Characterization of rust phases formed on low carbon steel exposed to natural marine environment of Chennai harbour – South India

The corrosion behaviour of low carbon steel exposed to marine atmospheric, splash and immersion zones has been systematically studied by exposing steel specimens for a period of 12 months at the boat basin corrosion station of Chennai harbour, Chennai, Tamil Nadu, South India. The literature on similar work has been thoroughly reviewed which led to the initiation of this study for the first time at this harbour. The corrosion product (rust) on the specimens at 1, 2, 3 and 12 months was obtained and characterized by Fourier transform infrared spectroscopy (FT‐IR) and X‐ray diffraction (XRD) analysis. Acaganeite was the rust phase identified in the splash zone as revealed by the FT‐IR and XRD analysis. The other dominant phases were lepidocrocite, goethite and ferroxyhite. Small amounts of magnetite were also found to be present. The transformation of phases was observed in this investigation and discussed. A remarkable difference in the FT‐IR and XRD patterns of the corrosion products at the splash and immersion zones were noticed and the corresponding phases formed were reported in this paper. The rate of corrosion in all the three zones was compared.     

Gibbs energies of formation of chromium carbides

The carbon potentials corresponding to the two-phase mixtures Cr + Cr₂₃C₆, Cr₂₃C₆ + Cr₇C₃, and Cr₇C₃ + Cr₃C₂ in the binary system Cr-C were measured in the temperature range 973 to 1173 K by using the methane-hydrogen gas equilibration technique. Special precautions were taken to prevent oxidation of the samples and to minimize thermal segregation in the gas phase. The standard Gibbs energies of formation of Cr₂₃C₆, Cr₇C₃, and Cr₃C₂ were derived from the measured carbon potentials. These values are compared with those reported in the literature. The Gibbs energies obtained in this study agree well with those obtained from solid-state cells incorporating CaF₂ and ThO2(Y₂O₃) as solid electrolytes and sealed capsule isopiestic measurements reported in the literature.     

Cloud Security Service for Identifying Unauthorized User Behaviour

Recently, an innovative trend like cloud computing has progressed quickly in Information Technology. For a background of distributed networks, the extensive sprawl of internet resources on the Web and the increasing number of service providers helped cloud computing technologies grow into a substantial scaled Information Technology service model. The cloud computing environment extracts the execution details of services and systems from end-users and developers. Additionally, through the system’s virtualization accomplished using resource pooling, cloud computing resources become more accessible. The attempt to design and develop a solution that assures reliable and protected authentication and authorization service in such cloud environments is described in this paper. With the help of multi-agents, we attempt to represent Open-Identity (ID) design to find a solution that would offer trustworthy and secured authentication and authorization services to software services based on the cloud. This research aims to determine how authentication and authorization services were provided in an agreeable and preventive manner. Based on attack-oriented threat model security, the evaluation works. By considering security for both authentication and authorization systems, possible security threats are analyzed by the proposed security systems.     

Investigation on effect of fibre hybridization and orientation on mechanical behaviour of natural fibre epoxy composite

Nowadays bio fibre composites play a vital role by replacing conventional materials used in automotive and aerospace industries owing to their high strength to weight ratio, biodegradability and ease of production. This paper aims to find the effect of fibre hybridization and orientation on mechanical behaviour of composite fabricated with neem, abaca fibres and epoxy resin. Here, three varieties of composites are fabricated namely, composite 1 which consists of abaca fibre and glass fibre, composite 2, which consists of neem fibre and glass fibre, whereas composite 3 consists of abaca, neem fibres and glass fibres. In all the above three varieties, fibres are arranged in three types of orientations namely, horizontal (type I), vertical (type II) and 45\(^{\circ }\) inclination (type III). The result shows that composites made up of abaca and neem fibres with inclined orientation (45\(^{\circ }\)) have better mechanical properties when compared with other types of composites. In addition, morphological analysis is carried out using scanning electron microscope to know the fibre distribution, fibre pull out, fibre breakage and crack propagation on tested composites.     

Propane Ammoxidation Over the Mo�CV�CTe�CNb�CO M1 Phase: Reactivity of Surface Cations in Hydrogen Abstraction Steps

Density functional theory calculations (GGA-PBE) have been performed to investigate the adsorption of C₃ (propane, isopropyl, propene, and allyl) and H species on the proposed active center present in the surface ab planes of the bulk Mo?CV?CTe?CNb?CO M1 phase in order to better understand the roles of the different surface cations in propane ammoxidation. Modified cluster models were employed to isolate the closely spaced V=O and Te=O from each other and to vary the oxidation state of the V cation. While propane and propene adsorb with nearly zero adsorption energy, the isopropyl and allyl radicals bind strongly to V=O and Te=O with adsorption energies, ??E, being ???1.75 eV, but appreciably more weakly on other sites, such as Mo=O, bridging oxygen (Mo?CO?CV and Mo?CO?CMo), and empty metal apical sites (??E > ?1 eV). Atomic H binds more strongly to Te=O (??E ?? ?3 eV) than to all the other sites, including V=O (??E = ?2.59 eV). The reduction of surface oxo groups by dissociated H and their removal as water are thermodynamically favorable except when both H atoms are bonded to the same Te=O. Consistent with the strong binding of H, Te=O is markedly more active at abstracting the methylene H from propane (E _a  ?? 1.01 eV) than V=O (E _a  = 1.70 eV on V⁵⁺=O and 2.13 eV on V⁴⁺=O). The higher-than-observed activity and the loose binding of Te=O moieties to the mixed metal oxide lattice of M1 raise the question of whether active Te=O groups are in fact present in the surface ab planes of the M1 phase under propane ammoxidation conditions.     

