We propose a new type of potentiometric gas sensor operating on the basis of the thermovoltaic effect in uniformly heated (without temperature gradients) ZnO/ZnO–Fe sandwich structures obtained by the sol–gel method. It is established that a significant contribution to the gas responsivity of sensors is related to the thickness of the upper doped layer of the structure.  相似文献   
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