排序方式: 共有33条查询结果,搜索用时 15 毫秒
1.
Satoru Iwamori Takehiro Miyashita Shin Fukuda Shouhei Nozaki Nobuhiro Fukuda Kazufuyu Sudoh 《The Journal of Adhesion》1997,63(4):309-321
Peel strength between a copper (Cu) thin film and a polyimide (pyromellitic dianhydride-oxydianiline, or PMDA-ODA) substrate is reduced by heat treatment at 150°C in air. In this work, we investigated the peel strength, the morphology of the interface between Cu films and polyimide substrates using optical microscopy and electron microscopy, and chemical change of the interface using Auger electron spectroscopy (AES) and micro X-ray photoelectron spectroscopy (XPS). The analysis showed that CuO “lumps” were present on the peeled surface of PMDA-ODA after heat treatment at 150°C in air. The peeled surfaces of other polyimide substrates were also analyzed: biphenyl dianhydride-para phenylene diamine (BPDA-PDA) and biphenyl dianhydride-oxydianiline (BPDA-ODA). CuO lumps were present on the peeled surface of BPDA-ODA after the heat treatment, but not that of BPDA-PDA. Compared with the adhesion strength for the Cu thin film, the adhesion strength was high for the Cu/PMDA-ODA and Cu/BPDA-ODA laminates, but the adhesion strength was very low for the Cu/BPDA-PDA laminate. This low strength is the reason that CuO lumps were not detected on the peeled surface of the BPDA-PDA substrate. These CuO lumps were related to the adhesion degradation of the Cu/polyimide laminates after the heat treatment. 相似文献
2.
Toshinori Okura Giichi Sudoh Hiroyuki Inoue Takafumi Kanazawa 《Journal of Materials Science》1995,30(4):1033-1036
The SiKΒ X-ray emission spectra for several silicates and silico-phosphates were measured using a high-resolution X-ray fluorescence spectrometer with two InSb(III) analyser crystals. Molecular orbital calculation analysis for the obtained spectra was performed by a SCC-DV-Xα method and the energy positions and relative intensities of the spectral fine structures were calculated with Slater's transition-state method. The calculated results interpreted the spectral profiles successfully. The energy shifts of the SiKΒ main peak were also discussed in terms of the electronegativity of the second-nearest-neighbour atoms. These shifts were attributed to the changes in the stability of the Si-O bonds due to the existence of second-nearest-neighbour P atoms. 相似文献
3.
S Sudoh Y Kawamura S Sato R Wang TC Saido F Oyama Y Sakaki H Komano K Yanagisawa 《Canadian Metallurgical Quarterly》1998,71(4):1535-1543
Mutations in the presenilin genes PS1 and PS2 cause the most common form of early-onset familial Alzheimer's disease. The influence of PS1 mutations on the generation of endogenous intracellular amyloid beta-protein (A beta) species was assessed using a highly sensitive immunoblotting technique with inducible mouse neuroblastoma (Neuro 2a) cell lines expressing the human wild-type (wt) or mutated PS1 (M146L or delta exon 10). The induction of mutated PS1 increased the intracellular levels of two distinct A beta species ending at residue 42 that were likely to be A beta1-42 and its N-terminally truncated variant(s) A beta x-42. The induction of mutated PS1 resulted in a higher level of intracellular A beta1-42 than of intracellular A beta x-42, whereas extracellular levels of A beta1-42 and A beta x-42 were increased proportionally. In addition, the intracellular generation of these A beta42 species in wt and mutated PS1-induced cells was completely blocked by brefeldin A, whereas it exhibited differential sensitivities to monensin: the increased accumulation of intracellular A beta x-42 versus inhibition of intracellular A beta1-42 generation. These data strongly suggest that A beta x-42 is generated in a proximal Golgi, whereas A beta1-42 is generated in a distal Golgi and/or a post-Golgi compartment. Thus, it appears that PS1 mutations enhance the degree of 42-specific gamma-secretase cleavage that occurs in the normal beta-amyloid precursor protein processing pathway (a) in the endoplasmic reticulum or the early Golgi apparatus prior to beta-secretase cleavage or (b) in the distinct sites where A beta x-42 and A beta1-42 are generated. 相似文献
4.
T Yabe T Yamada-Okabe T Nakajima M Sudoh M Arisawa H Yamada-Okabe 《Canadian Metallurgical Quarterly》1998,258(3):941-947
Saccharomyces cerevisiae harbors three chitin synthases termed Chs1p, Chs2p and Chs3p. Previously, we demonstrated that con1, a region that is highly conserved among all chitin synthases, contains amino acids essential for the catalytic activity of the enzyme and that Asp562, Gln601, Arg604, and Trp605 found in con1 together with Asp441 were probable catalytic sites of the enzyme. Here we report that another region, con2, in the C-terminal half of Chs2p is also conserved exclusively in chitin synthases that resemble S. cerevisiae Chs1p and Chs2p. Alanine substitutions for the conserved amino acids in con2 identified five amino acids, Asn797, His799, Asp800, Trp803, and Thr805, the mutation of which severely diminished enzymatic activity and the enzyme's ability to rescue the yeast chs2 delta chs3 delta null mutant strain. Although the activities of some of the mutant enzymes were too low to measure enzyme kinetics, most of the alanine mutations in con2 affected the kcat values rather than the K(m) values. Whereas a conservative mutation of Asn797 restored the activity, those of His799, Asp800, Trp803, and Thr805 did not. A fine alignment of the amino acid sequences of con2 and Chs3p revealed that Asp800, Trp803 and Thr805 are completely conserved near the C-terminal ends of Chs3p and its homologs in other fungi. On the basis of these findings, we propose that Asp800, Trp803, and Thr805 in con2 are additional residues involved in catalysis, and hypothesise that Asp800 together with the previously identified Asp441 and Asp562 serve as polar residues necessary for the acid-based catalytic reaction of chitin synthase. 相似文献
5.
