Characterization of the structure and properties of processed alumina-graphene and alumina-zirconia composites

The onset of hybrid alumina-based composites, which combines two or more nano-particles within the alumina matrix has already shown promising improvements in the matrix material. However, variations in mechanical properties including the optimum compositions that give improved properties faced with the development of alumina-based composites require further studies to understand the underlying mechanisms and synergistic effects of the nano-particle additions on the alumina matrix. In the current study, the structure and properties of Al?O?-graphene (0.5 wt%) and Al?O?–ZrO? (4 wt% and 10 wt%) composites fabricated via hot-pressing was studied as a baseline for multiple combinations. Even though the addition of 10 wt%ZrO? resulted in a 23% reduction in the grain size of the alumina matrix, the 4 wt%ZrO? addition resulted in a 14% increase in grain size as compared to the parent alumina matrix. X-ray diffraction analysis revealed that there was approximately 85% monoclinic (m-ZrO₂) vs. 15% tetragonal (t-ZrO₂) crystal structures in the A4ZrO? sample whilst the A₁₀ZrO? had approximately 93% m-ZrO₂ vs. 7% t-ZrO₂. The high-volume fraction of the monoclinic crystal structures in the A₁₀ZrO? accounts for the induced microcracks in the sample since the transition from the ductile-tetragonal to brittle-monoclinic is associated with the exertion of compressive stresses on the alumina matrix by the associated elastic volume expansion of m-ZrO₂. Also, the addition of 0.5 wt%graphene resulted in about 37% reduction in the grain size of the alumina matrix, and approximately 10% increase in hardness as a result of the distribution of graphene along the grain boundaries of the parent alumina matrix, which restricts grain coalescence and growth during processing. Furthermore, an increase up to 115% and 164% were observed in the fracture toughness (K_IC) with the inclusion of 0.5 wt%graphene and 10 wt%ZrO? respectively, which was primarily ascribed to the fine-grained microstructures and toughening mechanisms of the intergranular graphene and ZrO? particles.     

Gastroparesis after celiac plexus block

Pectin constituents, which were about 70 w/w% of extracellular polysaccharides (ECP) from a cell-suspension culture of Mentha, were purified by gel filtration chromatography, and their sugar composition and linkage were investigated. Two major constituents identified were (1-->3)-linked galactan carrying arabinosyl residues on C-6 and (1-->4)-alpha-linked galacturonan partially interspersed with (1-->2)-linked rhamnosyl resides. Acetylated or methylated pectins were not identified on 1H-NMR analysis.     

A panoramic view of Li7P3S11 solid electrolytes synthesis,structural aspects and practical challenges for all-solid-state lithium batteries

The development of an inorganic electrochemical stable solid-state electrolyte is essentially responsible for future state-of-the-art all-solid-state lithium batteries (ASSLBs). Because of their advantages in safety, working temperature, high energy density, and packaging, ASSLBs can develop an ideal energy storage system for modern electric vehicles (EVs). A solid electrolyte (SE) model must have an economical synthesis approach, exhibit electrochemical and chemical stability, high ionic conductivity, and low interfacial resistance. Owing to its highest conductivity of 17 mS·cm^-1, and deformability, the sulfide-based Li₇P₃S₁₁ solid electrolyte is a promising contender for the high-performance bulk type of ASSLBs. Herein, we present a current glimpse of the progress of synthetic procedures, structural aspects, and ionic conductivity improvement strategies. Structural elucidation and mechanistic approaches have been extensively discussed by using various characterization techniques. The chemical stability of Li₇P₃S₁₁ could be enhanced via oxide doping, and hard and soft acid/base (HSAB) concepts are also discussed. The issues to be undertaken for designing the ideal solid electrolytes, interfacial challenges, and high energy density have been discoursed. This review aims to provide a bird's eye view of the recent development of Li₇P₃S₁₁-based solid-state electrolyte applications and explore the strategies for designing new solid electrolytes with a target-oriented approach to enhance the efficiency of high energy density all-solid-state lithium batteries.     

Modeling and Analysis of Temperature Compensation for Multi-temperature Zone Sintering Furnace Temperature Sensing

International Journal of Control, Automation and Systems - The surface temperature of workpieces in a multi-temperature zone sintering furnace is an important parameter to characterize the...     

Green synthesised zinc oxide nanostructures through Periploca aphylla extract shows tremendous antibacterial potential against multidrug resistant pathogens

