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Nur Lina Rashidah Mohd Rashid Abdullah Abdul Samat Abdul Azim Jais Mahendra Rao Somalu Andanastuti Muchtar Nurul Akidah Baharuddin Wan Nor Roslam Wan Isahak 《Ceramics International》2019,45(6):6605-6615
The performance of low-to-intermediate temperature (400–800?°C) solid oxide fuel cells (SOFCs) depends on the properties of electrolyte used. SOFC performance can be enhanced by replacing electrolyte materials from conventional oxide ion (O2-) conductors with proton (H+) conductors because H+ conductors have higher ionic conductivity and theoretical electrical efficiency than O2- conductors within the target temperature range. Electrolytes based on cerate and/or zirconate have been proposed as potential H+ conductors. Cerate-based electrolytes have the highest H+ conductivity, but they are chemically and thermally unstable during redox cycles, whereas zirconate-based electrolytes exhibit the opposite properties. Thus, tailoring the properties of cerate and/or zirconate electrolytes by doping with rare-earth metals has become a main concern for many researchers to further improve the ionic conductivity and stability of electrolytes. This article provides an overview on the properties of four types of cerate and/or zirconate electrolytes including cerate-based, zirconate-based, single-doped cerate–zirconate and hybrid-doped cerate–zirconate. The properties of the proton electrolytes such as ionic conductivity, chemical stability and sinterability are also systematically discussed. This review further provides a summary of the performance of SOFCs operated with cerate and/or zirconate proton conductors and the actual potential of these materials as alternative electrolytes for proton-conducting SOFC application. 相似文献
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Dr. Lina Liang Tong-You Wade Wei Pei-Yu Wu Wouter Herrebout Ming-Daw Tsai Prof. Stéphane P. Vincent 《Chembiochem : a European journal of chemical biology》2020,21(20):2982-2990
d -Glycero-d -manno-heptose-1β,7-bisphosphate (HBP) and d -glycero-d -manno-heptose-1β-phosphate (H1P) are bacterial metabolites that were recently shown to stimulate inflammatory responses in host cells through the activation of the TIFA-dependent NF-κB pathway. To better understand structure-based activity in relation to this process, a family of nonhydrolyzable phosphonate analogues of HBP and H1P was synthesized. The inflammation modulation by which these molecules induce the TIFA-NF-κB signal axis was evaluated in vivo at a low-nanomolar concentration (6 nM) and compared to that of the natural metabolites. Our data showed that three phosphonate analogues had similar stimulatory activity to HBP, whereas two phosphonates antagonized HBP-induced TIFA-NF-κB signaling. These results open new horizons for the design of pro-inflammatory and innate immune modulators that could be used as vaccine adjuvant. 相似文献
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In this work,the ionospheric variability is analyzed by applying the wavelet decomposition technique to the noontime fo F2,F10.7,interplanetary magnetic field(IMF)Bz,Ap,and lower thermospheric temperature at pressure of 10?4 h Pa in 2002.Results show that the variance of periodic oscillations in the ionosphere is largest in the 2–4-day period and declines with the increase of the period.The maximum variance of the periodic oscillations in solar irradiation is in the 16–32-day period.For geomagnetic activities,most of the variance is about equally distributed on intervals of periods shorter than 32 days.Variance distributions of IMF Bz and lower thermospheric temperature are similar to those of the ionosphere.They show the maximum in the 2–4-day period and decline with the increase of the period.By analyzing the distributions of the variances,the potential connections between the ionosphere and the external sources are discussed. 相似文献
