Inhibition of pyrite oxidation by a phospholipid in the presence of silicate

The influence of sodium silicate on the ability of a diacetylene-containing phospholipid (23:2 diyne PC) to inhibit the oxidation of pyrite at pH 2 and pH 6 was investigated. The phospholipid used has previously been reported to show up to 80% suppression of pyrite oxidation and to show excellent stability down to at least pH 2. Pyrite was leached with a solution containing Fe3+ but no coating agent and three different solutions or treatments: a lipid treatment, a silicate treatment, and a lipid + silicate treatment. Pyrite oxidation was based on iron (Fe3+, Fe2+) leached out of a continuous-flow porous-bed reactor system. The results show that at pH 6 the silicate and lipid both bind strongly to the pyrite surfaces, providing a barrier that inhibits the production and subsequent release of oxidation products. The lipid is superior to the silicate in suppressing pyrite oxidation at both pH 2 and pH 6. Also, the presence of silicates decreased the ability for the lipid to suppress pyrite oxidation, both at pH 2 and pH 6. The reaction mechanism for pyrite oxidation at pH 2 is first order for pyrite leached by solutions containing only ferric, ferric together with silicate, and ferric combined with silicate and lipid. The only treatment that effectively prevented pyrite oxidation at pH 2 was the lipid treatment. The Fe speciation results are supported by both SEM images and EDS calculations.     

Stability of Silicate Coatings on Pyrite Surfaces in a Low pH Environment

The suppression of pyrite oxidation due to the formation of stable coatings of Fe3+–silica and/or Fe3+–hydroxy–silica complexes over pyrite surfaces in near-neutral and neutral solution pHs is well documented. On the contrary, there is currently no convincing experimental evidence that proves the existence of such a coating under low pH environments. Aqueous continuous flow kinetic experiments were conducted using coating solutions containing Na2SiO3?5H2O and H2O2 at pH 6, 4, 3, and 2. Results showed that at pH 2, pyrite oxidation in the presence of silica is pseudofirst order and oxidation is not inhibited by silica. At pH 6, silica significantly reduced pyrite oxidation via a pseudofirst-order reaction that takes on several stages related to changes in the relative contributions of H2O2 and Fe3+. Iron speciation data suggests a surface adsorption mechanism at pH 6 and an electrochemical mechanism at pH 2 for pyrite oxidation. Scanning electron microscopy and energy dispersive x-ray spectroscopy also support the kinetic model and showed the absence of any significant silica coating at pH 2.     

Heat transfer coefficient and thermal losses of solar collector and Nusselt number correlation for rectangular solar air heater duct with longitudinal fins hold under the absorber plate

An experimental investigation has been carried out for a series of system and operating parameters in order to analyze the effect of mass flow rate on heat transfer and Nusselt number characteristics in solar air heater. Experiments are performed at different air mass flow rates; varying from 0.012 to 0.016 kg/s, about hot summer days of Mai 2012. Hourly values of global solar radiation and some meteorological data (temperature, wind speed, relative humidities, etc.) for measuring days are obtained from the Biskra city of Algeria. The experiments encompassed the flow Reynolds number in the range 965.48–1301.4. Longitudinal fins were used inferior the absorber plate for an increase the heat exchange and render the flow fluid in the channel uniform. The effects of mass flow rate of air on the outlet temperature, Nusselt Number, Reynolds Number, Prandtl Number, the heat transfer in the thickness and length of the solar air collector were studied. For this effect was have created a new correlation correspondent of solar air collector with using fins it was written Nu = κ₀Re^1.36Pr^?0.68exp(0.342m)h ^[?0.018Pr].     

Comparative assessment of pest management practices in potato production at Farmer Field Schools

Farmer field schools (FFS) and other participatory approaches are useful methods for rapid delivery of agricultural technologies, knowledge, and information in resource-constrained agro-ecosystems. Cultivar selection, weekly fungicide applications and integrated disease management (IDM) based on a disease monitoring strategy were evaluated at FFS for late blight control. Farmers’ knowledge and perceptions of pest management and agronomic practices were also assessed for both FFS participants and non-participants from 1999–2002. Late blight development and tuber yield varied among field schools, but cultivars had significant effects on late blight severity and yield over a range of disease management options relative to the untreated check. FFS participants and non-participants used diverse sources of pest management information, but differed significantly (P?<?0.05) in their use of management methods and practices. Cultivar resistance and fungicides were ranked as major components of pest control by 18%–85% and 7%–30% of FFS participants and non-participants, respectively. Differences in knowledge of cropping practices and pest biology, causal agents, disease symptoms, factors favoring disease development and cultural management of insects and storage pests were recorded. Participatory field experiments, access to resistant cultivars, disease management and use of various agronomic practices learnt at FFS can greatly improve pest control and potato production.     