New reliable and accurate extensometers are presented using a single amorphous core multivibrator with a dc output. These extensometers can detect strains as large as 40 percent for tensile test samples without any destruction due to the outstanding elasticity of the Metglas 2605A amorphous ribbon-wound cores. High linearity (0.18 percent full scale (FS)) is realized by annealing and applying 1000 times alternating stresses to the cote. Hysteresis against alternating strains is removed to less than 0.48 percent FS by the effect of a compensation spring. The amorphous core extensometer has advantageous points regarding reliability, temperature stability, and maximum operating temperature over conventional extensometers using semiconductor strain gauges. 相似文献
6.
Koseki T Okuda M Sudoh S Kizaki Y Iwano K Aramaki I Matsuzawa H 《Journal of Bioscience and Bioengineering》2003,96(3):232-241
7.
The instantaneous wavelength shift in gain-switched short optical pulses from absorptive-grating gain-coupled distributed feedback semiconductor lasers showed unusual behaviour which resulted in much smaller chirping than that in conventional lasers. Measurements of spontaneous emission from the absorptive grating layer indicate carrier accumulation in that layer. The origin of the low chirping has been attributed to the fact that the index increase due to carrier depletion in the active layer is compensated for by an index decrease due to carrier accumulation in the grating layer 相似文献
8.
We have recently demonstrated that the time-dependent difference in urinary excretion of furosemide, a loop diuretic, diminishes during the aging process and disappears by 18 months of age in rats. The present study was undertaken to examine whether the amplitude of the daily variations in the urinary excretion of furosemide or their pattern, or both, are influenced in aged animals. Young (3 months of age) and aged (30 months of age) Wistar rats were maintained under conditions of light from 7 am to 7 pm and dark from 7 pm to 7 am. Furosemide (30 mg/kg) was given orally at 4 am, 8 am, 12 am, 4 pm, 8 pm or 12 pm. Urine was collected for 8 hours after furosemide administration and urinary excretion of furosemide was determined. There were significant daily variations in the urinary furosemide and the urine volume with the peak at 8 am and the trough at 12 pm in both groups of rats. The differences in these parameters between the 8 am and 12 pm trials were significantly smaller in the aged than in the young rats. These results suggest that the age-related alteration in the time-dependent phenomenon of furosemide is caused by the decreased amplitude of the daily variation in the urinary furosemide excretion and its diuretic effect. 相似文献
9.
Giichi Terui 《Journal of Low Temperature Physics》1976,25(5-6):645-670
From the second-sound velocityU
2
near the superfluid transition point, the superfluid densities in3He-4He mixtures,
s
(X) and
s
(), were deduced along the paths of constant3He concentrationX and of constant chemical potential difference of3He and4He. The following critical exponents of
s
are determined: (a) =XX for
s
(X) in the(X, T) plane,(b) X for
s
(X) in the(, T) plane, and(c) for
s
() in the(, T) plane. It is found that and X
change by about 4–6% relative to with increasing3He concentration up toX=0.4 and by 8–10% up toX=0.53. It seems that, belowX=0.53, universality hold for . Values of have been found to be in good agreement with the critical exponent of
s
in pure4He under constant pressure. The values of and X
forX0.53 are also found to be consistent with the scaling relations in the (,T) plane of3He-4He mixture.Work performed in part while at the Electrotechnical Laboratory. 相似文献
10.
Keiichi Okajima Atsushi Ikeda Kazunori Kamoshita Masao Sudoh 《Electrochimica acta》2005,51(5):972-977
Fullerene-activated carbon composite electrodes were prepared and their charge/discharge characteristics were studied for use in a high power electric double-layer capacitor. The capacitance of the C60-loaded activated carbon fiber (ACF) electrodes became greater than that of the unloaded ACF at charge/discharge current densities above 50 mA/cm2. In order to obtain a highly dispersed C60-loaded electrode, an ultrasonic treatment was performed. The size of the C60 agglomerate decreased from 1-2 to 0.1 μm or less, and the capacitance of the C60-loaded ACF electrodes increased with an increase in the ultrasonic treatment time. A higher capacitance of 172 F/g was obtained at 50 mA/cm2 on a 1 wt% C60-loaded electrode with ultrasonic treatment, and the C60-loaded ACF electrode also showed a higher cycle performance. 相似文献