Reactive Compatibilizer Precursors for LDPE/PA6 Blends, 4

Summary: The effectiveness of some thermoplastic elastomers grafted with maleic anhydride (MA) or with glycidyl methacrylate (GMA) as compatibilizer precursors (CPs) for blends of low density polyethylene (LDPE) with polyamide‐6 (PA) has been studied. The CPs were produced by grafting different amounts of MA or GMA onto a styrene‐block‐(ethylene‐co‐1‐butene)‐block‐styrene copolymer (SEBS) (KRATON G 1652), either in the melt or in solution. A commercially available SEBS‐g‐MA copolymer with 1.7 wt.‐% MA (KRATON FG 1901X) was also used. The effect of the MA concentration and of other characteristics of the SEBS‐g‐MA CPs was also studied. The specific interactions between the CPs and the blends components were investigated through characterizations of the binary LDPE/CP and PA/CP blends, in the whole composition range. It was demonstrated that the SEBS‐g‐GMA copolymers display poor compatibilizing effectiveness due to cross‐linking resulting from reactions of the epoxy rings of these CPs with both the amine and the carboxyl end groups of PA. On the contrary, the compatibilizing efficiency of the MA‐grafted elastomers, as revealed by the thermal properties and the morphology of the compatibilized blends, was shown to be excellent. The results of this study confirm that the anhydride functional groups possess considerably higher efficiency, for the reactive compatibilization of LDPE/PA blends, than those of the ethylene‐acrylic acid and ethylene‐glycidyl methacrylate copolymers investigated in previous works.

SEM micrograph of the 75/25 LD08/PA blend (with 2 phr SEBSMA1).     

Airwriting: a wearable handwriting recognition system

We present a wearable input system which enables interaction through 3D handwriting recognition. Users can write text in the air as if they were using an imaginary blackboard. The handwriting gestures are captured wirelessly by motion sensors applying accelerometers and gyroscopes which are attached to the back of the hand. We propose a two-stage approach for spotting and recognition of handwriting gestures. The spotting stage uses a support vector machine to identify those data segments which contain handwriting. The recognition stage uses hidden Markov models (HMMs) to generate a text representation from the motion sensor data. Individual characters are modeled by HMMs and concatenated to word models. Our system can continuously recognize arbitrary sentences, based on a freely definable vocabulary. A statistical language model is used to enhance recognition performance and to restrict the search space. We show that continuous gesture recognition with inertial sensors is feasible for gesture vocabularies that are several orders of magnitude larger than traditional vocabularies for known systems. In a first experiment, we evaluate the spotting algorithm on a realistic data set including everyday activities. In a second experiment, we report the results from a nine-user experiment on handwritten sentence recognition. Finally, we evaluate the end-to-end system on a small but realistic data set.     

Output feedback control for uncertain linear systems with faulty actuators based on a switching method

This paper investigates the problem of output feedback stabilization for a class of uncertain linear systems with faulty actuators via the synergy with a switching strategy. When actuators suffer a ‘destabilizing failure’ and the never‐faulty actuators cannot stabilize the given system, the closed‐loop exponential stability can still be achieved via the average dwell‐time scheme employing an arbitrary switching signal. The prerequisite condition found requires the ratio between the two lapse times, when the system is devoid of faulty actuators and when it is not so, to be less than a certain specified constant. Then the stabilizing output feedback controls are designed via the technique of linear matrix inequalities. The illustrative example and the respective simulation results demonstrate the feasibility and effectiveness of the proposed design synthesis. Copyright © 2008 John Wiley & Sons, Ltd.     