Prediction of the theoretical and semi-empirical model of ambient temperature

It is well known that the ambient temperature is a sensitive parameter which has a great effect on biology, technology, geology and even on human behavior. A prediction is a statement about an uncertain event. It is often, but not always, based upon experience or knowledge. Although guaranteed accurate information about the future is in many cases impossible, prediction can be useful to assist in making plans about possible developments. As a result, temperature profiles can be developed which accurately represent the expected ambient temperature exposure that this environment experiences during measurement. The ambient temperature over time is modeled based on the previous T _min and T _max data and using a Lagrange interpolation. To observe the comprehensive variation of ambient temperature the profile must be determined numerically. The model proposed in this paper can provide an acceptable way to measure the change in ambient temperature.     

Enzymatic Route toward 6-Methylated Baeocystin and Psilocybin

Psilocybin and its direct precursor baeocystin are indole alkaloids of psychotropic Psilocybe mushrooms. The pharmaceutical interest in psilocybin as a treatment option against depression and anxiety is currently being investigated in advanced clinical trials. Here, we report a biocatalytic route to synthesize 6-methylated psilocybin and baeocystin from 4-hydroxy-6-methyl-l -tryptophan, which was decarboxylated and phosphorylated by the Psilocybe cubensis biosynthesis enzymes PsiD and PsiK. N-Methylation was catalyzed by PsiM. We further present an in silico structural model of PsiM that revealed a well-conserved SAM-binding core along with peripheral nonconserved elements that likely govern substrate preferences.     

Transmission network of the 2014–2015 Ebola epidemic in Sierra Leone

Understanding the growth and spatial expansion of (re)emerging infectious disease outbreaks, such as Ebola and avian influenza, is critical for the effective planning of control measures; however, such efforts are often compromised by data insufficiencies and observational errors. Here, we develop a spatial–temporal inference methodology using a modified network model in conjunction with the ensemble adjustment Kalman filter, a Bayesian inference method equipped to handle observational errors. The combined method is capable of revealing the spatial–temporal progression of infectious disease, while requiring only limited, readily compiled data. We use this method to reconstruct the transmission network of the 2014–2015 Ebola epidemic in Sierra Leone and identify source and sink regions. Our inference suggests that, in Sierra Leone, transmission within the network introduced Ebola to neighbouring districts and initiated self-sustaining local epidemics; two of the more populous and connected districts, Kenema and Port Loko, facilitated two independent transmission pathways. Epidemic intensity differed by district, was highly correlated with population size (r = 0.76, p = 0.0015) and a critical window of opportunity for containing local Ebola epidemics at the source (ca one month) existed. This novel methodology can be used to help identify and contain the spatial expansion of future (re)emerging infectious disease outbreaks.     

Contribution to the Study of the Reduction of Energy Consumption through the Exchanger Coupled Conventional Air‐Ground‐Air Conditioner. Application to the Building

In this study, a new method of using the earth‐air heat exchangers to reduce energy consumption in buildings is discussed. The idea is to couple the EAHE with the condenser of a residential air conditioning system to enhance the effectiveness of the latter. Under the climatic conditions of high temperature in summer (south‐eastern region of Algeria), which can sometimes exceed 50 °C, what makes the heat exchange between the air conditioner and the external environment very difficult in addition to the problem of thermal comfort and the cost of energy consumption. Conducting a simulation by the TRNSYS software that allows to couple the model of the EAHE with the condenser of a residential air conditioner and connect the system with a building. The results show a clear reduction in the energy consumed by this system in connection with the direct use of the air conditioner and increase air conditioning efficiency, coefficient of performance, and energy efficiency rating. In this paper the Hollmuller model was ameliorated and the obtained results are in concord with it. The system is capable of resolving the problem of mal cooling of buildings by air conditioners under critical climate conditions, in addition to lowering the heat output of the condenser, and reducing its effect on the environment.