Models and emerging trends of concurrent constraint programming

Concurrent Constraint Programming (CCP) has been used over the last two decades as an elegant and expressive model for concurrent systems. It models systems of agents communicating by posting and querying partial information, represented as constraints over the variables of the system. This covers a vast variety of systems as those arising in biological phenomena, reactive systems, net-centric computing and the advent of social networks and cloud computing. In this paper we survey the main applications, developments and current trends of CCP.     

Phase equilibria of hydrates from ternary mixtures of methane + ethane + propane and methane + propane + carbon dioxide

Hydrate–liquid–vapour (HLV) equilibrium of aqueous clathrates formed from gas mixtures can be complex compared to hydrates formed with single guests. Typically, pressure and temperature are controlled to obtain these data, but for multicomponent systems, it is necessary to control/report more intensive variables, namely, composition. Metastability, manifested as impractically long experimental times, has been reported to be a challenge with some multicomponent systems. We present HLV equilibrium conditions of two ternary gas mixtures: methane + ethane + propane (90:7:3 molar ratio) and methane + propane + carbon dioxide (55:5:40 molar ratio). Conditions varied in the temperature range of 275–285 K and the pressure range of 1.24–4.75 MPa. Experimental standard uncertainties were on average 0.10 K and 0.005 MPa for methane + ethane + propane and 0.19 K and 0.005 MPa for methane + propane + carbon dioxide. Our technique allowed us to bypass the limitations reported in the literature and provided fast, reproducible HLV equilibria for gas-dominated systems.     

Multiobjective optimization of biorefineries with economic and safety objectives

A new approach for the incorporation of safety criteria into the selection, location, and sizing of a biorefinery is introduced. In addition to the techno‐economic factors, risk metrics are used in the decision‐making process by considering the cumulative risk associated with key stages of the life cycle of a biorefinery that includes biomass storage and transportation, process conversion into biofuels or bioproducts, and product storage. The fixed cost of the process along with the operating costs for transportation and processing as well as the value of the product are included. An optimization formulation is developed based on a superstructure that embeds potential supply chains of interest. The optimization program establishes the tradeoffs between cost and safety issues in the form of Pareto curves. A case study on bio‐hydrogen production is solved to illustrate the merits of the proposed approach. © 2013 American Institute of Chemical Engineers AIChE J, 59: 2427–2434, 2013     

Polyimide foams from powder: Experimental analysis of competitive diffusion phenomena

In the present study, various diffusive processes have been investigated during foaming of powdered precursors of polyimide. A detailed analysis of the powdered precursor's characteristics allows for an enhanced morphological understanding of the resulting microstructures and foam unit cell. Parameters that are central to the foaming process such as particle morphology, volatile concentration and sorption-desorption processes are evaluated. Isothermal and non-isothermal desorption experiments have been carried out by thermogravimetric analysis (TGA), and specific diffusive processes have been correlated to thermodynamic and kinetic transitions by means of modulated differential scanning calorimetry (MDSC) of the corresponding materials. It was found that two primary fluxes of volatiles, one out of the external surface of the particles (responsible for volatile desorption) and the other into the growing bubble (responsible for vapor supersaturation inside the bubble) compete against each other creating a competitive scenario that becomes the controlling factor for potential inflation within the precursor particles.     

Radiation absorption and rate constants for carbaryl photocatalytic degradation in a solar collector

We discuss an analytical model for the evaluation of radiation absorption in a tubular photocatalytic reactor. The model has no adjustable parameters and takes into account scattering in all directions. We compare the results of this model with those of Monte Carlo (MC) simulations and of a Lambert–Beer (LB) approximation, for a reactor illuminated by a parabolic solar concentrator. A good correspondence is found with the MC simulations. In particular, the model displays the correct saturation behavior of absorption for large catalyst particle concentrations, which is not obtained with the LB approximation. We have carried out experiments for the degradation of carbaryl in a solar parabolic collector (PC). The model is used to calculate the rate constant for this degradation from the experimental data. The theoretical model predictions reproduce well, the trends observed in the experiments.     

Effect of cavity surface coating and molding parameters on pressure drop: Developing a new software for rapid calculations

Nowadays, many of the plastic components are aesthetic pieces, and they are fabric, thermoplastic vulcanizates (TPVs), or film coated. In the case of upholstered pieces, they are injected onto a textile tissue introduced into the mold, and they are finished with an edging process. Simulation programs used to optimize the injection process are not able to simulate the injection over fabrics, and therefore, it is difficult to select an injection machine without knowing the pressure drop inside the mold and without knowing how the parameters affect to the injection cycle or to the aesthetic aspect of this kind of pieces. This article presents a software for rapid calculations during the filling phase without the need for complex modeling. The program will be able to calculate pressure drop and other flow parameters that are fundamental for a good design of an industrial mold used in in‐mold decoration (IMD) technique. POLYM. ENG. SCI., 2012. © 2011 Society of Plastics Engineers     

Renewable polybenzoxazines based in diphenolic acid

The reaction of mixtures of renewable diphenolic acid (DPA) and its methylesterbenzoxazine derivative (MDP-Bz) has been studied. The DPA was introduced to lower the high temperature needed to complete the curing of the pure benzoxazine. In this way, samples with different DPA/MDP-Bz ratio (0, 2, 5, 10 and 25% of DPA) were investigated. Moreover, high performance flame retardant thermosetting resins with phosphorus were prepared through the mixture of MDP-Bz and a DPA-phosphazene derivative (DPA-PPZ). The curing behavior of these materials was studied by differential scanning calorimetry (DSC). Finally, the properties of the materials were evaluated by termogravimetric analysis (TGA), dynamic mechanical analysis (DMTA), tensile measurements, limiting oxygen index (LOI) and UL-94 Burn Test.     

Self-foaming diphenolic acid benzoxazine

This work concerns the investigation of porous polybenzoxazines based on the non-toxic renewable diphenolic acid. The approach described relies on the in situ generation of foaming agent (CO₂) during the thermal curing. For this purpose, the previously synthesized benzoxazine monomer from diphenolic acid was thermally polymerized at different temperatures. As the beginning of decarboxylation is about 200 °C, we selected five foaming temperatures (T_f) ranging from 190 to 230 °C. The influence of the foaming temperature on the cellular structure and its dependency on final properties is discussed.     

Solar photoreactors comparison based on oxalic acid photocatalytic degradation

Solar heterogeneous photocatalytic degradation of oxalic acid in water is carried out in four different solar photoreactors: a parabolic trough concentrator (PC), a tubular collector (TC), a compound parabolic collector (CPC), and a V-trough collector (VC). The reactors operate under equal conditions of solar irradiance, collection surface and fluid flow rate to ensure a better comparison between the systems. The effects of TiO₂ catalyst concentration and radiation incidence angle on the degradation are studied. Oxalic acid degrades without appreciable generation of intermediates, and a simple kinetic model is proposed to describe the process. There are differences in the degradation rates depending on the collector geometry. The CPC shows the best overall performance in terms of accumulated energy, followed closely by the VC. Incidence angle affects the total amount of energy collected but does not reduce very much the efficiency of the reactors to use this energy in the photocatalytic process.