Biomimetic synthesis of spherical nano-hydroxyapatite in the presence of polyethylene glycol

Spherical nano-hydroxyapatite (nano-HA) was synthesized successfully by a biomimetic method using Ca(NO₃)₂·4H₂O and (NH₄)₃PO₄·3H₂O as reagents in the presence of polyethylene glycol (PEG). The crystalline phase, microstructure, chemical composition, and morphology of the obtained samples were characterized by X-ray powder diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and transmission electron microscopy (TEM). The results show that spherical nano-HA with diameter of 30–50 nm can be synthesized in the presence of a certain concentration (2–6%) of PEG. The crystallinity of HA powder synthesized in the presence of PEG was higher than that synthesized in the absence of PEG, but the crystallinity of HA reduced with increasing the concentration of PEG. The electrical conductivity (EC) of the solution revealed that PEG reduced the transfer rate of Ca²⁺ in the process of HA crystallization, indicating the interaction between PEG and HA. The possible mechanism of formation spherical nano-HA was discussed.     

数据仓库中元数据技术研究

元数据及其管理是数据仓库系统的核心部件,是内部技术人员开发与维护数据仓库的蓝图,是商业终端用户导航数据仓库以及定位有用信息的路标。该文详细介绍了无数据的功能及其管理,然后简单介绍了元数据联盟的开放信息模型。     

应用于电力谐波分析的改进相位差校正法

传统的相位差校正法在应用于电力谐波测量时,由于频谱泄漏问题的存在,在窗函数的旁瓣衰减速度较慢时存在较大误差,而校正过程对频域解析式的依赖又限制了窗函数的选用。采用一种基于汉宁窗的改进相位差校正法,其原理是对非同步采样序列的加窗快速傅里叶变换结果进行多项式变换,再依据变换所得的新频谱序列进行谐波参数的校正。将该方法和其他常用方法进行数值仿真对比,在基频随机变化的情况下进行10 000次仿真计算得到其标准误差,并缩短采样窗长以探究其实时性。结果表明,改进相位差校正法较其他常用方法有更高的精度;当基频在47~53 Hz范围内随机变化时,高次谐波的测量精度达到10-5次;在100 ms的采样窗长下,也能满足IEC 61000—4—7标准的精度要求。在兼顾计算精度的同时,该文校正公式由汉宁窗解析式推导得到,简便明了,所提方法是一种有实用价值的谐波参数检测算法。     

考虑非达西渗流的泥浆离心脱水分析

为深入探究离心脱水技术在处理主要由黏性土组成的建筑废弃泥浆时的内在机理及其影响因素,利用分段线性化方法,充分考虑黏性土中渗流的非达西特性以及土体变形的非线性特征,建立在离心作用下能够考虑其非达西渗流特性的泥浆脱水分析模型。通过与已有研究成果及室内试验结果的对比,证明了该模型的有效性。在此基础上,分析了模型参数对脱水过程的影响。研究结果表明:脱水速度和最终土水界面位移量随着电机转速的增大而增大;增加泥浆初始厚度会增大最终土水界面位移量,但会降低初期的土水界面移动速度;压缩指数在初期对土水界面位移的影响并不明显,但其增大会导致最终土水界面位移量的增加;非达西渗流参数的增大会导致土水界面位移的减少,但通过提升电机转速,可以有效地降低非达西渗流对脱水效果的不利影响。研究成果可为离心脱水技术在建筑废弃泥浆处理中的进一步优化与应用提供借鉴和参考。     

基于CAN总线的高分辨率工业显示屏控制器

为了优化工业显示屏,提出一种利用CAN总线的优势来优化工业显示屏控制器的方法。该控制器创新点在于以CAN总线作为传输,控制键和数字输入键的命令集经CAN总线传输到STM32单片机,STM32单片机运算、转换数据后经内部FSMC接口发送给FPGA,FPGA控制数据发送到SDRAM,显示屏由FPGA控制取读SDRAM内部的数据并显示,最大通信距离可达10km,通信速率可达1 Mbit/s。经实验验证,能提高传输速率并且能支持多个设备和高分辨率显示。     

