Effect of Adding Transition Metals to Copper on the Dehydrogenation Reaction of Ethanol

The present work aims to investigate the effect adding Ag, Co, Ni, Cd and Pt to copper on ethanol dehydrogenation. The catalysts synthesized by deposition–precipitation method were characterized using various physicochemical methods such as N₂ adsorption–desorption, TPR, SEM–EDX, XRD, XPS and TGA–DSC-MS. Catalytic evaluation results revealed that the predominant product of the reaction was acetaldehyde. Monometallic copper or mixed with Cd, Ag or Co show good catalytic performances. Adding nickel to copper improves the process conversion but reduces acetaldehyde selectivity, giving rise to methane in produced hydrogen. Pt-Cu/SiO₂ catalyst guides the reaction towards diethyl ether. Time on stream tests performed during 12 h at 260 °C, showed that adding Cd to Cu enhances its stability by over 30% of conversion, this is explained by the reduction of copper crystallites sintering, which makes Cd-Cu/SiO₂ a promising catalyst for the production of acetaldehyde by ethanol dehydrogenation.

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DPV: a taxonomy for utilizing deep learning as a prediction technique for various types of cancers detection

Multimedia Tools and Applications - Deep learning (DL) is a type of machine learning capable of processing large quantities of data to provide analytic results based on a particular...     

Dynamics of Plug Formation in a Circular Cylinder Under Low Bond Number Conditions: Experiment and Simulation

The goal of the current study is to investigate the dynamics of two phase interface under a low Bond number condition. Silicone oil is injected into a cylinder under a Bond number of about 0.47 via a side tube forming a T-junction with the former. The time evolution of the interface of silicon oil in a cylinder is captured using a high speed camera. The volume at which the plug is formed is then determined using an image processing tool to analyze the captured images. A numerical simulation is carried out where fluid is injected into a cylinder, under a less than unity Bond number condition, via a side tube. Numerical and experimental results are then compared.     

An improved mechanism for capacity payment based on system dynamics modeling for investment planning in competitive electricity environment

Many countries have experienced restructuring in their electric utilities. This restructuring has presented the power industries with new challenges, the most important of which is long-term investment planning under uncertain conditions. This paper presents an improved mechanism for capacity payment. The mechanism has been investigated based on system dynamic modeling. In our proposed mechanism, generators will recover a part of their investment through capacity payment. While the payment for any plant remains constant during the operation period, it depends on the investment needed to build it. The main factors affecting long-term planning have been considered in our model. The approach can be used to investigate the effects of fixed as well as variable capacity payment in market investment. We used the probability density function of load as a new concept to calculate average market price. Delays in unit constructions, estimation of demand, and market capacity growth during construction periods have been included in the proposed algorithm as parameters, which affect the regulator's decision for changing capacity payment. The model can be used by regulators to investigate strategies that may affect the fluctuations in the market.     

Four energy group neutron flux distributions in the Syrian Miniature Neutron Source Reactor using the WIMSD4 and CITATION codes

A 3-D (R, θ, Z) neutronic model for the Miniature Neutron Source Reactor (MNSR) was developed earlier to conduct the reactor neutronic analysis. The group constants for all the reactor components were generated using the WIMSD4 code. The reactor excess reactivity and the four group neutron flux distributions were calculated using the CITATION code. This model is used in this paper to calculate the pointwise four energy group neutron flux distributions in the MNSR versus the radius, angle and reactor axial directions. Good agreement is noticed between the measured and the calculated thermal neutron flux in the inner and the outer irradiation sites with relative differences less than 7% and 5%, respectively.     

CMOS photodiode with enhanced responsivity for the UV/blue spectralrange

A new photodiode for the UV/blue spectral range, which can be integrated monolithically with CMOS circuits, is presented. Such optoelectronic integrated circuits (OEICs) with a high sensitivity in the UV/blue spectral range are needed in near-future optical storage systems like digital versatile disk (DVD) or digital video recording (DVR). At 400 nm, our so-called finger photodiode achieves a responsivity of 0.23 A/W corresponding to a quantum efficiency η of 70% [with an antireflection coating (ARC)] and rise and fall times of 1.0 ns and 1.1 ns, respectively. The finger photodiode can be used in the red spectral range, too. At 638 nm, the responsivity is 0.49 A/W (η=95%) and rise and fall times of less than 2.3 ns are achieved. For the integration of the finger photodiode in an industrial 1 μm twin-well CMOS process, only one additional mask is needed in order to block out the threshold voltage implantation in the photo-active region     

