Effect of apple cider vinegar agent on the microstructure,phase evolution,and magnetic properties of CoFe2O4 magnetic nanoparticles

In the present study, spinel structure CoFe₂O₄ nanoparticles were successfully synthesized by the sol-gel auto-combustion technique. The effect of apple cider vinegar (ACV) addition as an organic biocompatible agent on the size, morphology, and magnetic properties of CoFe₂O₄ nanoparticles was investigated in detail. The phase evolution, particle size, and lattice parameter changes of the synthesized phase have been estimated by using Rietveld structure refinement analysis of X-ray powder diffraction data. Also, Fourier transform infrared spectra (FT-IR) of the samples verified the presence of two expected bands correspond to tetrahedral and octahedral metal-oxygen complexes within the spinel structure. Furthermore, microstructural observations revealed that ultrafine particles have a semi-spherical morphology. It was shown that the particles size decreased from ~45 to ~17 nm with an increase in the amount of ACV. Magnetic properties were carried out by vibrating sample magnetometer (VSM) at room temperature. Both the saturation magnetization (M_s) and coercivity (H_c) were found to be significantly dependent on the crystallite size and the amount of ACV.     

Efficient designs of reversible sequential circuits

The Journal of Supercomputing - Recently, the synthesis of reversible sequential circuits has attracted researchers’ attention for implementing low-power logic designs. So far, the direct and...     

Analysis and optimization of laminated composite circular cylindrical shell subjected to compressive axial and transverse transient dynamic loads

Optimization is one of the important stages in the design process. In this paper the genetic algorithms method is applied for weight and transient dynamic response and two constraints including critical buckling loads and principle strains optimization of laminated composite cylindrical shells. The multi-objective function seeks the minimum structural weight and transient dynamic response. Nine design variables including material properties (fibre and matrix), volume fraction of fibre, fibre orientation and thickness of each layer are considered. In analytical solution, vibration of composite circular cylindrical shells are investigated based on the first-order shear deformation shell theory. The boundary conditions are assumed to be fully simply support. The dynamic response of the composite shells is studied under transverse impulse and axial compressive loads. The modal technique is used to develop the analytical solution of the composite cylindrical shell. The solution for the shell under the given loading conditions can be found using the convolution integrals. An example of simply supported laminated composite cylindrical shells is given to demonstrate the optimality of the solution obtained by the genetic algorithms technique. Results are shown that the weight coefficient of multi-objective function and the type of the constraints have considerable effect on the optimum weight and dynamic response.     

Synthesis of lanthanum hydroxide and lanthanum oxide nanoparticles by sonochemical method

In this work lanthanum hydroxide nanoparticles were synthesized by sonochemical method. La₂O₃ nanoparticles were obtained after calcination of the La(OH)₃ nanoparticles precursor in air at 600 °C for 2 h. The effect of some parameters such as concentration of precursors, pulse time of sonication, time of sonication, and addition of PEG as surfactant on the morphology and the particle size were studied. The as-prepared products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectrum (XPS) and Fourier transform infrared (FT-IR) spectra.     

Synthesis, characterization and magnetic properties of NiS1+x nanocrystals from [bis(salicylidene)nickel(II)] as new precursor

[Bis(salicylidene)nickel(II)] was used as a precursor to prepare nickel sulfides nanoparticles of average size 20 nm by a chemical process in oleylamine. The products were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), ultraviolet-visible spectroscopy (UV-vis) and photoluminescence (PL) spectroscopy. Magnetization measurement indicates that both of the α-NiS and Ni₃S₄ nanoparticles show pramagnetism due to the size effect.     

Compaction Properties of Powders: The Relationship Between Compression Cycle Hysteresis Areas and Maximally Applied Punch Pressures

The consolidation behaviors of various pharmaceutical solids were characterized by investigating the relationship between the calculated hysteresis areas and the maximally applied punch pressures. An Instron universal testing apparatus and an instrumented die were used to generate compression cycle profiles at various maximally applied punch pressures for the materials studied. Based on the profiles obtained, hysteresis areas were calculated for the materials studied as a function of maximally applied punch pressures. Furthermore, model profiles describing the plastic and brittle fracture processes were utilized to derive mathematical relationships between the calculated hysteresis cycle areas and the maximally applied punch pressures. The mathematical relationships derived indicate that a linear relationship between hysteresis areas and maximally applied punch pressures exists for plastic materials, whereas for brittle materials the hysteresis areas are related to the square of the maximally applied punch pressures. Experimental data obtained support the mathematical relationships derived. The goodness of fit to the models derived is used to rank order the consolidation mechanism of various drugs and pharmaceutical excipients.     

Finite element modeling of low-velocity impact on laminated composite plates and cylindrical shells

In this study, composite laminates and shell structures subjected to low-velocity impact are investigated by numerical analysis using ABAQUS finite element code. In order to model the impact phenomena by commercial finite element codes, various procedures are available. Accurate modeling requires the appropriate selection of element type, solution method, impactor modeling method, meshing pattern and contact modeling. In this investigation, by considering several case studies with various conditions, validity of the existed modeling processes is examined. In each case, by comparing the results of various methods with the related available experimental test results in existing literature, the best procedure is proposed which can serve as benchmark method in low-velocity impact modeling of composite structures for future investigations.     

Application of glow discharge polymerisation to the preparation of reverse osmosis membranes

Reverse osmosis membranes have been prepared by the deposition of thin films on to the surface of a porous support membrane by glow discharge polymerisation. A film prepared from vinylene carbonate with the addition of 8% acrylonitrile was found to give the best salt rejection; salt rejection increased with the number of polymer coats deposited.     

Polyvinyl alcohol thin film reinforced by green synthesized zirconia nanoparticles

The focus of this work is to prepare polyvinyl alcohol (PVA) thin film reinforced by green synthesized zirconia nanoparticles. In order to do so, firstly, zirconia nanoparticles were synthesized by the rosemary extract-assisted sol-gel process as both template and stabilizing agents. The results showed that the as-obtained sample with zirconium salt to rosemary extract ratio of 1:4 had a semi-spherical morphology with the mean particle size of 12–17?nm. This nanoparticle was added as reinforcement with different ratios to the polyvinyl alcohol matrix. The mechanical property of the as-prepared nanocomposites revealed that the elastic modulus of 1?wt% ZrO2-PVA sample was about 5.5 times higher than pure PVA thin film.