Tracking control for switched linear systems with time‐delay: a state‐dependent switching method

Tracking control for switched linear systems with time‐delay is investigated in this paper. Based on the state‐dependent switching method, sufficient conditions for the solvability of the tracking control problem are given. We use single Lyapunov function technique and a typical hysteresis switching law to design a tracking control law such that the H_∞ model reference tracking performance is satisfied. The controller design problem can be solved efficiently by using linear matrices inequalities. Since convex combination techniques are used to derive the delay independent criteria, some subsystems are allowed to be unstable. It is highly desirable that a non‐switched time‐delay system can not earn such property. Simulation example shows the feasibility and validity of the switching control law. Copyright © 2009 John Wiley and Sons Asia Pte Ltd and Chinese Automatic Control Society     

Decentralized adaptive synchronization of an uncertain complex delayed dynamical network

In this paper, we investigate the locally and globally adaptive synchronization problem for an uncertain complex dynamical network with time-varying coupling delays based on the decentralized control. The coupling terms here are bounded by high-order polynomials with known gains that are ubiquitous in a large class of complex dynamical networks. We generalize the usual technology of searching for an appropriate coordinates transformation to change the network dynamics into a series of decoupled lower-dimensional systems. Several adaptive synchronization criteria are derived by constructing the Lyapunov-Krasovskii functional and Barbalat lemma, and the proposed criteria are simple in form and convenient for the practical engineering design. Numerical simulations illustrated by a nearest-neighbor coupling network verify the effectiveness of the proposed synchronization scheme.     

Feedback passivation of switched nonlinear systems using storage-like functions

This paper addresses the issues of passivity and feedback passivation of switched nonlinear systems via multiple storage functions. The concept of storage-like functions for switched systems is presented. A sufficient condition for passivity of switched nonlinear systems is given via multiple storage functions under some switching signal. Then, the result is extended to find conditions under which a switched system is feedback equivalent to a passive switched system. Furthermore, passivity of switched cascade systems is investigated.     

A formulation for near-wall RANS/LES coupling

A near-wall eddy-viscosity formulation for LES is presented. A RANS-like eddy-viscosity corrected with the resolved turbulent stress is imposed in the near-wall region. The RANS eddy-viscosity is obtained from a resolved LES of channel flow at Re_τ = 395 and stored in a look-up table. When used with a wall stress model, this technique enables LES to be performed on coarse grids. Results are presented for channel flow at several Reynolds numbers up to Re_τ = 10,000. Various issues concerning the numerical behavior of the method are discussed.     

The impact of the composition of structural steels on their corrosion stability in liquid Pb-Bi at 500 and 400 °C with different oxygen concentrations

In recent years, heavy liquid metals have found exercise as possible coolants and targets in the conversion of radioactive elements in accelerator driven systems (ADS). Liquid lead-bismuth eutectic alloy is one of candidates for this using tanks to its suitable nuclear and physical properties. Performed examination was aimed at research of compatibility choice materials for parts of ADS with liquid Pb-Bi eutectic alloy, influence of composition choice materials on their corrosion resistance, influence of temperature and oxygen content. We performed corrosion tests of 1000 h each on approximately 20 types of structural steels (austenitic, ferritic and martensitic) in convection loops with flowing Pb-Bi at 500 and 400 °C and using different oxygen concentrations. The impact of Fe, Cr, Ni, Mn, Si, Al and Mo content on the corrosion stability of these steels was measured without and after preliminary passivation through creating thin spinel or oxide layers on their surface.     

Dependence of Fluid Catalytic Cracking Unit Performance on H-Oil Severity,Catalyst Activity,and Coke Selectivity

The effect of the quality of ebullated bed vacuum residue H-Oil hydrocracking gas oils cracked in a commercial fluid catalytic cracking unit (FCCU) on its performance was studied. Six different catalysts were employed in this study. Four catalysts were tested in a commercial FCCU, and two in a laboratory FCCU. An increase of the H-Oil hydrocracker reaction temperature was associated with a decrease in the K_W factor of the H-Oil gas oils. The diminished K_W factor of H-Oil gas oils resulted in lower FCCU conversion and higher regenerator temperatures. The FCC conversion at maximum gasoline yield is best predicted by the feed K_W factor. The higher-activity, higher-Δcoke catalyst is unfavorable for FCCU performance because the excessive regenerator temperature excursions require reduction of the throughput.