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排序方式: 共有79条查询结果,搜索用时 15 毫秒
1.
Alla Popova Ghita Geoffroy Ellis M. Gartner A. Lapp 《Journal of the American Ceramic Society》2002,85(5):1303-1305
Small-angle neutron scattering (SANS) was used to study calcium silicate hydrate (C-S-H) formed via pozzolanic reaction between calcium oxide and ultrafine silica in water or polymer solutions at a temperature of 20°C. The SANS profile of this product was consistent with a structure that consisted of platelets with maximum diameters of ∼20 nm (± 5 nm) in the x – y plane, which was similar to a structure that had been deduced in previous work via X-ray diffractometry. The presence of two different types of superplasticizer in solution (at a concentration of 10 g/L) had no significant effect on its formation kinetics or its SANS profile. 相似文献
2.
In the forest industry, bark is an abundant residue, predominantly converted into calorific energy. As the antioxidant potential of phenolic compounds from sugar maple (Acer saccharum Marsh.) and red maple (Acer rubrum L.) bark has previously been established, the present study focused on the hot-water extraction optimization of these barks. Several process parameters (maple species, temperature, duration, ratio bark/water, particle size) were thus studied and large disparities were found between the two species. Extraction yield, phenolic content, and antioxidant capacity of red maple extracts were several times higher than those of sugar maple extracts. Principal component analysis, applied to the selected best extraction conditions, identified 3–4 clusters depending on the maple species. These groups were sorted from the highest extraction yield and energy consumption combined with the lowest phenolic content and antioxidant capacity, to moderate extraction yield and energy consumption with the highest phenolic content and antioxidant capacity. 相似文献
3.
Alla Popova Ghita Geoffroy Marie-France Renou-Gonnord Pascal Faucon Ellis Gartner 《Journal of the American Ceramic Society》2000,83(10):2556-2560
To better understand the mechanism of interaction between hydrating silicate-based cements and polymeric dispersants of the type used as superplasticizers in modern construction concretes, two different types of polymeric dispersant were added (at concentrations of 1 and 10 g/L) during the synthesis of calcium silicate hydrate (C-S-H) via the pozzolanic reaction in dilute slurries of lime and reactive silica, at Ca/Si ratios in the range of 0.66–1.50. Although both polymers gave degrees of adsorption of >79% in all cases studied, no significant structural modifications of the resulting C-S-H products were observed via X-ray diffraction or 29 Si magic angle spinning–nuclear magnetic resonance. These results differ from recent work in which it was shown that similar types of polymer could intercalate into the interlayers of C-S-H that was made using an alternative process. It is suggested that the process by which the C-S-H is formed may have a strong influence on whether C-S-H can intercalate polymers. This observation is relevant to understanding the fate of such polymers in concrete. 相似文献
4.
Thomas C. van den Ende Jeroen M. M. Heuts Dr. Geoffroy P. P. Gential Marten Visser Michel J. van de Graaff Dr. Nataschja I. Ho Prof. Dr. Wim Jiskoot Dr. A. Rob P. M. Valentijn Nico J. Meeuwenoord Prof. Dr. Herman S. Overkleeft Prof. Dr. Jeroen D. C. Codée Prof. Dr. Sjoerd H. van der Burg Dr. Els M. E. Verdegaal Prof. Dr. Gijsbert A. van der Marel Prof. Dr. Ferry Ossendorp Dr. Dmitri V. Filippov 《Chembiochem : a European journal of chemical biology》2021,22(7):1215-1222
Synthetic vaccines, based on antigenic peptides that comprise MHC−I and MHC-II T-cell epitopes expressed by tumors, show great promise for the immunotherapy of cancer. For optimal immunogenicity, the synthetic peptides (SPs) should be adjuvanted with suitable immunostimulatory additives. Previously, we have shown that improved immunogenicity in vivo is obtained with vaccine modalities in which an SP is covalently connected to an adjuvanting moiety, typically a ligand to Toll-like receptor 2 (TLR2). SPs were covalently attached to UPam, which is a derivative of the classic TLR2 ligand Pam3CysSK4. A disadvantage of the triply palmitoylated UPam is its high lipophilicity, which precludes universal adoption of this adjuvant for covalent modification of various antigenic peptides as it renders the synthetic vaccine insoluble in several cases. Here, we report a novel conjugatable TLR2 ligand, mini-UPam, which contains only one palmitoyl chain, rather than three, and therefore has less impact on the solubility and other physicochemical properties of a synthetic peptide. In this study, we used SPs that contain the clinically relevant neoepitopes identified in a melanoma patient who completely recovered after T-cell therapy. Homogeneous mini-UPam-SP conjugates have been prepared in good yields by stepwise solid-phase synthesis that employed a mini-UPam building block pre-prepared in solution and the standard set of Fmoc-amino acids. The immunogenicity of the novel mini-UPam-SP conjugates was demonstrated by using the cancer patient's T-cells. 相似文献
5.
