The effect of adding devulcanized rubber on the thermomechanical properties of recycled polypropylene

This work aims to investigate the effect of adding vulcanized or partially devulcanized rubbers on recycled polypropylene (PPr), considering thermomechanical and morphological properties. The study proposes to better understand how structural changes underwent by rubber (after the devulcanization) contributed to improving the mechanical properties of the PPr. The PPr/rubber blends were prepared by a co-rotating twin-screw extruder and then were injected. The blends composed of the most devulcanized rubbers by microwaves with refined microstructure showed higher values of elongation at break and toughness. Data showed that the devulcanization process applied to the rubber interfered positively in its adhesion to the PPr. Data from dynamic mechanical analysis and atomic force microscopy indicated that the most devulcanized rubbers presented an interface more connected to PPr. These chemical interactions possibly impacted the mechanical properties of the PPr. Moreover, dilatation processes favored the fracture mechanisms of the PPr when rubber was added to it.     

Diagnosis of lung nodule using Moran’s index and Geary’s coefficient in computerized tomography images

This paper analyzes the application of Moran’s index and Geary’s coefficient to the characterization of lung nodules as malignant or benign in computerized tomography images. The characterization method is based on a process that verifies which combination of measures, from the proposed measures, has been best able to discriminate between the benign and malignant nodules using stepwise discriminant analysis. Then, a linear discriminant analysis procedure was performed using the selected features to evaluate the ability of these in predicting the classification for each nodule. In order to verify this application we also describe tests that were carried out using a sample of 36 nodules: 29 benign and 7 malignant. A leave-one-out procedure was used to provide a less biased estimate of the linear discriminator’s performance. The two analyzed functions and its combinations have provided above 90% of accuracy and a value area under receiver operation characteristic (ROC) curve above 0.85, that indicates a promising potential to be used as nodules signature measures. The preliminary results of this approach are very encouraging in characterizing nodules using the two functions presented.

UnitWalk: A new SAT solver that uses local search guided by unit clause elimination

In this paper we present a new randomized algorithm for SAT, i.e., the satisfiability problem for Boolean formulas in conjunctive normal form. Despite its simplicity, this algorithm performs well on many common benchmarks ranging from graph coloring problems to microprocessor verification. Our algorithm is inspired by two randomized algorithms having the best current worst-case upper bounds ([27,28] and [30,31]). We combine the main ideas of these algorithms in one algorithm. The two approaches we use are local search (which is used in many SAT algorithms, e.g., in GSAT [34] and WalkSAT [33]) and unit clause elimination (which is rarely used in local search algorithms). In this paper we do not prove any theoretical bounds. However, we present encouraging results of computational experiments comparing several implementations of our algorithm with other SAT solvers. We also prove that our algorithm is probabilistically approximately complete (PAC).     

UnitWalk: A new SAT solver that uses local search guided by unit clause elimination

In this paper we present a new randomized algorithm for SAT, i.e., the satisfiability problem for Boolean formulas in conjunctive normal form. Despite its simplicity, this algorithm performs well on many common benchmarks ranging from graph coloring problems to microprocessor verification. Our algorithm is inspired by two randomized algorithms having the best current worst-case upper bounds ([27,28] and [30,31]). We combine the main ideas of these algorithms in one algorithm. The two approaches we use are local search (which is used in many SAT algorithms, e.g., in GSAT [34] and WalkSAT [33]) and unit clause elimination (which is rarely used in local search algorithms). In this paper we do not prove any theoretical bounds. However, we present encouraging results of computational experiments comparing several implementations of our algorithm with other SAT solvers. We also prove that our algorithm is probabilistically approximately complete (PAC).     

Improving chocolate flavor in poor-quality cocoa almonds by enzymatic treatment

Abstract: This paper proposes a method to enzymatically treat poor‐quality cocoa almonds (known as “slate”) to ensure the formation of chocolate flavor precursors. The production of flavor precursors improves the quality of these almonds, which are usually responsible for the low quality of the liquor produced. Proteases and carboxypeptidases from different sources were tested under various conditions. The different treatments were evaluated by chemical analysis (hydrolysis efficiency) and sensory analysis of the treated material compared to good‐quality cocoa almonds. The results show that it is possible, through the use of microbial enzymes, to generate the mixture of compounds that will release, after roasting, the characteristic chocolate flavor in poor‐quality almonds. However, it is necessary to optimize the conditions of enzymatic treatment to obtain better results and thus establish a process that can be used for industrial purposes for manufacturing cocoa and chocolate. Practical Application: The basidiomycete Moniliophtora perniciosa is the causative agent of witches’ broom disease (WBD) of the cocoa tree, whose seeds are the source of chocolate. It is the most important phytopathological problem of cocoa‐producing areas of the American continent, and has decimated the Brazilian cocoa industry. In Bahia (Brazil), M. perniciosa was identified in 1989 and, as a consequence of its spreading, the annual production of cocoa almonds dropped from 450000 to 90000 tons within 12 y, reducing export values from an all‐time high of about US$ 1 billion to 110 million. The high incidence of WBD incapacitates Brazil to produce enough cocoa almonds even for the internal market, leading the country to import low‐quality cocoa almonds mainly from African countries. Our work proposes an enzymatic treatment to increase the quality of that cocoa almonds and, consequently, to improve the quality of the chocolate produced and consumed in the country.     

Diagnosis of lung nodule using semivariogram and geometric measures in computerized tomography images

This paper uses the geostatistical function - semivariogram and a set of 3D geometric measures - sphericity index, convexity index, extrinsic and intrinsic curvature index and surface type, to characterize lung nodules as malignant or benign in computerized tomography images. Based on a sample of 31 nodules, 25 benign and 6 malignant, these methods are first analyzed individually and then jointly, with techniques for classification and analysis (stepwise discriminant analysis, leave-one-out and ROC curve). We have concluded that the individual measures and their combinations produce good results in the diagnosis of lung nodules.     

Blends and clay nanocomposites of cellulose acetate and poly(epichlorohydrin)

The aim of this work was to investigate cellulose acetate/poly(epichlorohydrin) (CA/PEPi) blends and cellulose acetate/poly(epichlorohydrin)/organically modified montmorillonite clay nanocomposites (CA/PEPi/MMTO) prepared by melt processing in a twin-screw extruder. The combination of an elastomer and clay in the cellulose acetate matrix was an attempt made to reach a balance between toughness and strength properties. The blend and nanocomposite structure, morphology and thermal properties were investigated by small angle X-ray scattering, transmission electron microscopy and dynamical mechanical analysis. The results showed immiscibility of the polymer components for all the CA/PEPi blend composition range investigated. In the case of the nanocomposites, the results indicated a significant polymer intercalation in the clay gallery as well as the exfoliation of the silicate layers. Moreover, the organoclay was present in the CA phase, but some of the organoclay migrated to the CA/PEPi interface and tended to surround the PEPi phase. The addition of PEPi elastomer to cellulose acetate showed a significant increase in the blend impact resistance. However the combination of PEPi and MMTO did not in fact produce a good stiffness versus toughness balance.