Plastic deformation of linear polyethylene containing row structures

The mechanical and thermal properties of highly oriented polyethylene films containing shish kebab type morphology are studied. At low deformations (strain<10%) strong work hardening is observed. Higher deformations ((40%) give rise to strain softening of the material and a decrease in the Young's modulus of as much as one-third of its initial value. In addition, the high melting component of the material originating from the shish-type crystals vanishes on higher deformation. The deformation processes are discussed from the point of view of a fibre-composite material and structural changes during the deformation are followed by transmission electron microscopy.     

Designing polyethylene terephthalate‐based barrier resins

We have studied the efficiencies of commercially available barrier resins used for food packaging and beverage bottle applications and compared them with resins made using copolymer and blending approaches. The effects of various copolymer related parameters that influence oxygen barrier performance and the underlying mechanisms for these effects in PET‐based copolymers and blends were investigated. Using these approaches, it is possible to make highly effective PET‐based copolymers for gas barrier applications. Blending of PET with phenolic and other organic materials shows equivalent barrier performance in PET copolymers having comonomer levels of <8‐mole %. Reduction in oxygen permeation rates results from the reduction or elimination of short range molecular motion of polyethylene terephthalate molecules. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Morphology–property relationship in oriented PET films: Microstructural reorganization during heat treatment

Morphology–property relationships for simultaneously biaxially stretched films and heatset with fixed dimensions in the temperature range of 100–240°C have been studied. The observed transition in various properties at 180°C can be explained on the basis of microstructural changes caused by competition among several processes, such as crystallization, solid-state thickening, melting, and molecular relaxation as well as by melting and recrystallization. The resulting structures and, thereby, the properties are different in temperature Regime-II (T_g to T_max) and Regime-III (T_max to T_m). In Regime-II, the high rate of crystallization compared to the rate of molecular relaxation develops a constrained amorphous phase, whereas the predominant melting and recrystallization process in Regime-III generates the relaxed amorphous phase. The structural reorganization during heat treatment is almost the same for uniaxially oriented film, fibers, and biaxially oriented films prepared under similar processing conditions. © 1994 John Wiley & Sons, Inc.     

Observation of screw dislocations in lamellar stacks of polyethylene and isotactic polystyrene

Lamellar stacks of polyethylene and isotactic polystyrene crystals are investigated by dark-field electron microscopy and electron diffraction. The observed effects suggest the presence of screw dislocations, the Burgers vector of which is parallel to the chain direction. The dislocation density in lamellar stacks is greater than 10¹¹ cm^?2. The occurrence of the dislocations is attributed primarily to shear forces arising from thermal stresses.     

Numerical study of mixed convective heat transfer in a lid‐driven enclosure with rotating cylinders

A numerical simulation is performed to characterize the mixed convective transport in a three‐dimensional square lid‐driven enclosure with two rotating cylinders. The top wall is moving in the positive x‐direction, and the bottom wall is at a higher fixed temperature compared with all other isothermal walls. Both cylinders are rotating in its own plane about their centroidal axis. On the basis of rotation of both cylinders in clockwise or counter‐clockwise directions, four rotational models are studied. Various controlling parameters considered in the present study are Grashof number (10 ³ < Gr < 10 ⁵), rotating speed of the cylinder (5 < ω < 50), and the Reynolds number based on top wall movement is fixed to 100. The effect of cylinder rotation on the heat transfer of bottom wall is reported with the help of streamlines, contour plots of z‐component of vorticity, averaged and local Nusselt number, ratios of secondary flow and drag coefficient. It is observed that the heat transfer at the bottom wall is substantially dependent on the rotational model and rotational speed of the cylinder.     

Phase separation in immiscible silver–copper alloy thin films

Far from equilibrium, immiscible nanocrystalline Ag–Cu alloy thin films of nominal composition Ag–40 at.% Cu have been deposited by co-sputter deposition. Both X-ray and electron diffraction studies indicate that the as-deposited films largely consist of nanocrystalline grains of a single alloyed face-centered cubic (fcc) phase. However, detailed three-dimensional atom probe tomography studies on the same films give direct evidence of a nanoscale phase separation within the columnar grains of the as-deposited Ag–Cu films. Subsequent annealing of these films at 200 °C leads to two effects; a more pronounced nanoscale separation of the Ag and Cu phases, as well as the early stages of recrystallization leading to the breakdown of the columnar grain morphology. Finally, annealing at a higher temperature of 390 °C for a long period of time leads to complete recrystallization, grain coarsening, and a complete phase separation into fcc Cu and fcc Ag phases.     

Sputter deposition of self-organized nanoclusters through porous anodic alumina templates

Silver nanoparticles were sputter deposited through self organized hexagonally ordered porous anodic alumina templates that were fabricated using a two-step anodization process. The average pore diameter of the template was 90 nm and the interpore spacing was 120 nm. Atomic force microscope studies of the sputter-deposited silver nanoparticle array on a Si substrate indicate an approximate replication of the porous anodic alumina mask. The nature of the deposition depends strongly on the process parameters such as sputtering voltage, ambient pressure and substrate temperature. We report a detailed study of the sputtering conditions that lead to an optimal deposition through the template.     

Insights into structural difference between sodium polyacrylate PAA and sodium polymethacrylate PMA in salt solutions investigated by molecular simulations

Journal of Materials Science - The difference in the structural properties of highly charged polyacrylic acid (PAA) and polymethacrylic acid (PMA) is investigated by atomistic molecular dynamics...     

Backpropagation neural-network-based retrieval of atmospheric water vapor and cloud liquid water from IRS-P4 MSMR

A new multiparameter retrieval algorithm based on a backpropagation neural network (BPNN) has been developed for deriving integrated water vapor (WV) and cloud liquid water (CLW) contents over oceans from brightness temperatures (BTs) measured by the Multi-frequency Scanning Microwave Radiometer (MSMR) launched onboard Indian Remote Sensing satellite IRS-P4. The MSMR measures brightness temperatures in vertical and horizontal polarizations at 6.0-, 10.65-, 18.0-, and 21.0-GHz frequencies. The data are available at three spatial grid resolutions of 150, 75, and 50 km. In this paper, a BPNN has been trained using brightness temperatures simulated through radiative transfer model and simulated surface and atmospheric parameters. The present algorithm has been compared with the operational MSMR retrieval algorithm based on statistical regression using the same dataset. The validation of WV with in situ data (Vaisala radiosonde) is presented. Moreover, comparison of WV and CLW derived from MSMR using BPNN with the finished products from the Special Sensor Microwave/Imager and the Tropical Rainfall Measuring Mission Microwave Imager has also been carried out. The complexity of the BPNN in retrieval of geophysical products, individually and simultaneously, has also been discussed. Simultaneous retrieval of WV and CLW improves the results.