To grapple with multidrug resistant bacterial infections, implementations of antibacterial nanomedicines have gained prime attention of the researchers across the globe. Nowadays, zinc oxide (ZnO) at nano‐scale has emerged as a promising antibacterial therapeutic agent. Keeping this in view, ZnO nanostructures (ZnO‐NS) have been synthesised through reduction by P. aphylla aqueous extract without the utilisation of any acid or base. Structural examinations via scanning electron microscopy (SEM) and X‐ray diffraction have revealed pure phase morphology with highly homogenised average particle size of 18 nm. SEM findings were further supplemented by transmission electron microscopy examinations. The characteristic Zn–O peak has been observed around 363 nm using ultra‐violet–visible spectroscopy. Fourier‐transform infrared spectroscopy examination has also confirmed the formation of ZnO‐NS through detection of Zn–O bond vibration frequencies. To check the superior antibacterial activity of ZnO‐NS, the authors'' team has performed disc diffusion assay and colony forming unit testing against multidrug resistant E. coli, S. marcescens and E. cloacae. Furthermore, protein kinase inhibition assay and cytotoxicity examinations have revealed that green fabricated ZnO‐NS are non‐hazardous, economical, environmental friendly and possess tremendous potential to treat lethal infections caused by multidrug resistant pathogens.Inspec keywords: nanomedicine, zinc compounds, II‐VI semiconductors, wide band gap semiconductors, nanoparticles, scanning electron microscopy, X‐ray diffraction, antibacterial activity, transmission electron microscopy, particle size, Fourier transform infrared spectra, ultraviolet spectra, visible spectra, enzymes, biochemistry, molecular biophysics, microorganisms, drugs, toxicology, bonds (chemical), semiconductor growth, nanofabrication, vibrational modesOther keywords: green synthesised zinc oxide nanostructures, Periploca aphylla extract, antibacterial potential, multidrug resistant pathogens, multidrug resistant bacterial infections, antibacterial nanomedicines, P. aphylla aqueous extract, structural examinations, scanning electron microscopy, X‐ray diffraction, pure phase morphology, homogenised average particle size, SEM, transmission electron microscopy, Fourier‐transform infrared spectroscopy, bond vibration frequency, antibacterial activity, disc diffusion assay, colony forming unit testing, S. marcescens, E. cloacae, E. coli, ultraviolet‐visible spectroscopy, protein kinase inhibition assay, cytotoxicity, lethal infections, ZnO     

A Service Level Agreement Aware Online Algorithm for Virtual Machine Migration

The demand for cloud computing has increased manifold in the recent past. More specifically, on-demand computing has seen a rapid rise as organizations rely mostly on cloud service providers for their day-to-day computing needs. The cloud service provider fulfills different user requirements using virtualization - where a single physical machine can host multiple Virtual Machines. Each virtual machine potentially represents a different user environment such as operating system, programming environment, and applications. However, these cloud services use a large amount of electrical energy and produce greenhouse gases. To reduce the electricity cost and greenhouse gases, energy efficient algorithms must be designed. One specific area where energy efficient algorithms are required is virtual machine consolidation. With virtual machine consolidation, the objective is to utilize the minimum possible number of hosts to accommodate the required virtual machines, keeping in mind the service level agreement requirements. This research work formulates the virtual machine migration as an online problem and develops optimal offline and online algorithms for the single host virtual machine migration problem under a service level agreement constraint for an over-utilized host. The online algorithm is analyzed using a competitive analysis approach. In addition, an experimental analysis of the proposed algorithm on real-world data is conducted to showcase the improved performance of the proposed algorithm against the benchmark algorithms. Our proposed online algorithm consumed 25% less energy and performed 43% fewer migrations than the benchmark algorithms.     

Highly Functional TNTs with Superb Photocatalytic,Optical, and Electronic Performance Achieving Record PV Efficiency of 10.1% for 1D‐Based DSSCs

Different nanostructures of TiO₂ play an important role in the photocatalytic and photoelectronic applications. TiO₂ nanotubes (TNTs) have received increasing attention for these applications due to their unique physicochemical properties. Focusing on highly functional TNTs (HF‐TNTs) for photocatalytic and photoelectronic applications, this study describes the facile hydrothermal synthesis of HF‐TNTs by using commercial and cheaper materials for cost‐effective manufacturing. To prove the functionality and applicability, these TNTs are used as scattering structure in dye‐sensitized solar cells (DSSCs). Photocatalytic, optical, Brunauer‐Emmett‐Teller (BET), electrochemical impedance spectrum, incident‐photon‐to‐current efficiency, and intensity‐modulated photocurrent spectroscopy/intensity‐modulated photovoltage spectroscopy characterizations are proving the functionality of HF‐TNTs for DSSCs. HF‐TNTs show 50% higher photocatalytic degradation rate and also 68% higher dye loading ability than conventional TNTs (C‐TNTs). The DSSCs having HF‐TNT and its composite‐based multifunctional overlayer show effective light absorption, outstanding light scattering, lower interfacial resistance, longer electron lifetime, rapid electron transfer, and improved diffusion length, and consequently, J _SC, quantum efficiency, and record photoconversion efficiency of 10.1% using commercial N‐719 dye is achieved, for 1D‐based DSSCs. These new and highly functional TNTs will be a concrete fundamental background toward the development of more functional applications in fuel cells, dye‐sensitized solar cells, Li‐ion batteries, photocatalysis process, ion‐exchange/adsorption process, and photoelectrochemical devices.     

AC Potential-Dependent Concentration Variation and Domain Wall Pinning in Co1−x Zn x (x=0.4−0.5) Nanorods

The Co_1?x Zn _x (x=0.4?0.5) nanorods were synthesized via an AC electrochemical deposition method into anodized aluminum oxide (AAO) templates at different voltages ranging from 10 to 18 V, and nanorods of varying concentrations of Co and Zn were obtained. The characterization tools were used to examine different aspects of nanorods, e.g., shape, size, morphology, chemical composition, and magnetic behavior. Scanning electron microscope (SEM) images show that CoZn nanorods have length L=1μm and diameter d=50 nm. The grain size was calculated to be 25.4 nm using an X-ray diffraction (XRD) technique. The XRD also shows some other phases of ZnCoO. The M?H loops measured by a vibrating sample magnetometer (VSM) at room temperature show pure ferromagnetic behavior at all AC potentials. The nanorods show magnetic isotropic behavior due to strong magnetic interactions and presence of random nanorods. The potential-dependent coercivity H _c and saturation magnetization M _s show a non-linear curve which is explained on the basis of magnetic islands and domain wall pinning. This study is useful to tune the magnetic properties of nanorods by a simple and low-cost technique.