Christophe Laurent Geoffroy Chevallier Alicia Weibel Alain Peigney Claude Estournès 《Carbon》2008,46(13):1812-1816
Bulk samples of double-walled carbon nanotubes are prepared for the first time. The best spark plasma sintering conditions are (1100 °C, 100 MPa). Raman spectroscopy and scanning electron microscopy show that the nanotubes are undamaged. The density is equal to 1.29 g cm−3 and the pores are all below 6 nm in diameter. The electrical conductivity is equal to 1650 S cm−1. The transverse fracture strength is equal to 47 MPa. 相似文献
6.
JM Tronchet L Brenas F Barbalat-Rey M Zsély M Geoffroy 《Canadian Metallurgical Quarterly》1998,17(6):1019-1031
Bicyclonucleosides bearing a 5-deoxy-5-N-hydroxyamino-3,N5-(1,1-ethano)-beta-D-furanosyl sugar moiety (15-18) have been prepared by glycosidation of the corresponding bicyclosugars obtained via an intramolecular reverse Cope elimination. The configuration of the asymmetric carbon of the 1,1-ethano bridge is the most important factor directing the conformation of the N-hydroxypyrrolidine ring and its invertomers ratio as shown by variable temperature H NMR experiments. 相似文献
7.
Tobin S.P. Vernon S.M. Bajgar C. Haven V.E. Geoffroy L.M. Lillington D.R. 《Electron Device Letters, IEEE》1988,9(5):256-258
Tandem cells of GaAs grown by metalorganic chemical vapor deposition (MOCVD) on thin Ge to address both higher efficiency and reduced weight are discussed. GaAs/Ge monolithic tandem cells of 4-cm 2 area have been produced with independently verified efficiencies up to 21.7% (AM0, one sun, 25°C, total area). Under AM1.5 global conditions, efficiencies are up to 24.3%. These are believed to be the highest one-sun efficiencies reported for GaAs/Ge cells, and the highest efficiency for a two-terminal monolithic tandem cell 相似文献
8.
Anubhav Jain Ivano E. Castelli Geoffroy Hautier David H. Bailey Karsten W. Jacobsen 《Journal of Materials Science》2013,48(19):6519-6534
We examine the performance of genetic algorithms (GAs) in uncovering solar water light splitters over a space of almost 19,000 perovskite materials. The entire search space was previously calculated using density functional theory to determine solutions that fulfill constraints on stability, band gap, and band edge position. Here, we test over 2500 unique GA implementations in finding these solutions to determine whether GA can avoid the need for brute force search, and thereby enable larger chemical spaces to be screened within a given computational budget. We find that the best GAs tested offer almost a 6 times efficiency gain over random search, and are comparable to the performance of a search based on informed chemical rules. In addition, the GA is almost 10 times as efficient as random search in finding half the solutions within the search space. By employing chemical rules, the performance of the GA can be further improved to approximately 12–17 better than random search. We discuss the effect of population size, selection function, crossover function, mutation rate, fitness function, and elitism on the final result, finding that selection function and elitism are especially important to GA performance. In addition, we determine that parameters that perform well in finding solar water splitters can also be applied to discovering transparent photocorrosion shields. Our results indicate that coupling GAs to high-throughput density functional calculations presents a promising method to rapidly search large chemical spaces for technological materials. 相似文献
9.
B.V. Neamţu O. Geoffroy I. Chicinaş O. Isnard 《Materials Science and Engineering: B》2012,177(9):661-665
The preparation and characterization of the nanocrystalline soft magnetic composite core based on Supermalloy powder obtained via mechanical alloying route are presented. The AC magnetic properties of the compacts were determined in frequency range from 100 Hz to 100 kHz for flux densities of 0.05 and 0.1 T. Composite materials were obtained by covering the Supermalloy particles with a polymer binder, then compacted into toroidal shape and finally polymerized. It is found that an increase of the compacting pressure from 600 MPa to 800 MPa leads to an increase of the compacts permeability by more than 8%. Also, reducing the polymer content from 2 wt.% to 0.5 wt.% leads to an increase of the magnetic losses (at 100 kHz and 0.1 T) by 380%. The removal of the stresses induced during compaction has been accomplished by a heat treatment at 170 °C for 120 h. This leads to a significant increase (12%) of the relative initial permeability of the compacts. 相似文献
10.
C?té Sylvana M.; Borge Anne I.; Geoffroy Marie-Claude; Rutter Michael; Tremblay Richard E. 《Canadian Metallurgical Quarterly》2008,44(1):155
The authors examined the role of familial risk and child characteristics in the association between the type of child care in infancy (maternal care [MC]) versus nonmaternal care [NMC]) and emotional/behavioral difficulties at 4 years old. Canadian families (N=1,358) with children between 1 and 12 months old were followed over 4 years. Family risks were found to moderate the association between type of child care and physical aggression. MC in infancy was associated with lower levels of physical aggression among children from a low-risk family background but not among those from a high-risk family background. The effect size was small (d=-0.16; confidence interval [CI]=-0.3, -0.01). Family risk and the sex of the child moderated the association between child care and emotional problems. MC in infancy was associated with a lower level of emotional difficulties among girls from low-risk families but not among boys or among children from high-risk families. The effect size was moderate (d=-0.44; CI=-0.65, -0.23). The study indicates that the effect of child care type in infancy varies by family and child characteristics. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献