Treatment of dairy wastewater using anaerobic and solar photocatalytic methods

The present study was aimed to treat the dairy wastewater by using anaerobic and solar photocatalytic oxidation methods. The anaerobic treatment was carried out in a laboratory scale hybrid upflow anaerobic sludge blanket reactor (HUASB) with a working volume of 5.9 L. It was operated at organic loading rate (OLR) varying from 8 to 20 kg COD/m³ day for a period of 110 days. The maximum loading rate of the anaerobic reactor was found to be 19.2 kg COD/m³ day and the corresponding chemical oxygen demand (COD) removal at this OLR was 84%. The anaerobically treated wastewater at an OLR of 19.2 kg COD/m³ day was subjected to secondary solar photocatalytic oxidation treatment. The optimum pH and catalyst loading for the solar photochemical oxidation was found to be 5 and 300 mg/L, respectively. The secondary solar photocatalytic oxidation using TiO₂ removed 62% of the COD from primary anaerobic treatment. Integration of anaerobic and solar photocatalytic treatment resulted in 95% removal of COD from the dairy wastewater. The findings suggest that anaerobic treatment followed by solar photo catalytic oxidation would be a promising alternative for the treatment of dairy wastewater.     

Invited review: Sugar reduction in dairy products

Sugar overconsumption continues to increase worldwide and contributes to multiple health-related issues. Dairy foods represent a large market, grossing more than $125 billion per year worldwide. Consumer demands for healthier products are leading to a large push for sugar reduction in dairy foods. Sugar plays an important role in dairy foods, not only in flavor but also in texture, color, and viscosity. Replacing sugar can have negative effects, making substitution inherently difficult. Natural and artificial nonnutritive sweeteners exist for sugar reduction. Natural nonnutritive sweeteners are popular, particularly for label appeal, but many consumers still prefer the taste of artificial nonnutritive sweeteners. Sweet taste perception can also be affected by texture of the food matrix and the presence of fat. Other sugar reduction techniques include hydrolysis of lactose, ultrafiltration, and direct reduction. This review will address the role of sugar, alternative sweeteners, and sugar reduction in ice cream, yogurt, and flavored milk.     

Influence of mixtures of calcium-chelating salts on the physicochemical properties of casein micelles

Calcium-chelating salts (CCS), such as phosphates and citrates, are often added to milk systems to modify physical properties like heat stability. The objective of this study was to investigate the effect of binary CCS mixtures on the properties of casein (CN) micelles including the distribution of Ca between the soluble and CN-bound states. Six binary CCS mixtures were prepared from 4 different types of CCS [i.e., trisodium citrate (TSC), disodium phosphate (DSP), tetrasodium pyrophosphate (TSPP), and sodium hexameta phosphate (SHMP)] by combining 2 CCS at a time in 5 different proportions (8.3:91.7, 29.2:70.8, 50:50, 70.8:29.2, and 91.7:8.3). Different concentrations of these mixtures (0, 0.1, 0.3, 0.5, and 0.7% wt/wt) were added to milk protein concentrate solutions (5% wt/wt) at pH 5.8. The ability of CCS to disperse CN particles and its interaction with Ca were assessed from turbidity measurements, acid-base titration behavior, and the quantity of CN-bound Ca and inorganic phosphate (Pi). Turbidity and the buffering peak at pH ∼5.0 during acid titration decreased with an increasing concentration of CCS. This was due to the chelation of Ca and the dispersion of CN micelles. The presence of TSC in mixtures decreased the amount of CN-bound Ca and Pi; however, the presence of TSPP in mixtures increased CN-bound Ca and Pi. When DSP was present at high proportions in mixtures of CCS, the CN-bound Ca and Pi slightly increased. When SHMP was used in mixtures of CCS, CN-bound Ca and Pi increased with the use of a low proportion of SHMP but decreased when SHMP was used at high proportions in the mixture. Combinations of DSP-TSPP used in the proportions 29.2:70.8, 50:50, and 70.8:29.2 resulted in the gelation of milk protein concentrates when the total CCS concentration was ≥0.3%. These results indicated that the type of CCS present in a mixture modified CN properties by various mechanisms, including chelation of Ca, dispersion of CN micelles, and formation of new types of Ca-CCS complexes. The type of interaction between the newly formed Ca-CCS complexes and the dispersed CN depended on the proportion, concentration, and type of CCS present in the mixtures. This information is useful in understanding how mixtures of CCS affect CN properties.     

Power Pinch Analysis supply side management: strategy on purchasing and selling of electricity

Pinch analysis concept has been recently stepped into the realm of design and optimisation of power systems. One well-established pinch analysis that has been used in power systems design and optimisation is called Power Pinch Analysis (PoPA). In PoPA, both graphical and numerical approaches have provided an insight on the systematic approach to target and design various power systems. By only visualising the minimum amount of outsource energy required by the power system, the graphical PoPA method as a whole does not show the purchasing of outsource energy based on the exact time intervals. Using graphical PoPA, the objective of this study is to determine a proper strategy to buy and sell outsource electricity to improve the overall performance of a hybrid power system comprising renewable power generators and energy storage system. The strategies are made based on three design parameters: energy-related capacity, power-related capacity of energy storage and maximum grid power rating between centralised grid and hybrid power system. While deciding on the best strategy and heuristics to be implemented, the effects on system operation and economy are indirectly analysed. It is experimented that the output can benefit electricity consumers or producers.