Lightning Surges in Open Wire, Coaxial, and Paired Cables

During the 1968 and 1969 lightning seasons, member companies of the Telephone Association of Canada conducted a field investigation of lightning voltages induced in outside plant toll facilities at ten selected sites across Canada. Oscillograms of longitudinal surge voltages occurring in open wire, paired, and coaxial cable were continuously photographed with an automatic camera system especially developed for the investigation during each season. On completion, approximately 10 000 useful surge photographs were obtained and analyzed. The results indicate that a standard test wave, with 1000-V peak and10 times 1000-mus waveshape, simulates 99.8 percent of the lightning surges encountered in paired and coaxial cables. For open wire circuits, a more suitable test wave with 2000-V peak amplitude and4 times 200-mus waveshape is required to simulate 99.8 percent of the lightning surges. The number of surges per storm was found to be far higher than previously assumed. The highest recorded incidence during a storm was 484 surges greater than 10 V. Surge repetition intervals were short in all three types of facility; about 15 percent were less than 2 s. The surge information presented provides fundamental data on lightning surge effects in Canadian telephone plants which were previously unavailable. The assembled data will be of value to the protection engineer when designing future protection systems, and also to the transmission engineer concerned with noise problems.     

Preliminary investigation of a vapor-open envelope tailored for subtropical climate

Concerning global warming and resource depletion, the impact of buildings in subtropical regions is becoming even greater due to a high growth rate of urbanized areas. From the viewpoint of building physics, the main problem concerning subtropical climate is the high level of humidity in combination with high temperature. In this study, a flexible building envelope consisting of wood and clay components was developed so that the materials and the assemblies can be easily tailored to comply with local climatic conditions. The movement and accumulation of moisture in the wall was of prime concern. This has been investigated by means of testing full scale walls in a climate chamber and the corresponding one dimensional transient heat and transfer simulation. In order to achieve a consistency between calculation and measurement, the individual materials were tested for their hygric and thermal properties. Based on these findings attempts were made to calculate the behavior of an optimized wall assembly under real climatic conditions of central Japan. As a result, it was shown that the hygrothermal behavior of the envelope is predictable by means of the models and the simulation program used, and that no risk of interstitial condensation and mold growth was predicted under the real climatic conditions of Kyoto.     

Increasing the aqueous solubility of acetaminophen in the presence of polyvinylpyrrolidone and investigation of the mechanisms involved

It was shown that the aqueous solubility of acetaminophen in the presence of polyvinylpyrrolidone (PVP) increased. The solubility at 25°C increased from 14.3 mg mL^-1 in the absence of PVP, to 19.7 mg mL^-1 in the presence of 4% w/v PVP, and to 26.7 mg mL^-1 in the presence of 8% w/v PVP. Dialysis studies indicated that there is a potential of binding between PVP and acetaminophen in their aqueous solutions. Dialysis studies also revealed that the nature of interaction between PVP and acetaminophen is physical and reversible, and there was no strong binding between PVP and acetaminophen in their solutions. Infrared spectroscopy of acetaminophen/PVP solid dispersion indicated that the mechanism of interaction between PVP and acetaminophen is via hydrogen bonding. Therefore, the increase in solubility of acetaminophen in the presence of PVP is probably attributed to its ability to form a water-soluble complex with PVP.     

Retrofitting of reinforced concrete beams using composite laminates

This paper presents the results of an experimental study to investigate the behaviour of structurally damaged full-scale reinforced concrete beams retrofitted with CFRP laminates in shear or in flexure. The main variables considered were the internal reinforcement ratio, position of retrofitting and the length of CFRP. The experimental results, generally, indicate that beams retrofitted in shear and flexure by using CFRP laminates are structurally efficient and are restored to stiffness and strength values nearly equal to or greater than those of the control beams. It was found that the efficiency of the strengthening technique by CFRP in flexure varied depending on the length. The main failure mode in the experimental work was plate debonding in retrofitted beams.