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Dovile Stravinskiene Aiste Sliziene Lina Baranauskiene Vilma Petrikaite Aurelija Zvirbliene 《International journal of molecular sciences》2020,21(24)
Monoclonal and recombinant antibodies are widely used for the diagnostics and therapy of cancer. They are generated to interact with cell surface proteins which are usually involved in the development and progression of cancer. Carbonic anhydrase XII (CA XII) contributes to the survival of tumors under hypoxic conditions thus is considered a candidate target for antibody-based therapy. In this study, we have generated a novel collection of monoclonal antibodies (MAbs) against the recombinant extracellular domain of CA XII produced in HEK-293 cells. Eighteen out of 24 MAbs were reactive with cellular CA XII on the surface of live kidney and lung cancer cells as determined by flow cytometry. One MAb 14D6 also inhibited the enzymatic activity of recombinant CA XII as measured by the stopped-flow assay. MAb 14D6 showed the migrastatic effect on human lung carcinoma A549 and renal carcinoma A498 cell lines in a ‘wound healing’ assay. It did not reduce the growth of multicellular lung and renal cancer spheroids but reduced the cell viability by the ATP Bioluminescence assay. Epitope mapping revealed the surface-exposed amino acid sequence (35-FGPDGENS-42) close to the catalytic center of CA XII recognized by the MAb 14D6. The variable regions of the heavy and light chains of MAb 14D6 were sequenced and their complementarity-determining regions were defined. The obtained variable sequences were used to generate recombinant antibodies in two formats: single-chain fragment variable (scFv) expressed in E. coli and scFv fused to human IgG1 Fc fragment (scFv-Fc) expressed in Chinese Hamster Ovary (CHO) cells. Both recombinant antibodies maintained the same specificity for CA XII as the parental MAb 14D6. The novel antibodies may represent promising tools for CA XII-related cancer research and immunotherapy. 相似文献
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考察了双河油田双河联、江河联注入水堵塞地层的因素;膨胀性黏土,悬浮固体颗粒。细菌及悬浮污油。含膨胀性黏土的双河南、双河北及不含膨胀性黏土的双江岩心粉,在注入水中相对于地层水中的体积膨胀度分别为14.5%、11.1%及0.02%;注入100PV不含悬浮颗粒的等体积比地层水、注入水混合水使双河、双江岩心渗透率分别下降7%和4%、9%和7%。注入水中悬浮颗粒引起岩心渗透率下降,粒径越大、颗粒浓度越大、注入量越大,则渗透率越低。在粒径2.1μm或颗粒浓度3mg/L前后下降幅度变化较大。注入水中硫酸盐还原菌引起岩心渗透率下降,含菌量越大则渗透率开始下降时的注水量越小,注入含菌50个/L的水100PV使岩心渗透率下降7%。岩心对注水合油量敏感,注入含油量20mg/L的水50PV使岩心渗透率下降20%。在岩心注水实验中渗透率下降最严重的是双河南岩心,其次是双河北岩心.江河岩心较轻,注入精细过滤水的双河北岩心渗透率下降大大减少.说明悬浮固体是造成注水堵塞的主要因素。为了解除双河油田注水井的堵塞,研制了含黏土稳定剂、缓蚀剂、铁离子稳定剂、互溶剂的土酸液,与南阳油田使用的低伤害酸液一起,用于1口注水井的解堵,效果良好。图7表4参5。 相似文献
8.
用LabVIEW演示PID控制规律 总被引:1,自引:0,他引:1
利用虚拟仪器技术,采用LabVIEW图形编程环境,设计了一个程序,用于演示PID控制规律,可将其用于教学中,以此为例说明LabVIEW对传统教学方法所带来的巨大变化. 相似文献
9.
利用粉煤灰合成分子筛及其脱除高浓度氨氮的研究 总被引:1,自引:0,他引:1
利用工业废渣流化床粉煤灰成功合成出X型分子筛.通过XRD衍射表征发现,碱的添加量是影响合成分子筛结晶度的关键因素,而原料中含有微量的α-石英对合成的影响较小.应用合成的分子筛处理高浓度氨氮废水效果良好.该项研究不仅可解决粉煤灰堆置所引起的占用土地污染环境等问题,而且可解决高浓度氨氮废水的降解难题,以废治废,具有很高的经济和社会效益. 相似文献
10.
气动贯通式潜孔锤反循环连续取心取样钻进新技术在河南钼矿中应用 总被引:4,自引:0,他引:4
三道庄钼矿勘探生产中钻遇的地层非常复杂,采用其他方法均无法实现钻进,经过分析比较,决定采用贯通式潜孔锤反循环连续取心(样)钻进新技术来解决该地层钻进难、成孔难、取样难等三大问题。文章从钻进技术特点、工作原理等方面对该技术进行详细分析,得出其具有钻进效率高、岩心(样)采取率高、成孔质量好等突出优点。并介绍了钻进主要设备机具的配套、施工工序、操作要点、遇到问题的解决方法等。在河南钼矿露天采石场应用该项技术,有效避免了塌孔和卡钻事故,工程进展顺利、质量好、岩心(样)采取率在98%以上,取得了良好的效果。针对在生产试验中遇到的某些问题,作者提出了一些改进建议。 相似文献