Grafting of vinyl monomers onto natural rubber,II. Graft copolymerization of methyl methacrylate onto natural rubber using tetravalent ceric ions

The use of tetravalent ceric ions to initiate graft-copolymerization of methyl methacrylate onto natural rubber (NR) has been investigated. The rate of grafting has been determined by varying the concentration of monomer and cerium(IV), the temperature and the solvents. The graft yield increases with increasing monomer concentration up to 1.877 M, with further increase of the monomer, the graft yield decreases. The percentage of grafting increases with increasing cerium(IV) concentration up to 0.035 M, thereafter it decreases. With increasing temperature the graft yield increases. The effect of CuSO₄ on the rate of grafting has also been investigated. A plausible mechanism has been suggested and the kinetic rate expressions have been derived.     

Improving Water Supply Outlook in Korea with Ensemble Streamflow Prediction

Abstract

The purpose of this study is to propose an alternative forecasting approach for improving the current water supply outlook in Korea. Using a rainfall-runoff model, the existing technique for the water supply outlook in Korea produces monthly low, average, and high runoff forecasts. The proposed technique is called Ensemble Streamflow Prediction (ESP), and is currently implemented by the National Weather Service in the U.S.A. ESP appears particularly valid in Korea where the historical rainfall record is much more comprehensive than the historical streamflow record. This study applies ESP to runoff forecasting for a river basin in Korea to examine its applicability. An ensemble of one-month ahead runoff forecasts at the Gongju gauging station in the Keum River basin, Korea, was generated for each month. The resulting ESP forecasts were compared with the corresponding observed runoff data as well as the existing forecasts. Although this study is limited to one case study, the following conclusions can be made: (1) the ESP technique dominates the existing forecasting techniques in terms of both systematic and random errors; and (2) ESP is more accurate when high flows occur.     

Diffusion of innovation model of consumer behaviour - Ideas to accelerate adoption of renewable energy sources by consumer communities in India

Renewable Energy (RE) sources form a minuscule portion of India’s overall Energy consumption today. India continues to rely on fast depleting fossil fuel and expensive Oil imports to satisfy the energy demands of the economy. But this is hardly sustainable and India has to quickly get RE sources to play a major role in servicing the energy needs of its population. Despite the best efforts the adoption of RE sources by consumer communities in India is patchy. This article will focus on what needs to be done to create a pull from the market for RE sources, by looking at Consumer Behaviour literature available in the area of Diffusion of Innovation[1]. Demand for RE sources from consumer communities must reach a tipping point[4] quickly; for the sector to take-off on its own and become a self-sustaining business.     

Performance Analysis of Gate-Stack Dual-Material DG MOSFET Using Work-Function Modulation Technique for Lower Technology Nodes

Silicon - Short channel effects (SCEs) along with mobility degradation has a great impact on CMOS technology below 100 nm. These effects can be overcome by using gate and channel...     

Nutritive value of mango seed kernel

Seed kernels of two cultivars (Chausa and Dusheri) of mango (Mangifera indica) were analysed for chemical composition, lipid classes, fatty acid composition, amino acid profile and chemical evaluation of protein quality. The seed kernels constituted about 18% of the total fruit and had 5% protein, 6–7% crude fat, 0.19–0.44% tannins, iodine value of 34–44 and saponification number 202–213. Oleic acid (42%) and stearic acid (39%) were the principal fatty acids in the oil. The in vitro digestibility was low in these cultivars, possibly due to the presence of tannins. Sulphur-containing amino acids (methionine+cystine) and isoleucine were the limiting amino acids in Chausa and Dusheri, respectively. The essential amino acid index and protein quality index were high, thus indicating the good quality of the protein in mango seed kernel.     

Penetration enhancers and ocular bioadhesives: two new avenues for ophthalmic drug delivery

This review is focused on the two avenues of development that promise a major impact on future ocular drug therapeutics: bioadhesives, including hydrogels and other agents like carbopols, polyacrylic acids, chitosan, etc., and penetration enhancers, including different surfactants, calcium chelators, etc. The capacity of some polymers to adhere to the mucin coat covering the conjunctiva and the corneal surface of the eye forms the basis for ocular mucoadhesion. These systems markedly prolong the residence time of a drug in the conjunctival sac, since clearence is now controlled by the much slower rate of mucus turnover rather than the tear turnover rate. But improving the corneal drug retention alone is inadequate in bringing about a significant improvement of drug bioavailability. Another approach consists of transiently increasing the pentration characteristics of the cornea with appropriate substances, known as penetration enhancers or absorption promoters. The main aim of this article is to give an insight into the potential application of mucoadhesives and corneal penetration enhancers for the conception of innovative opthalmic delivery appraoches, to decrease the systemic side effects, and create a more focused effect, which may be achieved with lower doses of the drug. Ophthalmic formulations based on these mucoadhesives and penetration enhancers are simple to manufacture and exhibit an excellent tolerance when administered into the cornea. The use of the former considerably prolongs the corneal contact time and the use of the latter increases the rate and amount of drug transport. The various corneal epithelial barriers along with the major routes of transport of drugs are discussed. The article includes a list of the various substances in use or under investigation for the aforementioned properties, along with their mechanisms of action. A fair appraisal of the subject with regard to these two therapeutic approaches and any expected ill effects has been made.     

Biodegradation of Phenol with Wastewater as a Cosubstrate in Upflow Anaerobic Sludge Blanket

Anaerobic degradation of phenol mixed with a readily degradable synthetic wastewater (DSWW) as a cosubstrate was studied in a 12?L upflow anaerobic sludge blanket reactor at 30±2°C over a period of 632?days. DSWW was prepared by diluting sugar cane based molasses. The biomass was acclimatized to high phenol concentration by gradually decreasing the DSWW chemical oxygen demand (COD) of 4,000?mg/L. Feed made up of phenol COD and DSWW COD in the ratio of 7:3 (phenol concentration = 1,176?mg/L) was successfully treated at a hydraulic retention time (HRT) of 12?h and organic loading rate (OLR) of 8?g?COD/L?day. Phenol removal ranged from 99.9 to 84% at phenol COD varying from 10 to 70% in the feed. During the entire operation, COD removal varied from about 74 to 91.3%. The influent COD was distributed into CH4–COD ( ～ 72%), effluent COD ( ～ 17%), and sludge and unaccounted COD ( ～ 11%). The process failure occurred at 4:1 phenol COD: DSWW COD. Specific methanogenic activity of granular sludge exhibited uniform activity up to phenol COD of 70%. The performance of the reactor could not be maintained beyond 70% phenol COD even by reducing the sludge loading rate, increasing HRT, or decreasing OLR.     

Solid state chemistry of Ruddlesden-Popper type complex oxides

Various criteria of formation of perovskites and K₂NiF₄-type compounds, which are the end members of homologous Ruddlesden-Popper series of phases, have been discussed. RP-phases show some general trends in their physical properties. Literature survey of the formation of these phases, their properties, and effect of oxygen stoichiometry and doping is presented. Some conditions for their synthesis are also described.