Determinants of Domestic Water Use by Rural Households Without Access to Private Improved Water Sources in Benin: A Seemingly Unrelated Tobit Approach

This paper analyzes the determinants of domestic water use in rural areas. The focus is on households without access to private improved water sources. These households use either only free sources, only purchased sources or a combination of free and purchased sources. We also analyze households’ water use behaviors as a function of water availability by explicitly estimating domestic water use for both rainy and dry seasons. Using a Seemingly Unrelated Tobit approach to simultaneously account for the censored nature of water demand and the correlation of error terms between free and purchased water use equations, we find that purchased water demand is perfectly price inelastic due to water scarcity. The important determinants of water use are household size and composition, access to water sources, wealth and time required for fetching water. Nevertheless, the effects of these determinants vary between household types and seasons, and the policy implications of the findings are discussed.     

Direct growth of Cu3(BTC)2(H2O)3 · xH2O thin films on modified QCM-gold electrodes – Water sorption isotherms

The preparation of a thin film of the metal–organic framework Cu₃(BTC)₂(H₂O)₃ · xH₂O (HKUST-1) on the gold electrode of a quartz-crystal microbalance (QCM) was achieved by direct growth on a 11-mercaptoundecanol self-assembled monolayer (SAM). The formation of the SAM on the gold substrate was proven via reflection–absorption infrared-spectroscopy. The HKUST-1 thin film was characterized by X-ray diffraction, Raman-spectroscopy, and scanning-electron microscopy. Water vapor sorption measurements allow us to directly characterize the sorption properties of the thin film grown on the electrode of the QCM-device.     

Influence of Cu off-stoichiometry on wide band gap CIGSe solar cells

The electric properties of solar cells based on co-evaporated Cu(In,Ga)Se₂ (CIGSe) thin film show a good tolerance regarding the absorber Cu content (y = [Cu]/([In] + [Ga])) for standard Ga concentration, i.e. x = [Ga] / ([In] + [Ga]) ~ 0.3. In the present contribution, we show that this tolerance is lost when the gallium content is increased. Wide bandgap CIGSe samples (x ~ 0.55) with a variation in y from 0.97 to 0.84 have been grown. The efficiency of the cells decreases from 12.6% to 6.5% for y = 0.97 and 0.84 respectively. For the lowest y, the efficiency is harmed because of a low short-circuit current density (J_sc), an increased voltage dependency in the current collection, which affects the fill factor (FF), and a decrease of the open-circuit voltage (V_oc). For y = 0.97 and 0.84 respectively, the decrease of the activation energy (E_a) from 1.36 to 1.24 eV indicates a shift of the area of the dominant recombination from the space charge region towards the interface. There seems to be evidence that reducing the Cu-content in the CIGSe thin film will cause a decrease in the width of the space charge region. Solar cells based on Cu-rich CIGSe (1.03 < y < 1.09) have also been fabricated and characterized. A strong deterioration of their electrical properties is observed despite the KCN etch of the segregated Cu_2 − xSe binary phases at the surface, suggesting the presence of residual Cu_2 − xSe precipitates within the layer.     

Hybrid Wireless Sensors Deployment Scheme with Connectivity and Coverage Maintaining in Wireless Sensor Networks

With the rapid growth of the internet of things (IoT), an impressive number of IoT’s application based on wireless sensor networks (WSNs) has been deployed in various domain. Due to its wide ranged applications, WSNs that have the capability to monitor a given sensing field, became the most used platform of IoT. Therefore, coverage becomes one of the most important challenge of WSNs. The search for better positions to assign to the sensors in order to control each point of an area of interest and the collection of data from sensors are major concerns in WSNs. This work addresses these problems by providing a hybrid approach that ensures sensors deployment on a grid for targets coverage while taking into account connectivity. The proposed sequential hybrid approach is based on three algorithms. The first places the sensors so as to all targets are covered. The second removes redundancies from the placement algorithm to reduce the number of sensors deployed. The third one, based on the genetic algorithm, aims to generate a connected graph which provide a minimal path that links deployed sensors and sink. Simulations and a comparative study were carried out to prove the relevance of the proposed method.

     

Comparative study of Cu(In,Ga)Se2/(PVD)In2S3 and Cu(In,Ga)Se2/(CBD)CdS heterojunction based solar cells by admittance spectroscopy, current-voltage and spectral response measurements

Co-evaporated Cu(In,Ga)Se₂ (CIGSe) based solar cells with Physical Vapour Deposited (PVD) Indium Sulphide (In₂S₃) as buffer layer have been studied by admittance spectroscopy and current-voltage characteristics measurements. The results have been compared to those obtained with a reference CBD-CdS/CIGSe device. In darkness, the PVD-In₂S₃ buffer layer devices exhibit higher densities of trapping defects and low values of shunt resistance. However, under illumination we have observed an important improvement of the In₂S₃/CIGSe electronic transport properties. This behavior seems to be linked to the presence of a metastable defect with activation energy of 0.3 eV.     

Semiconducting Nanowire‐Based Optoelectronic Fibers

The recent ability to integrate semiconductor‐based optoelectronic functionalities within thin fibers is opening intriguing opportunities for flexible electronics and advanced textiles. The scalable integration of high‐quality semiconducting devices within functional fibers however remains a challenge. It is difficult with current strategies to combine high light absorption, good microstructure and efficient electrical contact. The growth of semiconducting nanowires is a great tool to control crystal orientation and ensure a combination of light absorption and charge extraction for efficient photodetection. Thus far, however, leveraging the attributes of nanowires has remained seemingly incompatible with fiber materials, geometry, and processing approaches. Here, the integration of semiconducting nanowire‐based devices at the tip and along the length of polymer fibers is demonstrated for the first time. The scalable thermal drawing process is combined with a simple sonochemical treatment to grow nanowires out of electrically addressed amorphous selenium domains. First principles density‐functional theory calculations show that this approach enables to tailor the surface energy of crystal facets and favors nanowire growth along a preferred orientation, resulting in fiber‐integrated devices of unprecedented performance. This novel platform is exploited to demonstrate an all‐fiber‐integrated fluorescence imaging system, highlighting novel opportunities in sensing, advanced optical probes, and smart textiles.     

硅酸水垢及防治方法研究进展

在水资源再生利用过程中水中硅酸会沉淀在设备管道内壁或膜表面形成硅垢,影响设备的正常运行。硅垢的主要成分为无机硅酸盐和无定形SiO_2,是最难处理的水垢。抑制硅垢的方法有设备内添加阻垢剂和设备外预处理降低硅酸浓度等。设备内添加阻垢剂的方法又包括提高硅酸溶解度法和投加分散剂法;设备外预处理降低硅酸浓度的方法包括超滤膜法、反渗透膜法、絮凝法、离子交换法等。     

Estimating rural households' willingness to pay for water supply improvements: a Benin case study using a semi-nonparametric bivariate probit approach

This paper estimates households' willingness to pay (WTP) to improve rural water supply in Benin. Particular attention is given to the distribution of WTP, which is traditionally addressed using parametric assumptions. To avoid distributional assumptions, a semi-nonparametric bivariate probit approach is introduced. Results provide the first evidence that, in rural Benin, households wanting to improve water supply are willing to pay more than the current price. WTP for water supply is determined by wealth, education, and characteristics of existing and new water systems. Results indicate that a demand-driven management approach can contribute to water supply improvements and sustainability.