The chlorination of a titaniferous magnetite with low content in Ti and Fe has been studied between 1273 and 2273 K. Most
of the hercynite and ilmenite initially present are decomposed during the gas-solid phase reaction between 1273 and 1823 K.
Considerable ilmenite decomposition and FeCl3evolution already occur at 1273 K, leaving a residue consisting of TiO2, Fe2O3-TiO2 (pseudobrookite), and about 50 pct of each of the Cr and Mg initially present. X-ray diffractograms shown the formation of
Al2TiO5 which contributes to the stabilization of TiO2 up to 1773 K, above which temperature significant decomposition of Al2TiO5 is observed. At the melting point of the titaniferous magnetite sample (around 1823 K), the presence of both solid and liquid
phases result in a considerable decrease in the chlorination rate. In this respect, heating the sample under helium up to
the melting point, so that liquid and solid phases are obtained at equilibrium, yields two structures replacing the magnetite
present just prior to melting. One of these structures is of the spinel Fe2TiO4 type, while the other is a combination of the spinel types MgAl2O4, FeAl2O4, and MgCr2O4. When the sample is chlorinated, a high proportion of the initial Cr (90 pct) and Ti (80 pct) are found in the chlorination
residue at the early stages of fusion, together with 13 pct of the initial Fe. Chlorination of the liquid phase between 1823
and 2273 K shows a steady decrease of Ti and Cr in the chlorination residue, associated with an increase of Fe content. 相似文献
The behaviours of ten minor coal elements (Al, Ca, Fe, K, Mg, Mn, Na, P, Si and Ti) during coal combustion in the temperature range 400–2000 K, under both oxidising and reducing conditions, have been studied in detail by a thermodynamic equilibrium analysis.
The partitioning of these elements is calculated both in single minor element–coal–chlorine systems and in minor elements co-existing systems. Their vaporisation tendency is found in the order: (Si, Al)<(Fe, Ti)<(Ca, Mn)<(K, Na, P, Mg). Si, Ti, Al and P are present mostly as oxides and K and Na as chlorides, whatever the combustion conditions. Al, Ca, Fe, K, Mn and Na sulphates are dominant at low temperatures under oxidising conditions, whereas under reducing conditions most of them are sulphides and/or chlorides. Moreover, the interactions between these elements affect their major speciation: some species containing two elements among those studied are dominant in the minor elements co-existing systems. The affinities of minor coal elements to sulphur have been studied versus both temperature (400 or 800 K) and sulphur content (0.0062–6.20 wt.% in the coal), in order to find out their influence on the flue gas desulfurization. Two coal samples with different ash contents were considered, and it was found that the ash composition affects greatly the minor elements partitioning. 相似文献
Amphiregulin (Ar) is an EGF receptor ligand that functions to modulate the growth of both normal and malignant epithelial cells. We asked whether mouse preimplantation embryos express Ar, and if so, what the function of Ar is during preimplantation development. We used RT-PCR to show expression of Ar mRNA in mouse blastocysts, and using a polyclonal anti-Ar antibody and indirect immunofluorescence, we detected the presence of Ar protein in morula- and blastocyst-stage embryos. Ar protein was present in both the cytoplasm and nucleus in both morulae- and blastocyst-stage embryos, which is similar to Ar distribution in other cell types. Embryos cultured in Ar developed into blastocysts more quickly and also exhibited increased cell numbers compared to control embryos. In addition, 4-cell stage embryos cultured in an antisense Ar phosphorothioate-modified oligodeoxynucleotide (S-oligo) for 48 hr exhibited slower rates of blastocyst formation and reduced embryo cell numbers compared to embryos exposed to a random control S-oligo. TGF-alpha significantly improved blastocyst formation, but not cell numbers, for embryos cultured in the antisense Ar S-oligo. From these observations, we propose that Ar may function as an autocrine growth factor for mouse preimplantation embryos by promoting blastocyst formation and embryo cell number. We also propose that blastocyst formation is stimulated by Ar and TGF-alpha, while Ar appears to exert a greater stimulatory effect on cell proliferation than does TGF-alpha in these embryos. 相似文献
In the current paper, we propose a new online search, fault detection, and fault location approach for short faults in network on chip communication channels. The approach proposed consists of a built-in self-test as well as a packet/flit comparings module embedded in the network adapter and a router, respectively. The approach is mainly characterized by the fact that, firstly, the diagnosis and location processes are simultaneously carried out after which the test time is minimized. Secondly, the approach updates the NoC routing tables far less costly in a parallel fashion. Thirdly, insignificant hardware is added to the system. The high scalability in the approach, in addition, leads to 100% test coverage, 71.4% capability of detecting faulty channels, and 100% detected faults location in one round (two phases). The simulation results show that the approach hardware is optimized compared with the previous methodologies. 相似文献
Scientometrics - Zone identification is a topic in the area of text mining which helps researchers be benefited by the content of scientific papers in a satisfactory manner. The major aim of zone... 相似文献
Submicron Ti2AlC MAX phase powder was synthesized by molten salt shielded synthesis (MS3) using a Ti:Al:C molar ratio of 2:1:0.9 at a process temperature of 1000°C for 5 hours. The synthesized powder presented a mean particle size of ~0.9 µm and a purity of 91 wt. % Ti2AlC, containing 6 wt. % Ti3AlC2. The Ti2AlC powder was sintered by pressureless sintering, achieving a maximal relative density of 90%, hence field-assisted sintering technology/spark plasma sintering was used to enhance densification. The fine-grained microstructure was preserved, and phase purity of Ti2AlC was unaltered in the latter case, with a relative density of 98.5%. Oxidation was performed at 1200°C for 50 hours in static air of dense monolithic Ti2AlC with different surface finish, (polished, ground and sandblasted) which resulted in the formation of an approx. 8 µm thin aluminum oxide (Al2O3) layer decorated with titanium dioxide (rutile, TiO2) colonies. Surface quality had no influence on Al2O3 scale thickness, but the amount and size of TiO2 crystals increased with surface roughness. A phenomenon of rumpling of the thermally grown oxide (TGO) was observed and a model to estimate the extent of deformation is proposed. 相似文献