A vacuum ultraviolet laser with a submicrometer spot for spatially resolved photoemission spectroscopy

Vacuum ultraviolet(VUV)lasers have demonstrated great potential as the light source for various spectroscopies,which,if they can be focused into a small beam spot,will not only allow investigation of mesoscopic materials and structures but also find application in the manufacture of nano-objects with excellent precision.In this work,we report the construction of a 177 nm VUV laser that can achieve a record-small(〜0.76 μm)focal spot at a long focal length(~45 mm)by using a flat lens without spherical aberration.The size of the beam spot of this VUV laser was tested using a metal grating and exfoliated graphene flakes,and we demonstrated its application in a fluorescence spectroscopy study on pure and Tm3+-doped NaYF4 microcrystals,revealing a new emission band that cannot be observed in the traditional up-conversion process.In addition,this laser system would be an ideal light source for spatially and angleresolved photoemission spectroscopy.     

一种满足差分隐私的轨迹数据安全存储和发布方法

近些年基于位置服务的软件便利人们生活的同时,也带来了隐私泄露的风险.针对这一问题,提出一种基于噪声前缀树结构的轨迹数据发布方法.首先根据轨迹时空特性构建轨迹等价类,利用Hilbert曲线对轨迹位置点进行划分,得到划分区域的中心点,将得到的中心点聚合成新的轨迹,因此达到减少空间复杂度的目的.然后构建前缀树,并将聚合的轨迹位置点存入到前缀树中,可以有效地提高查询效率.最后为了保护节点中存储的敏感信息,利用等差隐私预算分配方式对前缀树节点中数据添加Laplace噪声,保证轨迹数据的安全性的同时也提高了数据可用性.通过真实数据集实验对比已有的方案,验证了所提出的算法在保证数据隐私性的同时,也提高了数据可用性.     

条带开采煤柱支承压力与塑性区分布规律研究

为了对条带开采煤柱支承压力与塑性区分布规律进行研究,采用理论分析、数值模拟及现场监测的方法,通过考虑采空区上覆煤岩体成拱效应,确定出煤柱支承压力分布情况。结合煤柱支承压力分布情况,根据玉华煤矿工程条件,采用ANSYS15.0软件模拟计算不同采空区宽度(100～260 m)、不同工作面埋深(400～600 m)的煤柱最大塑性区宽度,并对玉华煤矿2410工作面回风巷道护巷煤柱的最大塑性区进行监测。研究结果表明：依据所提出的煤柱支承压力计算方法,模拟计算出的煤柱最大塑性区宽度和现场监测结果一致。给出了确定煤柱支承压力分布的计算方法,以及依据该方法计算出的煤柱最大塑性区分布规律,可为煤柱留设宽度设计提供依据。     

Delay Constrained Relay Node Placement in Wireless Sensor Networks: A Subtree-and-Mergence-based Approach

Wireless Sensor Networks (WSNs) are applied in many time-critical applications, e.g., industrial automation and smart grid. This highlights the importance of Delay Constrained Relay Node Placement (DCRNP) problem that builds a path fulfilling a specified delay constraint between each sensor and the sink by using a minimum number of relays. Due to the NP-hardness of the DCRNP problem, in this paper, a polynomial time Subtree-and-Mergence-based Algorithm (SMA) is proposed to approximately solve the DCRNP problem. First, a shortest path tree rooted at the sink and connecting all sensors is built to check the feasibility of the DCRNP problem. If the DCRNP problem is feasible, then the paths of this tree are progressively merged at some relays, which are not limited to those relays lying in the originally the originally built shortest path tree, to save deployed relays while maintaining the obedience of delay constraints. With the repetition of this mergence, the number of deployed relays is gradually reduced. Furthermore, the approximation ratio and the time complexity of the proposed SMA are elaborately analyzed. Finally, extensive simulations are conducted to demonstrate the effectiveness of this work. Simulation results show that SMA can significantly save deployed relays comparing with existing algorithms.