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排序方式: 共有387条查询结果,搜索用时 31 毫秒
1.
2.
In order to stabilize ultrafine particles of SnO2 which is essential to obtain high gas sensitivity, a systematic investigation was undertaken regarding the stabilizing effects of 5 at% impregnated foreign additives, consisting of oxides or polyoxy compounds of 31 metals and 3 non-metals. The data of specific surface area, SA, as well as SnO2 crystallite size, D, evaluated from X-ray diffraction showed that the additives could be classified into several groups according to the effectiveness. The most effective group, consisting of P-Ba, Sm, Ba, P, Mo, W, Ca, Sr, Cr and In, could keepD less than 10 nm even after calcination at 900°C, whereas pure SnO2 underwent grain growth to haveD of 13 and 27 nm at 600 and 900°C, respectively. Electron microscopy revealed that neck sizes, X, between crystallites were fairly proportional toD(X/D = 0.80). A simple analysis of SA and D data based on a monosized sphere model suggested that each crystallite was coordinated with 3–4.5 neighbours through the necks. The existing state and stabilizing mechanism of additives are discussed in conjunction with the electrical resistance of porously sintered elements. 相似文献
3.
Hironori Oda 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1995,63(3):223-228
Fluorans are given considerable attention as functional dyes for heat-and/or pressure-sensitive recording media. Numerous potential metal complexes were synthesised to prolong the life of coloured species. The protecting effect of these compounds against the photofading was examined on cellulose. It was found that the zinc or nickel salts of 3,5-dihydroxy-2-naphthoic acid and its derivatives can be applied as effective stabilisers against the fading of fluoran dyes. 相似文献
4.
Fischer–Tropsch synthesis was carried out in slurry phase over uniformly dispersed Co–SiO2 catalysts prepared by the sol–gel method. When 0.01–1 wt.% of noble metals were added to the Co–SiO2 catalysts, a high and stable catalytic activity was obtained over 60 h of the reaction at 503 K and 1 MPa. The addition of noble metals increased the reducibility of surface Co on the catalysts, without changing the particle size of Co metal significantly. High dispersion of metallic Co species stabilized on SiO2 was responsible for stable activity. The uniform pore size of the catalysts was enlarged by varying the preparation conditions and by adding organic compounds such as N,N-dimethylformamide and formamide. Increased pore size resulted in decrease in CO conversion and selectivity for CO2, a byproduct, and an increase in the olefin/paraffin ratio of the products. By modifying the surface of wide pore silica with Co–SiO2 prepared by the sol–gel method, a bimodal pore structured catalyst was prepared. The bimodal catalyst showed high catalytic performance with reducing the amount of the expensive sol–gel Co–SiO2. 相似文献
5.
Hironori Minoshima 《Chemical engineering science》2006,61(6):2101-2102
Previously developed model for spray drying of slurry droplets with high solid content (Liang, 2001) was revised to describe correctly a boundary condition on the outer surface of droplet on basis of the rate of liquid evaporation. 相似文献
6.
Summary Multi-step precipitation separation system was developed by using aqueous mixtures of some thermosensitive polymers. The following
three polymers were used here; poly(N-n-propylacrylamide), poly(N-isopropylacrylamide), and poly(N-isopropylmethacrylamide). A mixture of the three polymers showed three endothermic peaks, and the peak top temperatures were
almost consistent with that of the each polymer solution. The polymers were purified by thermal precipitation to obtain fractions
which can respond in narrow temperature ranges prior to use. In the case of the precipitation separation of two polymers mixtures,
purities of the obtained precipitate and supernatant fractions became high comparing with the case in which the unpurified
polymers were used. Parts of the polymers which were not the precipitation targets were also precipitated by the separation
procedures. This was caused not only by insolubilization of the non-targeted polymers due to their phase transitions but also
by their non-specific entanglement with the targeted polymers. The purities of the fractions also improved when the difference
of the phase transition temperature between two polymers was large enough to avoid the coprecipitation. In the case of the
precipitation separation of mixtures of the three polymers, purities of each fraction also improved when the purified polymers
were used. 相似文献
7.
