Fast Li+ Transport via Silica Network-Driven Nanochannels in Ionomer-in-Framework for Lithium Metal Batteries

For the development of all-solid-state lithium metal batteries (LMBs), a high-porous silica aerogel (SA)-reinforced single-Li⁺ conducting nanocomposite polymer electrolyte (NPE) is prepared via two-step selective functionalization. The mesoporous SA is introduced as a mechanical framework for NPE as well as a channel for fast lithium cation migration. Two types of monomers containing weak-binding imide anions and Li⁺ cations are synthesized and used to prepare NPEs, where these monomers are grafted in SA to produce SA-based NPEs (SANPEs) as ionomer-in-framework. This hybrid SANPE exhibits high ionic conductivities (≈10⁻³ S cm⁻¹), high modulus (≈10⁵ Pa), high lithium transference number (0.84), and wide electrochemical window (>4.8 V). The resultant SANPE in the lithium symmetric cell possesses long-term cyclic stability without short-circuiting over 800 h under 0.2 mA cm⁻². Furthermore, the LiFePO₄|SANPE|Li solid-state batteries present a high discharge capacity of 167 mAh g⁻¹ at 0.1 C, good rate capability up to 1 C, wide operating temperatures (from −10 to 40 °C), and a stable cycling performance with 97% capacity retention and 100% coulombic efficiency after 75 cycles at 1 C and 25 °C. The SANPE demonstrates a new design principle for solid-state electrolytes, allowing for a perfect complex between inorganic silica and organic polymer, for high-energy-density LMBs.     

Myo-Inositol Limits Kainic Acid-Induced Epileptogenesis in Rats

Epilepsy is a severe neurological disease characterized by spontaneous recurrent seizures (SRS). A complex pathophysiological process referred to as epileptogenesis transforms a normal brain into an epileptic one. Prevention of epileptogenesis is a subject of intensive research. Currently, there are no clinically approved drugs that can act as preventive medication. Our previous studies have revealed highly promising antiepileptogenic properties of a compound–myo-inositol (MI) and the present research broadens previous results and demonstrates the long-term disease-modifying effect of this drug, as well as the amelioration of cognitive comorbidities. For the first time, we show that long-term treatment with MI: (i) decreases the frequency and duration of electrographic SRS in the hippocampus; (ii) has an ameliorating effect on spatial learning and memory deficit associated with epileptogenesis, and (iii) attenuates cell loss in the hippocampus. MI treatment also alters the expression of the glial fibrillary acidic protein, LRRC8A subunit of volume-regulated anion channels, and protein tyrosine phosphatase receptor type R, all expected to counteract the epileptogenesis. All these effects are still present even 4 weeks after MI treatment ceased. This suggests that MI may exert multiple actions on various epileptogenesis-associated changes in the brain and, therefore, could be considered as a candidate target for prevention of epileptogenesis.     

Effect of cooking on the nutritive value of koko/kosai—A traditional breakfast meal of the hausas in Northern Nigeria

The effect of cooking on the nutritive value of koko/kosai was assessed by chemical analysis. There was significant loss in the proximate composition due to cooking. In addition, losses of some mineral elements and vitamins were observed. The losses in potassium, iron, zinc and phosphorus were found to be 23%, 6·7%, 25% and 13·3%, respectively.Losses of vitamins B₁, B₂, C and carotene were found to be 20%, 46%, 37% and 9·6%, respectively.The amino acid pattern of the koko/kosai was only slightly affected by the traditional method of cooking employed. Some suggestions and recommendations are made on how to retain most of the nutrients when cooking the meals.     

Adaptive wire bow-tie antenna for GPR applications

In this paper, the basic design of an adaptive ground penetrating radar antenna is introduced. The antenna is able to adapt its input impedance to a variation in the antenna elevation and soil type to keep reflections at the antenna's terminal minimum. As a result, energy transfer from the generator to the antenna is maximized, which in turn maximizes the energy radiated by the antenna into the ground for different antenna elevations and soil types. The antenna is based on a wire bow-tie structure with variable flare angle for adjusting the antenna's input impedance. The flare angle variation is realized by short-circuiting the gaps separating the wires from the feed point of the antenna, for which electronic switching devices such as PIN diodes could be used to allow fast and convenient control of the antenna's flare angle.     

Capturing of transition by the RNG based algebraic turbulence model

This paper concerns the RNG based algebraic turbulence model. This model has characteristics to capture transitional process from laminar to turbulent flow. This is determined by the argument of the Heaviside function, which becomes a threshold for the occurrence of turbulence. It is supposed that proper modeling of this argument will lead to correctly capture transition location. In the present paper, this argument is modeled in such a way that the form of cubic equation for the turbulent kinematic viscosity be maintained. Moreover, the length scale which is required to calculate the turbulent kinematic viscosity is newly proposed, taking into account the freestream pressure gradient. The validation is performed by comparing the calculated results with the empirical expressions as well as the experimental data. This model can simulate the streamwise intermittency effect, by which a sudden increase of skin friction is prevented. Moreover, the transition location can be predicted within reasonable accuracy compared with the experimental data.     

Catalytic Deoxygenation of Stearic Acid and Palmitic Acid in Semibatch Mode

The deoxygenation experiments of different reactants, i.e., pure palmitic acid, stearic acid, and a technical grade stearic acid containing a mixture of 59% of palmitic and 40% of stearic acid were successfully performed over 4 wt% Pd/C mesoporous catalyst at 300 °C under 17 bar of 5% H₂ in argon. The main product in catalytic deoxygenation of saturated fatty acids, C16 and C18, were aliphatic chain length hydrocarbons containing one less carbon than the corresponding acid. Additionally it was found that the deoxygenation rates of different reactant were independent on carbon chain length of its fatty acids.