The compositions of ester- and amide-linked fatty acids from ceramides of human vernix caseosa were described with emphasis
on the distribution of the branched-chain fatty acid (BCFA). Two novel ceramides were isolated from vernix caseosa in the
course of this study: the acylated type of esterified α-OH-hydroxyacid/sphingosine ceramide (Cer[EAS]) and nonacylated type
of non-OH fatty acid/hydroxysphingosine ceramide (Cer[NH]). Their chemical structures were identified by nuclear magnetic
resonance and chemical procedure. The Cer[EAS] was an acylceramide and consisted of the highest concentrations of ester- and
amide-linked BCFA (62 and 67%, respectively). The iso- or anteiso-branching structures of the aliphatic chains were confirmed
by the mass spectra of their picolinyl or pyrrolidide derivatives. As a whole, amide-linked fatty acids of ceramides 1–7 and
Cer[NH] were normal types of straight-chain fatty acids with or without α- or ω-hydroxylation. The BCFA concentrations of
amide-linked fatty acids in these ceramides (ceramides 1–7 and Cer[NH]) were low and less than 10%. The BCFA thus occurred
exclusively in a novel acylceramide of Cer[EAS] in the vernix caseosa. 相似文献
8.
Residues important for the function of a multihelical DNA binding domain in the new transcription factor family of Cam and Tet repressors 总被引:5,自引:0,他引:5
Aramaki Hironori; Yagi Naoto; Suzuki Masashi 《Protein engineering, design & selection : PEDS》1995,8(12):1259-1266
We report that some prokaryotic repressors including CamR andTetR belong to the same family. CamR and TetR bind to DNA usinga multihelical DNA binding domain (DBD) at the N-termini ofthe proteins, while the C-termini are important for regulatingthe DNA binding in a manner dependent on their co-factors (camphorfor CamR, tetracycline for TetR). In all, 11 important aminoacid positions have been identified in the CamR DBD by the systematicsubstitution of residues by Ala. Of the 11 positions, 10 areeither buried in the core, and thus important for creating thehydrophobic environment, or exposed on the surface, and thusimportant for binding to DNA. The eleventh residue, Gly, seemsto be important for a loop structure. The DNA binding mode ofthis type of DBD and a general mechanism of regulating theirDNA binding are discussed in reference to the crystal structureof TetR [Hinrichs et al., (1994) Science, 264, 418420]. 相似文献
9.
Sohei Sato Hironori Hondoh Satoru Ueno 《Journal of the American Oil Chemists' Society》2021,98(3):269-280
Fat bloom in chocolate is a substantial problem that affects its sensory properties, such as texture and appearance. This phenomenon is because of diffuse light reflection on a roughened surface of chocolate, caused by structural changes of fat crystals subjected to various temperature conditions. The purpose of this study is to characterize the fat bloom formed through gradual two-step cooling after exposure to temperatures (35–37 °C) slightly above the cocoa butter Form βV melting point (33.8 °C). To clarify the fat bloom formation process, the structural changes in cocoa butter and on the chocolate surface, at the dynamic thermal condition for bloom formation, was investigated using X-ray diffraction (XRD), fluorescence light microscopy, and scanning electron microscopy (SEM). The results revealed that an entirely light brown fat bloom occurred, even in the absence of the Form βVI or other polymorphic transformation. Microscopic observation showed that the light brown appearance was because of the porous structure on the chocolate surface. This porous structure was formed by liquid oil moving inside of chocolate from the surface. The formation of a coarse network and the subsequent de-oiling, because of movement of unsolidified liquid fat into the chocolate, appeared to be the main causes of bloom formation. Therefore, a coarsened fat network and oil movement besides the conventional principles of polymorphic transformation of cocoa butter should be considered. 相似文献
10.
Konno Y. Tomioka K. Aiba Y. Yamazoe K. Bang-Sup Song 《Solid-State Circuits, IEEE Journal of》2006,41(3):642-650
Optical recording demands a meticulous write strategy to control the laser beam power and regulate the phase change layer temperature tightly. The width, height, and delay of a string of short pulses applied to the laser diode need to be adjusted in fine steps, and the writing speed varies widely per applications. A multi-phase phase-locked loop (PLL) tracks a wide range of clock frequencies, and provides a low-jitter time base for write pulses. With two enabling circuit concepts, PLL loop filter voltage folding/unfolding and switch-in of parallel MOS resistors in delay cells, it is possible to operate a PLL to cover a frequency range spanning over three octaves with one VCO. A 10-stage differential VCO is phase-locked to the input channel clock ranging from 26 to 420 MHz (1/spl times/-16/spl times/ DVD speed), and its 20-phase outputs are used to generate write pulses. The pulsewidth and delay are programmed with 120 /spl plusmn/ 40 ps time resolution. The prototype chip fabricated in 0.35 /spl mu/m CMOS occupies 3.5/spl times/3.3 mm/sup 2/, and consumes 294 mW at 3.3 V. 相似文献